scholarly journals The Influence of the Thickness of Compact TiO2 Electron Transport Layer on the Performance of Planar CH3NH3PbI3 Perovskite Solar Cells

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3295
Author(s):  
Andrzej Sławek ◽  
Zbigniew Starowicz ◽  
Marek Lipiński
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Transport Layer ◽  
Electron Transport Layer

In recent years, lead halide perovskites have attracted considerable attention from the scientific community due to their exceptional properties and fast-growing enhancement for solar energy harvesting efficiency. One of the fundamental aspects of the architecture of perovskite-based solar cells (PSCs) is the electron transport layer (ETL), which also acts as a barrier for holes. In this work, the influence of compact TiO2 ETL on the performance of planar heterojunction solar cells based on CH3NH3PbI3 perovskite was investigated. ETLs were deposited on fluorine-doped tin oxide (FTO) substrates from a titanium diisopropoxide bis(acetylacetonate) precursor solution using the spin-coating method with changing precursor concentration and centrifugation speed. It was found that the thickness and continuity of ETLs, investigated between 0 and 124 nm, strongly affect the photovoltaic performance of PSCs, in particular short-circuit current density (JSC). Optical and topographic properties of the compact TiO2 layers were investigated as well.

scholarly journals Improving the Performances of Perovskite Solar Cells via Modification of Electron Transport Layer

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 147 ◽  
Author(s):  
Mao Jiang ◽  
Qiaoli Niu ◽  
Xiao Tang ◽  
Heyi Zhang ◽  
Haowen Xu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Simple Method ◽  
Film Forming

The commonly used electron transport material (6,6)-phenyl-C61 butyric acid methyl ester (PCBM) for perovskite solar cells (PSC) with inverted planar structures suffers from properties such as poor film-forming. In this manuscript, we demonstrate a simple method to improve the film-forming properties of PCBM by doping PCBM with poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT) as the electron transport layer (ETL), which effectively enhances the performance of CH3NH3PbI3 based solar cells. With 5 wt % F8BT in PCBM, the short circuit current (JSC) and fill factor (FF) of PSC both significantly increased from 17.21 ± 0.15 mA·cm−2 and 71.1 ± 0.07% to 19.28 ± 0.22 mA·cm−2 and 74.7 ± 0.21%, respectively, which led to a power conversion efficiency (PCE) improvement from 12.6 ± 0.24% to 15 ± 0.26%. The morphology investigation suggested that doping with F8BT facilitated the formation of a smooth and uniform ETL, which was favorable for the separation of electron-hole pairs, and therefore, an improved performance of PSC.

scholarly journals The Performance Improvement of Using Hole Transport Layer with Lithium and Cobalt for Inverted Planar Perovskite Solar Cell

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 354
Author(s):  
Shaoxi Wang ◽  
He Guan ◽  
Yue Yin ◽  
Chunfu Zhang
Keyword(s):  
Solar Cells ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Hole Mobility ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Planar Heterojunction

With the continuous development of solar cells, the perovskite solar cells (PSCs), whose hole transport layer plays a vital part in collection of photogenerated carriers, have been studied by many researchers. Interface transport layers are important for efficiency and stability enhancement. In this paper, we demonstrated that lithium (Li) and cobalt (Co) codoped in the novel inorganic hole transport layer named NiOx, which were deposited onto ITO substrates via solution methods at room temperature, can greatly enhance performance based on inverted structures of planar heterojunction PSCs. Compared to the pristine NiOx films, doping a certain amount of Li and Co can increase optical transparency, work function, electrical conductivity and hole mobility of NiOx film. Furthermore, experimental results certified that coating CH3NH3PbIxCl3−x perovskite films on Li and Co- NiOx electrode interlayer film can improve chemical stability and absorbing ability of sunlight than the pristine NiOx. Consequently, the power conversion efficiency (PCE) of PSCs has a great improvement from 14.1% to 18.7% when codoped with 10% Li and 5% Co in NiOx. Moreover, the short-circuit current density (Jsc) was increased from 20.09 mA/cm2 to 21.7 mA/cm2 and the fill factor (FF) was enhanced from 0.70 to 0.75 for the PSCs. The experiment results demonstrated that the Li and Co codoped NiOx can be a effective dopant to improve the performance of the PSCs.

scholarly journals Graphene/ZnO nanocomposite as an electron transport layer for perovskite solar cells; the effect of graphene concentration on photovoltaic performance

RSC Advances ◽  
2017 ◽  
Vol 7 (46) ◽  
pp. 28610-28615 ◽  
Author(s):  
P. S. Chandrasekhar ◽  
Vamsi K. Komarala
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Electron Transporting Layer

Perovskite solar cells (PSCs) have been fabricated by a graphene/ZnO nanocomposite (G/ZnO NC) as an electron transporting layer.

scholarly journals Improved photovoltaic performance of triple-cation mixed-halide perovskite solar cells with binary trivalent metals incorporated into the titanium dioxide electron transport layer

2019 ◽  
Vol 7 (17) ◽  
pp. 5028-5036 ◽  
Author(s):  
M. Thambidurai ◽  
Shini Foo ◽  
K. M. Muhammed Salim ◽  
P. C. Harikesh ◽  
Annalisa Bruno ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Solar Cells ◽  
Electron Transport ◽  
Energy Level ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Highly Efficient ◽  
Halide Perovskite

Simultaneous improvement in transparency, conductivity, and energy level alignment was attained via a highly efficient AlIn-TiO2 ETL with the unrivaled PCE of 19%.

Interfacial modification of various alkali metal cations in perovskite solar cells and their influence on photovoltaic performance

2020 ◽  
Vol 44 (21) ◽  
pp. 8902-8909
Author(s):  
Yinyi Huang ◽  
Shina Li ◽  
Chaorong Wu ◽  
Shuo Wang ◽  
Chengyan Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Alkali Metal ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Alkali Metal Cations ◽  
Interfacial Modification ◽  
Perovskite Material

The electron transport layer (ETL) between the perovskite material and cathode plays an important role in planar perovskite solar cells.

Enhanced efficiency and air-stability of NiOX-based perovskite solar cells via PCBM electron transport layer modification with Triton X-100

Nanoscale ◽  
2017 ◽  
Vol 9 (42) ◽  
pp. 16249-16255 ◽  
Author(s):  
Kisu Lee ◽  
Jaehoon Ryu ◽  
Haejun Yu ◽  
Juyoung Yun ◽  
Jungsup Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Triton X

In this work, a phenyl-C61-butyric acid methyl ester (PCBM) electron transport layer was modified with Triton X-100, and this improved the photovoltaic performance and air-stability of perovskite solar cells.

Improving photovoltaic performance of perovskite solar cells: The interfacial modification role of aluminum chloride and ammonia on ZnO nanorods

2017 ◽  
Vol 10 (03) ◽  
pp. 1750017 ◽  
Author(s):  
Zhaosong Li ◽  
Jun Zhang ◽  
Yang Xu ◽  
Mengni Xue ◽  
Hanbin Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Aluminum Chloride ◽  
Light Transmission ◽  
Photovoltaic Performance ◽  
Zno Nanorods ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Primary Advantage

ZnO nanorods (ZnO NRs) as electron transport layer (ETL) in organometal halide perovskite solar cells (PSCs) had been prepared because of ZnO exhibiting excellent electron mobility and light transmission performance. The ZnO NRs were modified with a simple solvothermal method using aluminum chloride (AlCl3) and ammonia (NH[Formula: see text]H2O) as precursor solution, the primary advantage of this approach was low temperature, simple process. The concentration of the precursor solution was further investigated, and a power conversion efficiency (PCE) of 12.1% was achieved.

scholarly journals Facile Synthesis of Spherical TiO2 Hollow Nanospheres with a Diameter of 150 nm for High-Performance Mesoporous Perovskite Solar Cells

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 629
Author(s):  
Hoang Van Quy ◽  
Dang Hai Truyen ◽  
Sangmo Kim ◽  
Chung Wung Bark
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Synthesis Method ◽  
Short Circuit Current ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Hollow Nanospheres ◽  
Facile Synthesis

The electron transport layer (ETL) of organic–inorganic perovskite solar cells plays an important role in their power conversion efficiency (PCE). In this study, TiO2 hollow nanospheres with a diameter of 150 nm were prepared by a facile synthesis method. The synthesized TiO2 hollow nanospheres had a highly porous structure with a surface area of 85.23 m2 g−1, which is significantly higher than commercial TiO2 (P25) (54.32 m2 g−1), indicating that they can form an ideal mesoporous layer for Formamidinium iodide-based perovskite solar cells (PSCs). In addition, the nanospheres achieved a remarkable perovskite performance, and the average PCE increased from 12.87% to 14.27% with a short circuit current density of 22.36 mAcm−2, an open voltage of 0.95 V, and a fill factor of 0.65. The scanning electron microscopy images revealed that the enhanced PCE could be due to the improved carrier collection and transport properties of the nanosphere, which enabled efficient filtration of perovskite into the TiO2 mesoporous ETL. The TiO2 hollow nanospheres fabricated in this study show high potential as a high-quality ETL material for efficient (FAPbI3)0.97(MAPbBr3)0.03-based PSCs.

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