scholarly journals Two New Spiro-Heterocyclic γ-Lactams from A Marine-Derived Aspergillus fumigatus Strain CUGBMF170049

Marine Drugs ◽  
2019 ◽  
Vol 17 (5) ◽  
pp. 289 ◽  
Author(s):  
Xiuli Xu ◽  
Jiahui Han ◽  
Yanan Wang ◽  
Rui Lin ◽  
Haijin Yang ◽  
...  
Keyword(s):  
Spectral Analysis ◽  
Circular Dichroism ◽  
Aspergillus Fumigatus ◽  
2D Nmr ◽  
Two Dimensional ◽  
One Dimensional ◽  
Helvolic Acid ◽  
Circular Dichroïsm

Two new spiro-heterocyclic γ-lactam derivatives, cephalimysins M (1) and N (2), were isolated from the fermentation cultures of the marine-derived fungus Aspergillus fumigatus CUGBMF17018. Two known analogues, pseurotin A (3) and FD-838 (4), as well as four previously reported helvolic acid derivatives, 16-O-propionyl-16-O-deacetylhelvolic acid (5), 6-O-propionyl-6-O-deacetylhelvolic acid (6), helvolic acid (7), and 1,2-dihydrohelvolic acid (8) were also identified. One-dimensional (1D), two-dimensional (2D) NMR, HRMS, and circular dichroism spectral analysis characterized the structures of the isolated compounds.

Pseurotin A1 and A2, two new 1-oxa-7-azaspiro[4.4]non-2-ene-4,6-diones from the holothurian-derived fungus Aspergillus fumigatus WFZ-25

2011 ◽  
Vol 89 (1) ◽  
pp. 72-76 ◽  
Author(s):  
Fa-Zuo Wang ◽  
De-Hai Li ◽  
Tian-Jiao Zhu ◽  
Min Zhang ◽  
Qian-Qun Gu
Keyword(s):  
Circular Dichroism ◽  
Aspergillus Fumigatus ◽  
Spectroscopic Data ◽  
2D Nmr ◽  
Esi Ms ◽  
Extensive Analysis ◽  
Circular Dichroïsm ◽  
New Metabolites

Two new metabolites containing a 1-oxa-7-azaspiro[4.4]non-2-ene-4,6-dione core, pseurotin A1 (1) and A2 (2), as well as pseurotin A (3), were isolated from the holothurian-derived fungus Aspergillus fumigatus WFZ-25. These compounds were determined using extensive analysis of their spectroscopic data, including 1D and 2D NMR, HR-ESI-MS, and circular dichroism (CD) experiments.

scholarly journals Novel Polyketides Produced by the Endophytic Fungus Aspergillus Fumigatus from Cordyceps Sinensis

Molecules ◽  
2018 ◽  
Vol 23 (7) ◽  
pp. 1709 ◽  
Author(s):  
Da-Le Guo ◽  
Xiao-Hua Li ◽  
Dan Feng ◽  
Meng-Ying Jin ◽  
Yu-Mei Cao ◽  
...  
Keyword(s):  
Aspergillus Fumigatus ◽  
Inhibitory Activity ◽  
Endophytic Fungus ◽  
Fermentation Broth ◽  
2D Nmr ◽  
Cordyceps Sinensis ◽  
Two Dimensional ◽  
One Dimensional ◽  
Ic50 Values

Five new polyketides, including two pairs of enantiomers and a racemate, were isolated from the fermentation broth of Aspergillus fumigatus, an endophytic fungus isolated from Cordyceps sinensis. Their structures were identified using one-dimensional (1D) and two-dimensional (2D) NMR experiments, and the absolute configurations of the enantiomers were confirmed using electronic circular dichroism (ECD) calculations. Compounds 1a and 2a exhibited inhibitory activity against the MV4-11 cell line in vitro, with IC50 values of 23.95 µM and 32.70 µM, respectively.

Two-dimensional Imaging of a Model Pharmaceutical Dosage Tablet Using a Scanning Vibrational Circular Dichroism System

2021 ◽  
Author(s):  
Hisako Sato ◽  
Sumio Aisawa ◽  
Honoka Ida ◽  
Masaru Shimizu ◽  
Keisuke Watanabe ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Vibrational Circular Dichroism ◽  
Two Dimensional ◽  
Circular Dichroïsm

scholarly journals Spectral Analysis of Sampled Signals in the Linear Canonical Transform Domain

2012 ◽  
Vol 2012 ◽  
pp. 1-19 ◽  
Author(s):  
Bing-Zhao Li ◽  
Tian-Zhou Xu
Keyword(s):  
Spectral Analysis ◽  
Spectral Representation ◽  
Digital Signal ◽  
Sampling Theorem ◽  
Transform Domain ◽  
Linear Canonical Transform ◽  
Two Dimensional ◽  
Research Papers ◽  
One Dimensional ◽  
Uniform Sampling

The spectral analysis of uniform or nonuniform sampling signal is one of the hot topics in digital signal processing community. Theories and applications of uniformly and nonuniformly sampled one-dimensional or two-dimensional signals in the traditional Fourier domain have been well studied. But so far, none of the research papers focusing on the spectral analysis of sampled signals in the linear canonical transform domain have been published. In this paper, we investigate the spectrum of sampled signals in the linear canonical transform domain. Firstly, based on the properties of the spectrum of uniformly sampled signals, the uniform sampling theorem of two dimensional signals has been derived. Secondly, the general spectral representation of periodic nonuniformly sampled one and two dimensional signals has been obtained. Thirdly, detailed analysis of periodic nonuniformly sampled chirp signals in the linear canonical transform domain has been performed.

scholarly journals A New Chlorinated Phenolic Compound From the Antarctic Lichen, Pertusaria dactylina

2020 ◽  
Vol 15 (3) ◽  
pp. 1934578X2090288
Author(s):  
Man H. Koo ◽  
Min J. Kim ◽  
Jae E. Seo ◽  
Ji H. Kim ◽  
Se J. Han ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Phenolic Compound ◽  
Fast Atom Bombardment ◽  
2D Nmr ◽  
Antimicrobial Activities ◽  
Inhibitory Effect ◽  
Two Dimensional ◽  
One Dimensional ◽  
The Antarctic

A new chlorinated phenolic compound, methyl-3-chloro-2-hydroxy-4-methoxy-6-pentylbenzoate (1) and 4 known compounds (2-5) were isolated from the Antarctic lichen, Pertusaria dactylina ( Pertusariaceae). The structure of the new compound was determined by means of One-dimensional and two dimensional nuclear magnetic resonance (1D and 2D NMR) and high-resolution fast atom bombardment mass spectrometry (HRFABMS) experiments. The antimicrobial activities of compounds 1 to 5 against Staphylococcus aureus and Candida albicans were evaluated. The results showed that compound 1 exhibited a weak inhibitory effect against C. albicans with an IC50 value of 67 ± 7 μg/mL.

scholarly journals A New Neolignan from Panicum turgidum

2016 ◽  
Vol 11 (7) ◽  
pp. 1934578X1601100
Author(s):  
Ahmed A. Zaki ◽  
Zulfiqar Ali ◽  
Yasser A. El-Amier ◽  
Ikhlas A. Khan
Keyword(s):  
Circular Dichroism ◽  
Optical Rotation ◽  
2D Nmr ◽  
Circular Dichroism Spectroscopy ◽  
Spectroscopic Methods ◽  
Relative Configuration ◽  
Esi Ms ◽  
Spectroscopy Optical ◽  
Circular Dichroïsm

A new neolignan, paniculignan (1), and a known lignan, tetracentronside B (2), were isolated from Panicum turgidum. The structure of 1 was elucidated by extensive spectroscopic methods including 1D and 2D NMR and HR-ESI-MS. The relative configuration of 1 was determined on the basis of circular dichroism spectroscopy, optical rotation, and NOESY correlations.

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