scholarly journals Thermodynamic Modeling and Performance Analysis of Vehicular High-Temperature Proton Exchange Membrane Fuel Cell System

Membranes ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 72
Author(s):  
Yanju Li ◽  
Dongxu Li ◽  
Zheshu Ma ◽  
Meng Zheng ◽  
Zhanghao Lu
Keyword(s):  
High Temperature ◽  
Power Distribution ◽  
System Performance ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Exergy Loss ◽  
Inlet Pressure ◽  
Inlet Temperature ◽  
Exchange Membrane

Since the high temperature proton exchange membrane fuel cells (HT-PEMFC) stack require a range of auxiliary equipments to maintain operating conditions, it is necessary to consider operation of related components in the design of HT-PEMFC systems. In this paper, a thermodynamic model of a vehicular HT-PEMFC system using phosphoric acid doped polybenzimidazole membrane is developed. The power distribution and exergy loss of each component are derived according to thermodynamic analysis, where the stack and heat exchanger are the two components with the greatest exergy loss. In addition, ecological functions and improvement potentials are proposed to evaluate the system performance better. On this basis, the effects of stack inlet temperature, pressure, and stoichiometric on system performance are analyzed. The results showed that the energy efficiency, exergy efficiency and net output power of the system achieved the maximum when the inlet gases temperature is 406.1 K. The system performance is better when the cathode inlet pressure is relatively low and the anode inlet pressure is relatively high. Moreover, the stoichiometry should be reduced to improve the system output performance on the basis of ensuring sufficient gases reaction in the stack.

scholarly journals Experimental Study on the Effect of Hydrogen Sulfide on High-Temperature Proton Exchange Membrane Fuel Cells by Using Electrochemical Impedance Spectroscopy

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 441 ◽  
Author(s):  
Ren-Jun Kang ◽  
Yong-Song Chen
Keyword(s):  
Hydrogen Sulfide ◽  
High Temperature ◽  
Proton Exchange Membrane ◽  
Electrochemical Impedance ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Cell Performance ◽  
Membrane Electrode ◽  
Pure Hydrogen ◽  
Exchange Membrane

When the fuel supplied to a high-temperature proton exchange membrane fuel cell (HT-PEMFC) is produced by hydrocarbon formation, hydrogen sulfide (H2S) may appear, resulting in decreased cell performance and durability. To study the effects of H2S on the performance and durability of the HT-PEMFC, a series of experiments was conducted. In the first step, the effects of polyvinylidene fluoride (PVDF) and platinum loading on cell performance were investigated and discussed under pure hydrogen operation conditions. Optimal PVDF and platinum compositions in the catalyst layer are suggested. Then, the effect of H2S on membrane electrode assembly (MEA) performance with various platinum loadings was investigated by supplying hydrogen containing 5.2 ppm of H2S to the anode of the MEA. An electrochemical impedance spectroscope was employed to measure the impedance of the MEAs under various operating conditions. Finally, degradation of the MEA when supplied with hydrogen containing 5.2 ppm of H2S was analyzed and discussed. The results suggest that the performance of an MEA with 0.7 mg Pt cm−2 and 10% PVDF can be recovered by supplying pure hydrogen. The rate of voltage decrease is around 300 μV h−1 in the presence of H2S.

scholarly journals Exergetic Performance Coefficient Analysis and Optimization of a High-Temperature Proton Exchange Membrane Fuel Cell

Membranes ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 70
Author(s):  
Dongxu Li ◽  
Yanju Li ◽  
Zheshu Ma ◽  
Meng Zheng ◽  
Zhanghao Lu
Keyword(s):  
Energy Efficiency ◽  
High Temperature ◽  
Fuel Cell ◽  
Power Density ◽  
Doping Level ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Inlet Pressure ◽  
Exergy Destruction ◽  
Exchange Membrane

Performance of a high-temperature proton exchange membrane fuel cell (HT-PEMFC) and the influence of different parameters on HT-PEMFC is analyzed in this study. Firstly, mathematical expression for energy efficiency, power density, exergy destruction and exergetic performance coefficient (EPC) are derived. Then, the relationship between the dimensionless power density, exergy destruction rate, exergetic performance coefficient (EPC) and energy efficiency is compared. Furthermore, the effect of flow rate, doping level, inlet pressure and film thickness are considered to evaluate the performance of HT-PEMFC. Results show that EPC not only considers exergetic loss rate to minimize exergetic loss, but also considers the power density of HT-PEMFC to maximize its power density and improve its efficiency, so EPC represents a better performance criterion. In addition, increasing inlet pressure and doping level can improve EPC and energy efficiency, respectively.

scholarly journals Modelling of Humidity Dynamics for Open-Cathode Proton Exchange Membrane Fuel Cell

2021 ◽  
Vol 12 (3) ◽  
pp. 106
Author(s):  
Fengxiang Chen ◽  
Liming Zhang ◽  
Jieran Jiao
Keyword(s):  
Fuel Cell ◽  
Mass Flow ◽  
Proton Exchange Membrane ◽  
Flow Model ◽  
Transport Theory ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Output Performance ◽  
Exchange Membrane

The durability and output performance of a fuel cell is highly influenced by the internal humidity, while in most developed models of open-cathode proton exchange membrane fuel cells (OC-PEMFC) the internal water content is viewed as a fixed value. Based on mass and energy conservation law, mass transport theory and electrochemistry principles, the model of humidity dynamics for OC-PEMFC is established in Simulink® environment, including the electrochemical model, mass flow model and thermal model. In the mass flow model, the water retention property and oxygen transfer characteristics of the gas diffusion layer is modelled. The simulation indicates that the internal humidity of OC-PEMFC varies with stack temperature and operating conditions, which has a significant influence on stack efficiency and output performance. In order to maintain a good internal humidity state during operation, this model can be used to determine the optimal stack temperature and for the design of a proper control strategy.

Submicro-pore containing poly(ether sulfones)/polyvinylpyrrolidone membranes for high-temperature fuel cell applications

2015 ◽  
Vol 3 (16) ◽  
pp. 8847-8854 ◽  
Author(s):  
Zhibin Guo ◽  
Ruijie Xiu ◽  
Shanfu Lu ◽  
Xin Xu ◽  
Shichun Yang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Exchange Membrane

A novel submicro-pore containing proton exchange membrane is designed and fabricated for application in high-temperature fuel cells.

scholarly journals Design of Incremental Conductance Sliding Mode MPPT Control Applied by Integrated Photovoltaic and Proton Exchange Membrane Fuel Cell System under Various Operating Conditions for BLDC Motor

2015 ◽  
Vol 2015 ◽  
pp. 1-14 ◽  
Author(s):  
Jehun Hahm ◽  
Hyoseok Kang ◽  
Jaeho Baek ◽  
Heejin Lee ◽  
Mignon Park
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Sliding Mode ◽  
Proton Exchange ◽  
Operating Conditions ◽  
System Control ◽  
Atmospheric Conditions ◽  
Pv Array ◽  
Incremental Conductance ◽  
Exchange Membrane

This paper proposes an integrated photovoltaic (PV) and proton exchange membrane fuel cell (PEMFC) system for continuous energy harvesting under various operating conditions for use with a brushless DC motor. The proposed scheme is based on the incremental conductance (IncCond) algorithm combined with the sliding mode technique. Under changing atmospheric conditions, the energy conversion efficiency of a PV array is very low, leading to significant power losses. Consequently, increasing efficiency by means of maximum power point tracking (MPPT) is particularly important. To manage such a hybrid system, control strategies need to be established to achieve the aim of the distributed system. Firstly, a Matlab/Simulink based model of the PV and PEMFC is developed and validated, as well as the incremental conductance sliding (ICS) MPPT technique; then, different MPPT algorithms are employed to control the PV array under nonuniform temperature and insolation conditions, to study these algorithms effectiveness under various operating conditions. Conventional techniques are easy to implement but produce oscillations at MPP. Compared to these techniques, the proposed technique is more efficient; it produces less oscillation at MPP in the steady state and provides more precise tracking.

A high performance polybenzimidazole–CNT hybrid electrode for high-temperature proton exchange membrane fuel cells

2014 ◽  
Vol 2 (19) ◽  
pp. 7015-7019 ◽  
Author(s):  
He-Yun Du ◽  
Chen-Hao Wang ◽  
Chen-Shuan Yang ◽  
Hsin-Cheng Hsu ◽  
Sun-Tang Chang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
High Temperature ◽  
High Performance ◽  
Proton Exchange Membrane ◽  
Electrochemical Activity ◽  
Proton Exchange ◽  
Exchange Membrane

A well-controlled Pt/PBI–CNT electrode provides not only good interfacial continuity but also numerous edge planes, which has strong electrochemical activity in HT-PEMFCs.

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