scholarly journals U-Pb, Ar-Ar, and Re-Os Geochronological Constraints on Multiple Magmatic–Hydrothermal Episodes at the Lake George Mine, Central New Brunswick

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 566 ◽  
Author(s):  
Carlin Lentz ◽  
Kathleen Thorne ◽  
Christopher R. M. McFarlane ◽  
Douglas A. Archibald
Keyword(s):  
New Brunswick ◽  
Zircon Geochronology ◽  
Weighted Mean ◽  
Metasedimentary Rocks ◽  
Quartz Veins ◽  
Icp Ms ◽  
Step Heating ◽  
Geochronological Constraints ◽  
Lake George

The Lake George antimony mine was at one time North America’s largest producer of antimony. Despite being widely known for the antimony mineralization, the deposit also hosts a range of styles of mineralization such as multiple generations of W-Mo bearing quartz veins as well as a system of As-Au bearing quartz–carbonate veins. In situ U-Pb zircon geochronology, using LA ICP-MS, of the Lake George granodiorite yielded a weighted mean 206Pb/238U age of 419.6 ± 3.0 Ma. Step heating of phlogopite separated from the lamprophyre dykes produced a 40Ar/39Ar plateau segment date of 419.4 ± 1.4 Ma. Single molybdenite crystal analysis for Re-Os geochronology was conducted on two W-Mo-bearing quartz veins, which cross-cut altered granodiorite and altered metasedimentary rocks and yielded two dates of 415.7 ± 1.7 Ma and 416.1 ± 1.7 Ma respectively. 40Ar/39Ar geochronology of muscovite from alteration associated with Au-bearing quartz–carbonate veins yielded one representative plateau segment date of 414.1 ± 1.3 Ma. The dates produced in this study revealed that the different magmatic–hydrothermal events at the Lake George mine occurred over approximately a 10-million-year period at the end of the Silurian and the start of the Devonian following the termination of the Acadian orogeny.

High-resolution LA-ICP-MS trace-element mapping of magmatic biotite: A new approach for studying syn- to post-magmatic evolution

2020 ◽  
Vol 58 (3) ◽  
pp. 293-311 ◽  
Author(s):  
Zeinab Azadbakht ◽  
David R. Lentz
Keyword(s):  
New Brunswick ◽  
Trace Element ◽  
Inductively Coupled Plasma ◽  
Fluid Phase ◽  
New Approach ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Magma Crystallization ◽  
Topaz Granite

ABSTRACT Biotite grains from 22 felsic intrusions in New Brunswick were mapped in situ using a laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS). We investigated the extent to which biotite can retain its magmatic zoning patterns and, where zoning does exist, how it can be used to elucidate early to late stage, syn-magmatic to post-crystallization processes. Although the major element and halogen contents of the examined biotite phenocrysts are homogeneous, two-thirds of the grains display trace-element zoning for Ba, Rb, and Cs. The results also indicated that zoning is better retained in larger grains (i.e., > 500 × 500 μm) with minimal alteration and mineral inclusions. An exceptionally well-zoned Li-rich siderophyllite from the Pleasant Ridge topaz granite in southwestern New Brunswick shows Ti, Ta, Sn, W, Cs, Rb, and V (without Li or Ba) zoning. Cesium values increase from 200 to 1400 ppm from core to rim. Conversely, Sn and W values decrease toward the rim (50 to 10 and 100 to 10 ppm, respectively). Tantalum and Ti values show fewer variations but drop abruptly close to the rim of the grain (100 to 20 and 2000 to 500 ppm, respectively). These observations may indicate crystallization of mineral phases with high partition coefficients for these highly incompatible elements (except Ti) (e.g., cassiterite and rutile) followed by fractionation of a fluid phase at a later stage of magma crystallization. The preservation of zoning may indicate rapid cooling post-crystallization of the parent magma.

First in-situ Rb-Sr dating of metasedimentary rocks from the Pontiac subprovince, Superior Craton, Canada. Implications towards the regional metamorphic evolution of the sequence.

2020 ◽  
Author(s):  
Nicholas Leventis ◽  
Thomas Zack ◽  
Iain Pitcairn ◽  
Johan Högmalm
Keyword(s):  
Accretionary Prism ◽  
Metasedimentary Rocks ◽  
Metamorphic History ◽  
Accuracy And Precision ◽  
Icp Ms ◽  
Age Variations ◽  
History Of ◽  
Peak Metamorphism ◽  
Superior Craton

<p>The Pontiac subprovince consists of metaturbidites, plutons and thin ultramafic rock layers of Archean age and lies south of the Cadillac-Larder Lake (C-LL) fault zone which is the boundary between the Pontiac and the extensively mineralized Abitibi Greenstone Belt. The sediments show a Barrovian metamorphic gradient which increases southwards, away from the C-LL fault. The most likely tectonic provenance for the Pontiac sedimentary rocks is that they represent a relic accretionary prism with material derived from both the Abitibi and an older terrane. Zircon U-Pb dating shows that deposition occurred not later than 2685±3 Ma ago and recent, robust Lu-Hf dating of garnets bracketed Pontiac's peak metamorphic conditions at 2658±4 Ma. For this study we used a recently developed LA-ICP-MS/MS method for in-situ Rb-Sr dating of biotite and plagioclase in samples ranging in metamorphic grade (biotite to sillimanite zones) from the Pontiac subprovince. Calibration of the instrument was achieved by repeated ablations on several reference materials (see Hogmalm et al. 2017) which also provided the monitoring of accuracy and precision throughout the analyses. Results show a range in dates between 2550 Ma and 2200 Ma with an average of 2440±50 Ma (2σ). Samples from the staurolite and kyanite zones have a larger range with respect to the other zones, but no significant differences are observed in the data with any method of data handing. These dates are ≈300Ma younger than the peak metamorphism in the area and this is attributed to either overgrowth and re-setting of the Rb-Sr system by a second metamorphic/hydrothermal event, or diffusional resetting with core-rim age variations. Possible influence from the adjacent late syntectonic to post-tectonic monzodiorite-monzonite-granodiorite-syenite (MMGS) plutons dated 2671±4 Ma and the garnet-muscovite-granite series (GMG) dated ≈2650 Ma cannot be ruled out. This study provides insights about the metamorphic history of the sequence and supports previous findings regarding resetting of some isotopic systems with relatively low closure temperatures (≈350-400°C) by later thermal events.</p>

scholarly journals Zircon geochronology from the Kangaatsiaq– Qasigiannguit region, the northern part of the 1.9–1.8 Ga Nagssugtoqidian orogen, West Greenland

2006 ◽  
Vol 11 ◽  
pp. 87-100 ◽  
Author(s):  
Kristine Thrane ◽  
James N. Connelly
Keyword(s):  
Detrital Zircons ◽  
Zircon Geochronology ◽  
West Greenland ◽  
Metasedimentary Rocks ◽  
The North ◽  
Ion Probe ◽  
Icp Ms ◽  
Supracrustal Belt ◽  
Granitoid Rocks ◽  
Age Patterns

The Kangaatsiaq–Qasigiannguit region in the northern part of the Palaeoproterozoic Nagssugtoqidian orogen of West Greenland consists of poly-deformed orthogneisses and minor occurrences of interleaved, discontinuous supracrustal belts. Laser ablation ICP-MS 207Pb/206Pb analyses of detrital zircons from four metasedimentary rocks (supplemented by ion probe analysis of one sample) and igneous zircons from six granitoid rocks cutting metasedimentary units indicate that the supracrustal rocks in the Kangaatsiaq–Qasigiannguit (Christianshåb) region are predominantly Archaean in age. Four occurrences of metasedimentary rocks are clearly Archaean, two have equivocal ages, and only one metasedimentary unit, from within the Naternaq (Lersletten) supracrustal belt, is demonstrably Palaeoproterozoic and readily defines a large fold complex of this age at Naternaq. The 2.9–2.8 Ga ages of detrital Archaean grains are compatible with derivation from the local basement orthogneisses within the Nagssugtoqidian orogen. The detrital age patterns are similar to those of metasediments within the central Nagssugtoqidian orogen but distinct from age patterns in metasediments of the Rinkian belt to the north, where there is an additional component of pre-2.9 Ga zircons. Synkinematic intrusive granitoid rocks constrain the ages of some Archaean deformation at 2748 ± 19 Ma and some Palaeoproterozoic deformation at 1837 ± 12 Ma.

Pre-Alpine evolution of the Seckau Complex (Austroalpine basement/Eastern Alps): Constraints from in-situ LA-ICP-MS U Pb zircon geochronology

Lithos ◽  
2018 ◽  
Vol 296-299 ◽  
pp. 412-430 ◽  
Author(s):  
Magdalena Mandl ◽  
Walter Kurz ◽  
Christoph Hauzenberger ◽  
Harald Fritz ◽  
Urs Klötzli ◽  
...  
Keyword(s):  
Eastern Alps ◽  
Zircon Geochronology ◽  
Icp Ms ◽  
Austroalpine Basement

scholarly journals Early Cambrian U-Pb zircon age and Hf-isotope data from the Guasayán pluton, Sierras Pampeanas, Argentina: implications for the northwestern boundary of the Pampean arc

2016 ◽  
Vol 43 (1) ◽  
pp. 137 ◽  
Author(s):  
Juan A. Dahlquist ◽  
Sebastián O. Verdecchia ◽  
Edgardo G. Baldo ◽  
Miguel A.S. Basei ◽  
Pablo H. Alasino ◽  
...  
Keyword(s):  
Central Area ◽  
Magma Source ◽  
Western Boundary ◽  
Low Grade ◽  
Early Cambrian ◽  
Zircon Age ◽  
Sierras Pampeanas ◽  
Metasedimentary Rocks ◽  
Icp Ms

An Early Cambrian pluton, known as the Guasayán pluton, has been identified in the central area of Sierra de Guasayán, northwestern Argentina. A U-Pb zircon Concordia age of 533±4 Ma was obtained by LA-MC-ICP-MS and represents the first report of robustly dated Early Cambrian magmatism for the northwestern Sierras Pampeanas. The pluton was emplaced in low-grade metasedimentary rocks and its magmatic assemblage consists of K-feldspar (phenocrysts)+plagioclase+quartz+biotite, with zircon, apatite, ilmenite, magnetite and monazite as accessory minerals. Geochemically, the granitic rock is a metaluminous subalkaline felsic granodiorite with SiO2=69.24%, Na2O+K2O=7.08%, CaO=2.45%, Na2O/ K2O=0.71 and FeO/MgO=3.58%. Rare earth element patterns show moderate slope (LaN/YbN=8.05) with a slightly negative Eu anomalies (Eu/Eu*=0.76). We report the first in situ Hf isotopes data (εHft=-0.12 to -4.76) from crystallized zircons in the Early Cambrian granites of the Sierras Pampeanas, helping to constrain the magma source and enabling comparison with other Pampean granites. The Guasayán pluton might provide a link between Early Cambrian magmatism of the central Sierras Pampeanas and that of the Eastern Cordillera, contributing to define the western boundary of the Pampean paleo-arc.

scholarly journals Geological relationships and laser ablation ICP-MS U-Pb geochronology of the Saint George Batholith, southwestern New Brunswick, Canada: implications for its tectonomagmatic evolution

2017 ◽  
Vol 53 ◽  
pp. 207-240 ◽  
Author(s):  
Nadia Mohammadi ◽  
Les Fyffe ◽  
Christopher R.M. McFarlane ◽  
Kay G. Thorne ◽  
David R. Lentz ◽  
...  
Keyword(s):  
New Brunswick ◽  
Geochemical Data ◽  
Late Devonian ◽  
Magmatic Evolution ◽  
Early Devonian ◽  
Tectonic Environment ◽  
Icp Ms ◽  
Zircon Crystallization ◽  
Two Samples

  The Late Silurian to Late Devonian Saint George Batholith in southwestern New Brunswick is a large composite intrusion (2000 km2) emplaced into the continental margin of the peri-Gondwanan microcontinent of Ganderia. The batholith includes: (1) Bocabec Gabbro; (2) equigranular Utopia and Wellington Lake biotite granites; (3) Welsford, Jake Lee Mountain, and Parks Brook peralkaline granites; (4) two-mica John Lee Brook Granite; (6) Jimmy Hill and Magaguadavic megacrystic granites; and (6) rapakivi Mount Douglas Granite. New LA ICP-MS in situ analyses of six samples from the Saint George Batholith are as follows: (1) U-Pb monazite crystallization age of 425.5 ± 2.1 Ma for the Utopia Granite in the western part of the batholith (2) U-Pb zircon crystallization ages of 420.4 ± 2.4 Ma and 420.0 ± 3.5 Ma for two samples of the Utopia Granite from the central part of the batholith; (3) U-Pb zircon crystallization age of 418.0 ± 2.3 Ma for the Jake Lee Mountain Granite; (4) U-Pb zircon crystallization age of 415.5 ± 2.1 Ma for the Wellington Lake Granite; and (5) U-Pb monazite crystallization age of 413.3 ± 2.1 Ma for the John Lee Brook Granite. The new geochronological together with new and existing geochemical data suggest that the protracted magmatic evolution of the Late Silurian to Early Devonian plutonic rocks is related to the transition of the Silurian Kingston arc-Mascarene backarc system from an extensional to compressional tectonic environment during collision of the Avalonian microcontinent with Laurentia followed by slab break-off. 

scholarly journals U-Pb (zircon) age, petrology, and tectonic setting of the Canaan River pluton, southeastern New Brunswick, Canada

2018 ◽  
pp. 389-408
Author(s):  
Susan Johnson ◽  
Sandra M. Barr ◽  
Deanne Van Rooyen ◽  
Chris E. White
Keyword(s):  
New Brunswick ◽  
Tectonic Setting ◽  
Leading Edge ◽  
Borehole Data ◽  
Zircon Age ◽  
Early Devonian ◽  
Icp Ms ◽  
Laurentian Margin ◽  
Radiometric Data

 The Canaan River pluton comprises megacrystic monzogranite and quartz diorite to monzodiorite that is exposed in several small inliers on the Carboniferous New Brunswick Platform west of Moncton in southeastern New Brunswick. Its distinct geophysical signature and borehole data suggest that the Canaan River pluton is part of a large buried felsic to mafic intrusive body that lies at relatively shallow depths beneath flat-lying Pennsylvanian sandstone on the platform. New laser ablation ICP-MS in situ analysis of the megacrystic monzogranite yielded a U-Pb zircon concordia age of 412.6 ± 2.1 Ma, indicating that the intrusion is of Early Devonian (upper Lochkovian) age.The new radiometric data along with lithological, geochemical, and isotopic data suggest that the Canaan River pluton is most like the megacrystic Hawkshaw Granite of upper Lochkovian age in the Pokiok Batholith in southwestern New Brunswick. The similarities shown by these granites suggests that they may have been generated in the same complex tectonomagmatic setting related to the successive arrival of the leading edge of Ganderia and Avalonia at the composite Laurentian margin during the Salinic and Acadian orogenies. 

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