The effect of filtration size on the geochemistry of groundwater samples from a massive sulfide deposit at the Bathurst Mining Camp, New Brunswick, Canada

In hydrogeochemical studies, samples are commonly filtered to limit the fraction of analyte that is adsorbed or structurally bound to suspended particles, ensuring that only the dissolved fraction is analyzed, and thereby reducing analytical bias during measurement. The standard filter size that has been adopted is 0.45 μm, however, ultrafiltration can be used to remove colloidal particles two orders of magnitude smaller. In the following, we investigate the effect that standard (0.45 μm) and ultrafiltration (0.004 μm) have on the hydrogeochemistry of groundwaters from a volcanogenic massive sulfide (VMS) deposit at the Bathurst Mining Camp, New Brunswick, Canada. Groundwater samples were collected from six monitoring wells at the Nigadoo Mine tailings facility, and major and trace geochemistry were determined using a combination of inductively coupled plasma optical emission spectrometry (ICP-OES), inductively coupled plasma mass spectrometry (ICP-MS), and ion chromatography. Waters at the Nigadoo deposit are generally enriched in Ca and SO4, relative to other major cations and anions. Some element contents - including those associated with VMS deposits - differ depending on the filtration technique used (e.g., As, Fe, Pb, rare earth elements and yttrium [REY]), some are equally affected by both techniques (e.g., Cu, Ni, Zn), and some are unaffected by filtration (e.g., Ba, Ca, Mn, Cl-). Shale-normalized REY anomalies (CeSN/CeSN*, EuSN/EuSN*, and YSN/HoSN) and overall patterns can differ greatly (e.g., changing the sign of the anomaly) depending on the filtration technique used. We observe previously undocumented, and, at this time, unexplainable fractionation of Ho and Yb (non-redox sensitive REYs, unaffected by the tetrad effect) in unfiltered waters from the Nigadoo deposit. Differences in groundwater geochemistry induced by filtration technique can result in false positive and negative anomalies during environmental and exploration projects and must therefore be carefully considered. At the Nigadoo site, oxidation of sulfide minerals can occur, resulting in the formation of relatively unstable oxide minerals. Away from the tailings, where carbonate minerals are scarce and can no longer act as a pH buffer, the unstable oxide minerals break down and release metals and metalloids into the surrounding environment. The filtration methods used in this study can provide insight into where the specific metals and metalloids are hosted and how they are likely to behave under different redox conditions. Because VMS deposit pathfinder elements are enriched in unfiltered water, and differ by degree of filtration, geochemical analysis of the filtride material may also make an effective exploration tool.Thematic collection: This article is part of the Hydrochemistry related to exploration and environmental issues collection available at: https://www.lyellcollection.org/cc/hydrochemistry-related-to-exploration-and-environmental-issues

Great Mining Camps of Canada 8. The Bathurst Mining Camp, New Brunswick, Part 2: Mining History and Contributions to Society

In the Bathurst Mining Camp (BMC), 12 of the 45 known massive sulphide deposits were mined between 1957 and 2013; one was mined for iron prior to 1950, whereas three others had development work but no production. Eleven of the deposits were mined for base metals for a total production of approximately 179 Mt, with an average grade of 3.12% Pb, 7.91% Zn, 0.47% Cu, and 93.9 g/t Ag. The other deposit was solely mined for gold, present in gossan above massive sulphide, producing approximately one million tonnes grading 1.79 g/t Au. Three of the 11 mined base-metal deposits also had a gossan cap, from which gold was extracted. In 2012, the value of production from the Bathurst Mining Camp exceeded $670 million and accounted for 58 percent of total mineral production in New Brunswick.Base-metal production started in the BMC in 1957 from deposits at Heath Steele Mines, followed by Wedge in 1962, Brunswick No. 12 in 1964, Brunswick No. 6 in 1965, Caribou in 1970, Murray Brook, Stratmat Boundary and Stratmat N-5 in 1989, Captain North Extension in 1990, and lastly, Half Mile Lake in 2012. The only mine in continuous production for most of this time was Brunswick No. 12. During its 49-year lifetime (1964–2013), it produced 136,643,367 tonnes of ore grading 3.44% Pb, 8.74% Zn, 0.37% Cu, and 102.2 g/t Ag, making it one of the largest underground base-metal mines in the world.The BMC remains important to New Brunswick and Canada because of its contributions to economic development, environmental measures, infrastructure, mining innovations, and society in general. The economic value of metals recovered from Brunswick No. 12 alone, in today’s prices exceeds $46 billion. Adding to this figure is production from the other mines in the BMC, along with money injected into the local economy from annual exploration expenditures (100s of $1000s per year) over 60 years. Several environmental measures were initiated in the BMC, including the requirement to be clean shaven and carry a portable respirator (now applied to all mines in Canada); ways to treat acid mine drainage and the thiosalt problem that comes from the milling process; and pioneering studies to develop and install streamside-incubation boxes for Atlantic Salmon eggs in the Nepisiguit River, which boosted survival rates to over 90%. Regarding infrastructure, provincial highways 180 and 430 would not exist if not for the discovery of the BMC; nor would the lead smelter and deep-water port at Belledune. Mining innovations are too numerous to list in this summary, so the reader is referred to the main text. Regarding social effects, the new opportunities, new wealth, and training provided by the mineral industry dramatically changed the living standards and social fabric of northern New Brunswick. What had been a largely poor, rural society, mostly dependent upon the fishing and forestry industries, became a thriving modern community. Also, untold numbers of engineers, geologists, miners, and prospectors `cut their teeth’ in the BMC, and many of them have gone on to make their mark in other parts of Canada and the world.

Great Mining Camps of Canada 7. The Bathurst Mining Camp, New Brunswick, Part 1: Geology and Exploration History

The Bathurst Mining Camp of northern New Brunswick is approximately 3800 km2 in area, encompassed by a circle of radius 35 km. It is known worldwide for its volcanogenic massive sulphide deposits, especially for the Brunswick No. 12 Mine, which was in production from 1964 to 2013. The camp was born in October of 1952, with the discovery of the Brunswick No. 6 deposit, and this sparked a staking rush with more hectares claimed in the province than at any time since. In 1952, little was known about the geology of the Bathurst Mining Camp or the depositional settings of its mineral deposits, because access was poor and the area was largely forest covered. We have learned a lot since that time. The camp was glaciated during the last ice age and various ice-flow directions are reflected on the physiographic map of the area. Despite abundant glacial deposits, we now know that the camp comprises several groups of Ordovician predominantly volcanic rocks, belonging to the Dunnage Zone, which overlie older sedimentary rocks belonging to the Gander Zone. The volcanic rocks formed during rifting of a submarine volcanic arc on the continental margin of Ganderia, ultimately leading to the formation of a Sea of Japan-style basin that is referred to as the Tetagouche-Exploits back-arc basin. The massive sulphide deposits are mostly associated with early-stage, felsic volcanic rocks and formed during the Middle Ordovician upon or near the sea floor by precipitation from metalliferous fluids escaping from submarine hot springs. The history of mineral exploration in the Bathurst Mining Camp can be divided into six periods: a) pre-1952, b) 1952-1958, c) 1959-1973, d) 1974-1988, and e) 1989-2000, over which time 45 massive sulphide deposits were discovered. Prior to 1952, only one deposit was known, but the efforts of three men, Patrick (Paddy) W. Meahan, Dr. William J. Wright, and Dr. Graham S. MacKenzie, focused attention on the mineral potential of northern New Brunswick, which led to the discovery of the Brunswick No. 6 deposit in October 1952. In the 1950s, 29 deposits were discovered, largely resulting from the application of airborne surveys, followed by ground geophysical methods. From 1959 to 1973, six deposits were discovered, mostly satellite bodies to known deposits. From 1974 to 1988, five deposits were found, largely because of the application of new low-cost analytical and geophysical techniques. From 1989 to 2000, four more deposits were discovered; three were deep drilling targets but one was at surface. RÉSUMÉLe camp minier de Bathurst, dans le nord du Nouveau-Brunswick, s’étend sur environ 3 800 km2 à l’intérieur d’un cercle de 35 km de rayon. Il est connu dans le monde entier pour ses gisements de sulfures massifs volcanogènes, en particulier pour la mine Brunswick n° 12, exploitée de 1964 à 2013. Le camp est né en octobre 1952 avec la découverte du gisement Brunswick n° 6 et a suscité une ruée au jalonnement sans précédent avec le plus d’hectares revendiqués dans la province qu’à présent. En 1952, on savait peu de choses sur la géologie du camp minier de Bathurst ou sur les conditions de déposition de ses gisements minéraux, car l’accès était très limité et la zone était en grande partie recouverte de forêt. Nous avons beaucoup appris depuis cette période. Le camp était recouvert de glace au cours de la dernière période glaciaire et diverses directions d’écoulements glaciaires sont révélées sur la carte physiographique de la région. Malgré des dépôts glaciaires abondants, nous savons maintenant que le camp comprend plusieurs groupes de roches ordoviciennes à prédominance volcanique, appartenant à la zone Dunnage, qui recouvrent de plus vieilles roches sédimentaires de la zone Gander. Les roches volcaniques se sont formées lors du rifting d’un arc volcanique sous-marin sur la marge continentale de Ganderia, ce qui a finalement abouti à la formation d’un bassin de type mer du Japon, appelé bassin d’arrière-arc de Tetagouche-Exploits. Les gisements de sulfures massifs sont principalement associés aux roches volcaniques felsiques de stade précoce et se sont formés au cours de l’Ordovicien moyen sur ou proche du plancher océanique par la précipitation de fluides métallifères s’échappant de sources chaudes sous-marines. L’histoire de l’exploration minière dans le camp minier de Bathurst peut être divisée en six périodes: a) antérieure à 1952, b) 1952-1958, c) 1959-1973, d) 1974-1988 et e) 1989-2000, au cours desquelles 45 dépôts de sulfures massifs ont été découverts. Avant 1952, un seul dépôt était connu, mais les efforts de trois hommes, Patrick (Paddy) W. Meahan, William J. Wright et Graham S. MacKenzie, ont attiré l’attention sur le potentiel minier du nord du Nouveau-Brunswick, ce qui a conduit à la découverte du gisement Brunswick n° 6 au mois d’octobre 1952. Dans les années 50, 29 gisements ont été découverts, résultant en grande partie de l’utilisation de levés aéroportés, suivis de campagnes géophysiques terrestres. De 1959 à 1973, six gisements ont été découverts. Ce sont essentiellement des formations satellites de gisements connus. De 1974 à 1988, cinq gisements ont été découverts, principalement grâce à l’utilisation de nouvelles techniques analytiques et géophysiques peu coûteuses. De 1989 à 2000, quatre autres gisements ont été découverts. Trois étaient des cibles de forage profondes, mais l’un était à la surface.

Borehole magnetic surveys in weakly magnetic sediments (Chicxulub impact crater) versus strongly magnetic volcanics (Bathurst mining camp)

Borehole navigation surveys performed using a triaxial fluxgate magnetometer record the change in orientation of the magnetic vector versus depth. Variations in the orientation of the magnetic vector arise from either on- or off-hole magnetic sources. On-hole magnetic sources associated with magnetic property fluctuations in the immediate wall of the borehole (i.e., susceptibility) and (or) remanence polarity changes produce sharp-edged anomalies. Off-hole magnetic sources, caused by a magnetic body near, but not penetrated by, the borehole, produce broad smooth anomalies. Prior to the interpretation of borehole magnetic anomaly logs, data corrections must be applied. Data from each of the magnetic and tiltmeter sensors must be corrected for differential gain, base value offset, and nonorthogonality. By using a probe with two sets of triaxial fluxgates, it is possible to detect along hole magnetic field rotations, which compromise the borehole navigation calculations. After rotation into geographic coordinate space, borehole vector magnetic data from the Chicxulub impact crater in Mexico showed no evidence for any systematic change of magnetic property versus depth. What was originally interpreted as reversal stratigraphy has proved to be minor changes in borehole geometry. Borehole magnetic data from a borehole through the Stratmat deposit, located in the Bathurst mining camp, New Brunswick, show strong off-hole and on-hole anomalies associated with the pyrrhotite-rich ore bodies.

The Bathurst Mining Camp, New Brunswick: data integration, geophysical modelling, and implications for exploration

The Bathurst Mining Camp (BMC) is one of Canada’s oldest mining districts for volcanogenic massive sulphide (VMS) deposits. Most of the 46 known deposits were discovered in the 1950s using a combination of geological and geophysical methods. However, renewed exploration efforts over the past 15 years have not been as successful as one would expect given the level of expenditure of the camp. Nevertheless, this has created a large database of high resolution airborne geophysical data (magnetics, electromagnetics, radiometrics, and full tensor gravity gradiometry) which makes Bathurst a unique case. We show data compilation and map view interpretation, followed by two-and-a-half-dimensional (2.5D) gravity and magnetic modelling. From this, we provide constraints on the folded structure of the mafic and felsic volcanic units, and we interpret a large gravity anomaly in the southeast as a possible ophiolite or a dense thick package of basaltic rocks. Finally, we show an example of 3D modelling in the northwestern part of the camp, where we combine map view interpretation with section-based modelling and 3D geophysical inversion.

Applying laterally varying density corrections to ground gravity and airborne gravity gradiometry data: a case study from the Bathurst Mining Camp

The influence of topography on gravity and gravity gradiometry measurements is profound and should be minimized prior to geological interpretation. The standard way of minimizing these effects is through the computation of a terrain correction. Terrain corrections require two inputs: topography and density. Often, geology and topography are inextricably intertwined: topography is caused by a change in geology. In geologic environments where there is a structural and (or) stratigraphic control on the near-surface mass distribution, using a single density value in the corrections leads to removal of the topographic effect of rocks having the chosen density. Any remaining gravity signal that correlates with topography is providing geological information. If the objective is to produce a gravity map with minimal topographic signal, then a regionally variable density correction is a means of compensating for this effect. In this paper, we demonstrate how to apply a spatially variable density correction using ground gravity and airborne gravity gradiometry data for the geologically complex Bathurst Mining Camp, northern New Brunswick, Canada. Ground gravity and airborne full tensor gravity gradiometry measurements are subdivided into a series of domains on the basis of the underlying tectonostratigraphic group. Terrain and Bouguer corrections are calculated for each domain using representative density values obtained from drill core and surface sampling throughout the Bathurst Mining Camp. The output from the spatially variable density correction is then compared with previous maps. Overall, the differences are subtle, but the spatially variably density allows for isolated anomalies to be better resolved.

Chlorite-White Mica Pairs’ Composition as a Micro-Chemical Guide to Fingerprint Massive Sulfide Deposits of the Bathurst Mining Camp, Canada

The compositions of phyllosilicates, with a focus on fluid-mobile elements, were evaluated as a means to fingerprint the Middle Ordovician metamorphosed (greenschist facies) volcanogenic massive sulfide deposits of the Bathurst Mining Camp (BMC), Canada. Ninety-five drill-core samples from six of the major deposits of the Bathurst Mining Camp (Brunswick No. 12, Heath Steele B zone, Halfmile Lake Deep zone, Key Anacon East zone, Louvicourt, and Restigouche) were analyzed using electron microprobe and laser ablation inductively coupled plasma-mass spectrometry. Typically, phyllosilicates (chlorite, white mica, and to a lesser extent biotite) are ubiquitous phases in the host rocks of the massive sulfide deposits of the BMC. Electron microprobe analysis results show a wide compositional variation in chlorite and white mica. Laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis was performed to measure fluid-mobile elements, showing that Tl is distinctly enriched in all white mica (up to 719 ppm) relative to chlorite (up to 50.1 ppm). Chlorite hosts Sn (up to 4600 ppm), Hg (up to 7.3 ppm), Sb (up to 35.4 ppm), As (up to 1320 ppm), In (up to 307 ppm), Cd (up to 83.2 ppm), and Se (up to 606 ppm). White mica hosts Sn (up to 1316 ppm), Hg (up to 93 ppm), Sb (up to 1630 ppm), As (up to 14,800 ppm), In (up to 1186 ppm), Cd (up to 98 ppm), and Se (up to 38.8 ppm). Limited LA-ICP-MS analysis on biotite indicates a higher overall concentration of Tl (mean = 14.6 ppm) relative to co-existing white mica (mean = 2.18 ppm). On average, biotite is also more enriched in Hg, Sn, and Ba relative to chlorite and white mica. Laser Ablation ICP-MS profiles of chlorite, white mica, and biotite demonstrate smooth time-dependent variations diagnostic of structural substitution of these elements. Compositional variation of chlorite-white mica pairs presented in the current study shows systematic variations as a function of distance from the mineralized horizons. This highlights the potential to use trace-element signatures in these phyllosilicate pairs to identify proximal (chlorite) and distal (white mica) footprints for volcanogenic massive sulfides exploration.