scholarly journals Effects of Pyrite Texture on Flotation Performance of Copper Sulfide Ores

Minerals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1218
Author(s):  
İlkay B. Can ◽  
Seda Özçelik ◽  
Zafir Ekmekçi
Keyword(s):  
Copper Sulfide ◽  
Surface Cleaning ◽  
Copper Recovery ◽  
Sulfide Ores ◽  
Copper Ore ◽  
Ore Deposit ◽  
Framboidal Pyrite ◽  
Process Plant ◽  
Flotation Performance ◽  
Flotation Behavior

Pyrite particles, having framboidal/altered texture, are known to significantly affect pulp chemistry and adversely affect flotation performance. Therefore, the main objectives of this study were to demonstrate influence of pyrite mineralogy on the flotation of copper (sulphidic) ores and develop alternative conditions to improve the performance. Two copper ore samples (Ore A and Ore B) having different textural/modal mineralogy and flotation characteristics were taken from different zones of the same ore deposit. Ore B contained framboidal pyrite and altered pyrite/marcasite, which is considered the main reason for the low flotation performance in both copper and pyrite flotation sections of the process plant. Flotation tests were conducted under different conditions using the two ore samples and a 50:50 blend. The results showed that Ore A could be concentrated under the base conditions, as applied in the existing flotation plant. On the other hand, Ore B did not respond to the base conditions and a copper recovery of only 5% could be obtained. Besides, blending Ore B with Ore A negatively affected the flotation behavior of Ore A. An alternative flotation chemistry was applied on Ore B using Na2S for surface cleaning and Na-Metabisulfite (MBS) for pyrite depression in the copper flotation stage. The surface cleaning reduced the rate of oxidation of the framboidal pyrite in Ore B. As a result, the copper recovery could be increased to 52% Cu for Ore B, and 65% for the mixed ore sample.

Primary Copper Ore Leaching by Leaching Solution Adjusted Oxidation-Reduction Potential in Column

2015 ◽  
Vol 1130 ◽  
pp. 355-358
Author(s):  
Tatsuya Shinkawa ◽  
Taro Kamiya ◽  
Kazuhiro Kojima ◽  
Tadashi Chida
Keyword(s):  
Sulfuric Acid ◽  
Recovery Rate ◽  
Copper Sulfide ◽  
Copper Recovery ◽  
Copper Ore ◽  
Column Leaching ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
Copper Leaching ◽  
Leaching Solution

Copper ore is classified into three groups; primary copper sulfide, copper oxide and secondary copper sulfide. Leaching copper from primary copper sulfide, such as chalcopyrite, with sulfuric acid takes longer time than from copper oxide and secondary copper sulfide. As such, an oxidant is required to extract copper from chalcopyrite. In this study, column leaching tests were carried out using primary copper sulfide ores produced in an iron oxide copper gold (IOCG) deposit and rich in iron in coparison to porphyry copper ores. The columns of 10 cm diameter and 100 cm long had a double tube structure so that the column temperature can be kept at desired temperature by circulating warm water in the outer tube. The oxidation-reduction potential (ORP) of the leaching solutions were adjustedto 400, 450 and 500 mV vs Ag/AgCl. The column leaching test using just pH 2.0 sulfuric acid without adjustment of ORP at 45 °C got a copper recovery rate of 37 % in 400 days. On the other hand, with ORP adjusted leaching solutions of pH 2.0 sulfuric acid containing 500 mg/L Fe, the copper recovery rate reached up to 87 % in 400 days.In addition, it was necessary to keep the temperature above 45 oC to enhance copper leaching by ORP adjusted leaching solution. The result of the column leaching test at room temperature (around 30 °C) using ORP adjusted leaching solution shows that the recovery rate of copper is lower than the result at 45 °C. The ORP adjustment of leaching solution is effective for leaching copper from primary copper sulfide ore, however, the leaching temperature needs to be kept above 45 °C. As a result, it makes clear that copper leaching is enhanced by utilization of ORP adjusted leaching solutions and suggests that the solution ORP control is important to the application of bioleaching.

scholarly journals Parametric Optimization in Rougher Flotation Performance of a Sulfidized Mixed Copper Ore

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 660 ◽  
Author(s):  
Asghar Azizi ◽  
Mojtaba Masdarian ◽  
Ahmad Hassanzadeh ◽  
Zahra Bahri ◽  
Tomasz Niedoba ◽  
...  
Keyword(s):  
Parametric Optimization ◽  
Goal Function ◽  
Copper Recovery ◽  
Critical Parameters ◽  
Agitation Rate ◽  
Methyl Isobutyl ◽  
Copper Ore ◽  
Effective Factors ◽  
Flotation Cell ◽  
Flotation Performance

The dominant challenge of current copper beneficiation plants is the low recoverability of oxide copper-bearing minerals associated with sulfide type ones. Furthermore, applying commonly used conventional methodologies does not allow the interactional effects of critical parameters in the flotation processes to be investigated, which is mostly overlooked in the literature. To tackle this issue, the present paper aimed at characterizing the behavior of five key effective factors and their interactions in a sulfidized copper ore. In this context, dosage of collector (sodium di-ethydithiophosphate, 60–100 g/t), depressant (sodium silicate, 80–120 g/t) and frother (methyl isobutyl carbinol (MIBC), 6–10 g/t), pulp pH (7–11) and agitation rate (900–1300 rpm) were examined and statistically analyzed using response surface methodology. Flotation experiments were conducted in a Denver type agitated flotation cell at the rougher stage. The experimental results showed that increasing the pH (from 8 to 10) at low agitation rate (1000 rpm) enhanced the recovery from 80.36% to 85.22%, while at high agitation rate (1200 rpm), a slight declination occurred in the recovery. Meanwhile, increasing the collector dosage at a lower frother value (7 g/t), caused a reduction of about 4.44% in copper recovery owing to the interactions between factors, whereas at a higher frother level (9 g/t), the recovery was almost unchanged. The optimization process was also performed using the goal function approach, and maximum copper recovery of 92.75% was obtained using ~70 g/t collector, 110 g/t depressant, 7 g/t frother, pulp pH of 10 and 1000 rpm agitation rate.

Experimental Study of Floatation on Non-Independent Copper Oxide Ore from Jilin Province in China

2012 ◽  
Vol 581-582 ◽  
pp. 851-855
Author(s):  
Rong Dong Deng ◽  
Quan Jun Liu ◽  
Xiao Feng Yang ◽  
Ting Hu ◽  
Feng Hong Ye
Keyword(s):  
Copper Oxide ◽  
Copper Sulfide ◽  
Jilin Province ◽  
High Grade ◽  
High Recovery ◽  
Copper Ore ◽  
Sulfide Ore ◽  
Mineralogical Study ◽  
Oxide Minerals ◽  
Copper Sulfide Ore

Through the processing of mineralogical study on a copper ore from Jilin province in China, it found that the copper exist mostly with the form of chalcopyrite, and others exist with the form of copper oxide minerals which with complex ingredient. The copper oxide minerals are due to the altered of the edge of chalcopyrite, and have not formed the independent copper oxide ore. It belongs to unconventional hard-to-beneficiate copper ore. Coarse grinding fineness and bulk floatation was used to recover the copper oxide ore and copper sulfide ore by using amino double phosphoric acid and butylamine dithiophosphate as the collector. This process was similar to the carrier flotation and achieved an effective processing of the copper oxide ore and obtained a high-grade copper concentrate assaying 15.8% with a high recovery of 82.4%.

Bioleaching of Low-Grade Copper Sulfide Ore Using a Colum Reactor

2009 ◽  
Vol 71-73 ◽  
pp. 409-412
Author(s):  
Wen Qing Qin ◽  
Yan Sheng Zhang ◽  
Shi Jie Zhen ◽  
Jun Wang ◽  
Jian Wen Zhang ◽  
...  
Keyword(s):  
Iron Concentration ◽  
Mixed Cultures ◽  
Copper Recovery ◽  
Low Grade ◽  
Leaching Rate ◽  
Ministry Of Education ◽  
Copper Ore ◽  
Copper Leaching ◽  
Pure Cultures ◽  
Mixed Bacteria

The effects of several variables on the column bioleaching of copper sulphide ore have been investigated. The copper ore contained chalcopyrite as the main sulfide minerals and bornite and chalcocite as the minor minerals. The experiment was carried out using bench-scale column leach reactors designed in Key Lab of Biometallurgy of Ministry of Education, which were inoculated with the pure mesophile bacteria (Acidithiobacillus ferrooxidans) and thermophile bacteria (Sulfobacillus), respectively, and the mixed bacteria which contain both iron- and sulfur-oxidizing bacteria. The results show that the mixed cultures were more efficient than the pure cultures alone and the maximum copper recovery 53.64% was achieved using the mixed cultures after 85 days. The leaching rate of chalcopyrite tended to increase with the increased dissolved ferric iron concentration. The effect of particle size on the rate of the copper leaching was also investigated, and it was shown that the copper bioleaching rate decreases as the amount of fines increase, which limits the permeability, thus decreases leaching rate. Jarosite and elemental sulphur formed in the column were characterized by the X-ray and EDS.

Influence of particle size on copper recovery from sulfide ore by the moderately thermophilic microorganisms

2019 ◽  
Vol 116 (1) ◽  
pp. 119
Author(s):  
Wen-bo Zhou ◽  
Kai Li ◽  
Yu-guang Wang ◽  
Li-juan Zhang ◽  
Hai-na Cheng ◽  
...  
Keyword(s):  
Particle Size ◽  
Xrd Analysis ◽  
Microbial Interactions ◽  
Copper Recovery ◽  
Mineral Particle ◽  
Copper Ore ◽  
Thermophilic Microorganisms ◽  
Moderately Thermophilic ◽  
Before And After ◽  
Leaching Condition

The bioleaching of copper ore by the defined moderately thermophilic consortium containing Leptospirillum ferriphilum and Acidithiobacillus caldus was carried out in the bench-scale column. Bioleaching experiments showed that the leaching rate was 25% higher than that of a conventional leaching and the acid consumption was reduced by 33% at the optimal leaching condition. Meanwhile, the effect of different particle sizes on the rate of the copper leaching was also investigated, and it was shown that the particle size affects the bioleaching rate significantly in the range of 5–25 mm, in which approximately 89.27% of copper was extracted at 5–10 mm, while only 57.08% at 15–25 mm. The results obtained by X-ray diffraction (XRD) analysis of the mineral samples before and after microbial and chemical leaching revealed that the decrease in particle size of the minerals resulted in an enhancement of complex microbial interactions. Especially for the particle size of 5–10 mm, a significant amount of elemental sulfur and jarosite formed on the surface of the mineral, while it was further confirmed that critical microbe-mineral interactions have taken place on the mineral surface. The results indicated that mineral particle size is an integral factor to improve the copper recovery from ore in heap leaching operation. This will provide a reference to the heap construction for the bioleaching.

Major and minor element lithogeochemical anomalies surrounding the Louvem copper deposit, Val d'Or, Quebec

1978 ◽  
Vol 15 (7) ◽  
pp. 1161-1169 ◽  
Author(s):  
Guy Spitz ◽  
Richard Darling
Keyword(s):  
Major Element ◽  
Copper Deposit ◽  
Longitudinal Direction ◽  
Minor Element ◽  
Copper Ore ◽  
Ore Deposit ◽  
Chemical Zoning ◽  
Practical Tool ◽  
Volcanogenic Deposits ◽  
Alteration Pattern

Major element distributions in meta-rhyodacitic flows and fragmental rocks surrounding the Louvem volcanogenic copper deposit show a broad linear anomaly parallel to the local strike. At least 420 m long and up to 210 m wide, this altered area contains rocks that have high Fe+2, S, and low Na2O, CaO, and CO2 values. Included in the central portion of this large anomaly is a 100 m by 50 m highly altered area that contains rocks with high H2O and MgO values and crudely outlines the ore deposit.Element-ratio maps and a map showing percentage peraluminous character all display easily recognizable anomalies that mark the zone of altered rocks enclosing the ore deposit. Of the element ratios investigated at Louvem, Al2O3/Na2O appears to offer the most practical tool for mineral exploration.The chemical zoning of the altered fragmental layer that includes the copper ore is symmetrical about the long axis of the stratigraphically concordant orebody, but in a longitudinal direction this symmetry is absent. Instead, the alteration changes progressively from dominantly chloritic at the western end to pyritic at the eastern end of the study area. This alteration pattern seems to suggest that ore deposition was effected by hydrothermal solutions moving along the layer of now-altered fragmental rocks. By analogy with the chloritic alteration pipes underlying pyritic volcanogenic deposits, it seems probable that the direction of fluid flow was from west to east.

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