scholarly journals Microwave and Ultrasound Effect on Ammoniacal Leaching of Deep-Sea Nodules

Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 351
Author(s):  
Anna Knaislová ◽  
Hong Vu ◽  
Petr Dvořák

The influence of ultrasound and microwaves on extraction of copper, nickel, and cobalt from manganese deep-sea nodules by reductive ammoniacal leaching in the presence of ammonium thiosulfate as a reducing agent was studied. The ultrasonic ammoniacal leaching provides higher metals extraction, while the effect of microwaves on the metals extraction under the studied leaching conditions is insignificant. In general, increasing leaching temperature increases significantly extraction of the metals of interest. At high temperatures, extraction efficiencies of copper, nickel, and cobalt decrease over longer leaching duration as a result of decomposition of the metals amino-complexes and reverse precipitation of metals. However, during the ultrasonic leaching at a temperature of 85 °C, the extraction of nickel remains almost unchanged over longer leaching durations and does not follow the decreasing course, observed in the extraction of copper and cobalt. The finding suggests that nickel can be selectively extracted from the nodules by the ultrasonic leaching. The maximal extraction efficiency of copper, nickel, and cobalt was 83%, 71%, and 32%, respectively, when the reductive ultrasonic ammoniacal leaching was carried out at 85 °C for 90 min. In the presence of microwaves, the maximal extraction efficiency of copper, nickel, and cobalt was 67%, 48%, and 8%, respectively, when the reductive ultrasonic ammoniacal leaching was carried out at the output power of 60 W for 210 min.

2014 ◽  
Vol 152 ◽  
pp. 407-413 ◽  
Author(s):  
Ulker D. Keris-Sen ◽  
Unal Sen ◽  
Gulfem Soydemir ◽  
Mirat D. Gurol

2012 ◽  
Vol 24 (5) ◽  
pp. 1033-1037
Author(s):  
张骁 Zhang Xiao ◽  
刘文广 Liu Wenguang

1999 ◽  
Vol 53 (1) ◽  
pp. 45-56 ◽  
Author(s):  
R.K. Jana ◽  
B.D. Pandey ◽  
Premchand

2004 ◽  
Vol 831 ◽  
Author(s):  
Hideki Kasugai ◽  
Yasuto Miyake ◽  
Akira Honshio ◽  
Takeshi Kawashima ◽  
Kazuyoshi Iida ◽  
...  

ABSTRACTNitride-based blue-light-emitting diodes having a moth-eye structure were fabricated on the backside of a 6H-SiC substrate. The light extraction efficiency and the corresponding output power were increased by 3.8 times compared with those of an LED having the conventional structure. The results of theoretical analysis agree with these findings.


1972 ◽  
Vol 72 (1) ◽  
pp. 193-206 ◽  
Author(s):  
J. Robert Moore

SynopsisAlthough we may consider the insular phosphate mining interest of John Murray as one of the initial efforts in exploiting ocean-related mineral resources, only in the past decade has a concerted effort been made to mine the sea floor. At this time, commercial recovery of copper, nickel and cobalt from deep-sea ferro-manganese nodules is rapidly approaching reality, and the mining of newly discovered noble and base metal placers and lodes beneath shallow coastal waters is already in early commercial development. While some entrepreneurs, and certain member states of the United Nations, have expressed overly optimistic views, the projected growth trend of the infant ocean minerals industry does point to truly large-scale undersea mining by the end of the 1980s. The chief constraints include lack of legal protection for deep-sea operators, a need for further research on the origin of shelf placer deposits, limited trained personnel for exploration and insufficient risk capital to sustain long-term exploration, particularly in unexplored coastal areas of politically unstable states.In terms of meeting the exploratory and engineering needs of the next two decades, we must initiate extensive research on (1) high- and low-energy marine placers, (2) direct metal sensing systems,(3) new sampling tools for rapid economic evaluation of underwater prospects and on (4) the design and development of unmanned sea-floor mining and processing machines which are highly efficient and yet do not degrade the environment.Legal, political and social problems must also be overcome by providing laws for (1) mining in international waters, (2) for conservation of resources, (3) for protection of the marine environment, including inland seas, and (4) by directing early attention to the related socio-economic problems of employment and labour.Of timely concern is providing the highly specialised education required of marine minerals explorationists and mining engineers, and training for sea-going technologists. Specific recommendations for solving these several problems are presented and discussed, including interdisciplinary,multi-nation co-operation.Based on recent studies, predictions for the expansion of ocean minerals extraction during the remainder of this century are presented. The periods 1970-80, 1980-90 and 1990-2000 are reviewed to show the projected early successes of copper, nickel and cobalt recovery from deep-sea nodules by 1975, the introduction of large-scale shelf mining of noble and base metal deposits by 1980, the use of unmanned sea-floor mining systems by 1990, and the major shift to marine base metal resources by the year 2000.Based on contemporary studies at the University of Wisconsin, mineral prospects in waters off Canada, Norway, Alaska, USSR, Greenland and Malagasy are presented, as are prospective sites on the mid-ocean ridge and beneath the North American Great Lakes. These prospects relate to copper, rare earths, gold, platinum, uranium and base metal sulfides.Opportunities for participation by emerging nations in ocean minerals are many, including encouragement of exploration in sovereign waters, participating in exchange student training programmes, and revising tax laws to allow broader economic incentives which will, in time, provide commerce, revenue and, most importantly, employment for nationals.


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