scholarly journals Mineralogical and Geochemical Features of Cretaceous Bauxite from San Giovanni Rotondo (Apulia, Southern Italy): A Provenance Tool

Minerals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 567 ◽  
Author(s):  
Rosa Sinisi

In this study, the mineralogical and chemical compositions of bauxite from San Giovanni Rotondo (SGR) on the Gargano Promontory (northern Apulia, Italy) are presented and discussed with the aim of assessing the nature of its source material. Bauxite from the SGR, which is known as the “Montecatini mine”, was exploited intensively until the 1970s to recover alumina. As with most of the autochthonous peri-Mediterranean bauxites, the studied deposit is a karst bauxite with a massive, matrix-supported texture and an oolitic structure. Boehmite and hematite are the main mineral phases, and anatase, rutile, and kaolinite are present in lesser amounts along with detrital zircons and monazite grains. Calcite is abundant only in the deposit’s lower portion, triggering a significant dilution effect on trace element concentrations. However, with respect to the average crust and chondrite compositions, strong enrichments of trace metals (up to 10X Upper Continental Crust’s (UCC)) and rare earth elements (REEs, up to 800X chondrite) exist throughout the studied deposit. The distribution of REEs, the (La/Yb)N and Eu/Eu* ratios, and an Eu/Eu* versus Sm/Nd diagram have been used for determining the bauxite’s provenance. These geochemical proxies point to a parental material consisting of a mixture of distant magmatic and siliciclastic components.

2019 ◽  
Author(s):  
Katherine Jones ◽  
◽  
Daniel J. Lehrmann ◽  
Michele Morsilli ◽  
Khalid Al-Ramadan ◽  
...  

2017 ◽  
Vol 17 (3) ◽  
pp. 467-480 ◽  
Author(s):  
Maria Elena Martinotti ◽  
Luca Pisano ◽  
Ivan Marchesini ◽  
Mauro Rossi ◽  
Silvia Peruccacci ◽  
...  

Abstract. In karst environments, heavy rainfall is known to cause multiple geohydrological hazards, including inundations, flash floods, landslides and sinkholes. We studied a period of intense rainfall from 1 to 6 September 2014 in the Gargano Promontory, a karst area in Puglia, southern Italy. In the period, a sequence of torrential rainfall events caused severe damage and claimed two fatalities. The amount and accuracy of the geographical and temporal information varied for the different hazards. The temporal information was most accurate for the inundation caused by a major river, less accurate for flash floods caused by minor torrents and even less accurate for landslides. For sinkholes, only generic information on the period of occurrence of the failures was available. Our analysis revealed that in the promontory, rainfall-driven hazards occurred in response to extreme meteorological conditions and that the karst landscape responded to the torrential rainfall with a threshold behaviour. We exploited the rainfall and the landslide information to design the new ensemble–non-exceedance probability (E-NEP) algorithm for the quantitative evaluation of the possible occurrence of rainfall-induced landslides and of related geohydrological hazards. The ensemble of the metrics produced by the E-NEP algorithm provided better diagnostics than the single metrics often used for landslide forecasting, including rainfall duration, cumulated rainfall and rainfall intensity. We expect that the E-NEP algorithm will be useful for landslide early warning in karst areas and in other similar environments. We acknowledge that further tests are needed to evaluate the algorithm in different meteorological, geological and physiographical settings.


2021 ◽  
pp. 9-38
Author(s):  
Christopher de Lisle

This chapter provides a narrative overview of Agathokles’ life and career as a foundation for the analytical chapters which follow. The collapse and revival of Syracusan hegemony in Sicily and the rise of Macedon in mainland Greece were the central features of Agathokles’ youth. His rise to dominance in Syracuse in the years preceding 317 BC highlight the difficulties inherent in our source material for his career. This seizure of power resulted in three interlinked wars: against his exiled Syracusan opponents, against the other poleis of eastern Sicily, and eventually against the Carthaginians. Agathokles invaded Africa in 310. Unable to decisively defeat the Carthaginians, he made peace with them in 306, but destroyed his opponents in Sicily. Around 304 BC he assumed the title of king. Subsequently he engaged in campaigns in southern Italy and the Adriatic. An ill-managed succession resulted in the dissolution of his kingdom at his death in 289.


2020 ◽  
Author(s):  
Manuel Pimenta Silva ◽  
Peter Ulmer ◽  
Othmar Müntener

<p>In the southern part of the Adamello Batholith (43-33 Ma; Schaltegger et al., 2019) in Northern Italy (Re di Castello superunit), we identified a multi-generational dyke suite with “exotic” chemical compositions intruding quartz-dioritic units surrounding a gabbroic complex. These dykes are characterised by SiO<sub>2</sub> contents between 43 and 46 wt.%, high Al<sub>2</sub>O<sub>3</sub> (20-21 wt.%), and low MgO and Ni (below 6.5 wt.% and 40 μg/g, respectively), displaying a nepheline-normative character. Furthermore, they exhibit positive Sr and Ba anomalies. These chemical features exclude a possible primitive character or derivation from a typical calc-alkaline liquid line of descent, as identified for the Adamello Massif (Ulmer et al, 2018). The primocrystic cargo of these dikes (clinopyroxene, anorthitic plagioclase, and low-Si, high-Na pargasitic amphibole) displays striking similarities with cumulate crystals of the contiguous Blumone amphibole gabbroic cumulate, inferring mechanical interaction of these exotic liquids with and/or derivation from the cumulate complex. Amphibole-plagioclase equilibration temperatures of the dikes (875 to 775ºC) are consistent with thermal equilibration with the surrounding quartz-dioritic mush. Sharp contacts and dyke fragmentation are also observed and are thermally congruent with the ductile-brittle transition of a quartz-dioritic to tonalitic mush (Marxer & Ulmer, 2019).</p><p>Simple mass balance calculations modelling of the peritectic melting of pargasitic amphibole and high-An plagioclase (major mineral phases of the contiguous amphibole gabbroic cumulates) with simultaneous crystallisation of low-Al clinopyroxene reveal that melt compositions similar to these dykes can be achieved with amphibole-plagioclase proportions ranging between 65:35 and 50:50. To verify if peritectic cumulate remelting represents a possible generation mechanism of these dykes we performed<span>  </span>experiments at 0.2 GPa.</p><p>Established phase equilibria of these dyke compositions reveal a lack of near-liquidus olivine, which is a rare phase in gabbroic complex. This is consistent with preliminary experimental results on cumulate melting, where olivine is also absent at high temperatures (> 1075ºC). These observations further disprove the petrogenesis of these liquids via a calc-alkaline liquid line of descent, where mafic magmas would be early saturated in olivine at low pressure further supporting their generation by local remelting of amphibole-plagioclase dominated mafic cumulates.Geochemical as well as experimental results both strongly point towards the petrogenesis of these nepheline-normative, high-Al, low-Mg picrobasalts by low pressure peritectic melting of a pargasite-anorthite cumulate assemblage in an active magmatic system.</p><p> </p><p>Marxer, F. & Ulmer, P. <em>Contrib Mineral Petr.</em> <strong>174(10)</strong>, 84 (2019).</p><p>Schaltegger, U. <em>et al. J Petrol. </em><strong>60(4)</strong>, 701-722 (2019).</p><p>Ulmer, P. <em>et al. J. Petrol.</em> <strong>59(1)</strong>, 11-58 (2018).</p>


2013 ◽  
Vol 13 (8) ◽  
pp. 3645-3650 ◽  
Author(s):  
Oliver Bierwagen ◽  
André Proessdorf ◽  
Michael Niehle ◽  
Frank Grosse ◽  
Achim Trampert ◽  
...  

2001 ◽  
Vol 697 ◽  
Author(s):  
Ecaterina Vasilescu ◽  
Paula Drob ◽  
Doina Raducanu ◽  
Lucia Angelescu ◽  
Constantin Iliuc

AbstractThe item of the paper is focussed on some bio-compatible coatings for rare earth based permanent magnets, which are used as dental materials for prosthetic devices as retention units. The studied alloy belongs to Nd-Fe-B system with some Dy and Al content. The double-layer coatings had different chemical compositions; first layer: Ag30-Cr70, Co30-Cr70, Stainless Steel and the second layer: titanium nitride (TiN). Data about corrosion behavior, wear resistance and adhesion are presented. The corrosion resistance of these coatings was tested in artificial saliva, using electrochemical potentiostatic and potentiodynamic polarization techniques. The stability in the corrosion media, the localized corrosion susceptibility and the corrosion rates were determined. It resulted that the Nd30-Dy5-Fe-Al0.4-B alloy with Ag30-Cr70 + TiN film is very stable in artificial saliva. The wear behavior of the coatings in different conditions of contact and load was tested, also. The adhesion was determined by scratching test.


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