Equilibrium crystallization of massif-type anorthosite residual melts: a case study from the 1.64 Ga Ahvenisto complex, Southeastern Finland

Fe–Ti–P-rich mafic to intermediate rocks (monzodiorites and oxide–apatite–gabbronorites, OAGNs) are found as small intrusions in most AMCG (anorthosite–magnerite–charnokite–granite) suites. The origin of the monzodioritic rocks is still debated, but in many studies, they are presumed to represent residual liquid compositions after fractionation of anorthositic cumulates. In the 1.64 Ga Ahvenisto complex, SE Finland, monzodioritic rocks occur as minor dike-like lenses closely associated with anorthositic rocks. We report new field, petrographic, and geochemical (XRF, ICP-MS, EMPA) data complemented with crystallization modeling (rhyolite-MELTS, MAGFRAC) for the monzodioritic rocks, apatite–oxide–gabbronorite, and olivine-bearing anorthositic rocks of the Ahvenisto complex. The presented evidence suggest that the monzodioritic rocks closely represent melt compositions while the apatite–oxide–gabbronorite and olivine-bearing anorthositic rocks are cumulates. The monzodioritic rocks seem to form a liquid line of descent (LLD) from primitive olivine monzodiorites to more evolved monzodiorites. Petrological modeling suggests that the interpreted LLD closely corresponds to a residual melt trend left after fractional crystallization (FC) and formation of the cumulate anorthositic rocks and minor apatite–oxide–gabbronorite in shallow magma chambers. Consequent equilibrium crystallization (EC) of separate monzodioritic residual magma batches can produce the observed mineral assemblages and the low Mg numbers measured from olivine (Fo25–45) and pyroxenes (En48–63, Mg#cpx 60–69). The monzodioritic rocks and apatite–oxide–gabbronorites show similar petrological and geochemical characteristics to corresponding rock types in other AMCG suites, and the model described in this study could be applicable to them as well.

Self-cannibalisation of an active cumulate system (Blumone complex, Adamello, Italy): Geochemical and experimental evidence

<p>In the southern part of the Adamello Batholith (43-33 Ma; Schaltegger et al., 2019) in Northern Italy (Re di Castello superunit), we identified a multi-generational dyke suite with “exotic” chemical compositions intruding quartz-dioritic units surrounding a gabbroic complex. These dykes are characterised by SiO<sub>2</sub> contents between 43 and 46 wt.%, high Al<sub>2</sub>O<sub>3</sub> (20-21 wt.%), and low MgO and Ni (below 6.5 wt.% and 40 μg/g, respectively), displaying a nepheline-normative character. Furthermore, they exhibit positive Sr and Ba anomalies. These chemical features exclude a possible primitive character or derivation from a typical calc-alkaline liquid line of descent, as identified for the Adamello Massif (Ulmer et al, 2018). The primocrystic cargo of these dikes (clinopyroxene, anorthitic plagioclase, and low-Si, high-Na pargasitic amphibole) displays striking similarities with cumulate crystals of the contiguous Blumone amphibole gabbroic cumulate, inferring mechanical interaction of these exotic liquids with and/or derivation from the cumulate complex. Amphibole-plagioclase equilibration temperatures of the dikes (875 to 775ºC) are consistent with thermal equilibration with the surrounding quartz-dioritic mush. Sharp contacts and dyke fragmentation are also observed and are thermally congruent with the ductile-brittle transition of a quartz-dioritic to tonalitic mush (Marxer & Ulmer, 2019).</p><p>Simple mass balance calculations modelling of the peritectic melting of pargasitic amphibole and high-An plagioclase (major mineral phases of the contiguous amphibole gabbroic cumulates) with simultaneous crystallisation of low-Al clinopyroxene reveal that melt compositions similar to these dykes can be achieved with amphibole-plagioclase proportions ranging between 65:35 and 50:50. To verify if peritectic cumulate remelting represents a possible generation mechanism of these dykes we performed<span>  </span>experiments at 0.2 GPa.</p><p>Established phase equilibria of these dyke compositions reveal a lack of near-liquidus olivine, which is a rare phase in gabbroic complex. This is consistent with preliminary experimental results on cumulate melting, where olivine is also absent at high temperatures (> 1075ºC). These observations further disprove the petrogenesis of these liquids via a calc-alkaline liquid line of descent, where mafic magmas would be early saturated in olivine at low pressure further supporting their generation by local remelting of amphibole-plagioclase dominated mafic cumulates.Geochemical as well as experimental results both strongly point towards the petrogenesis of these nepheline-normative, high-Al, low-Mg picrobasalts by low pressure peritectic melting of a pargasite-anorthite cumulate assemblage in an active magmatic system.</p><p> </p><p>Marxer, F. & Ulmer, P. <em>Contrib Mineral Petr.</em> <strong>174(10)</strong>, 84 (2019).</p><p>Schaltegger, U. <em>et al. J Petrol. </em><strong>60(4)</strong>, 701-722 (2019).</p><p>Ulmer, P. <em>et al. J. Petrol.</em> <strong>59(1)</strong>, 11-58 (2018).</p>

The role of contamination in the tightrope of Gran Canaria felsic magma differentiation

<p>Peralkaline magmatism is mostly sustained by extensive feldspar fractionation from mafic parents at shallow depths in intraplate settings. In this case, silica saturation is critical as it controls the differentiation trend that a peralkaline magma follows. SiO<sub>2</sub>-oversaturated parents fractionate towards rhyolites, and SiO<sub>2</sub>-undersaturated towards phonolitic compositions. The Miocene post-shield stage of Gran Canaria records both differentiation trends, which has previously been ascribed to changes in the mantle source. Such stage has been divided in the Mogan and Fataga Group based on silica saturation. Here, we propose that contamination plays a key role in the differentiation of Gran Canaria volcanics. This assumption is supported with new <sup>40</sup>Ar/<sup>39</sup>Ar geochronology, mineral, glass and juvenile clast chemistry (oxygen isotopes, major and trace elements) merged with a detailed stratigraphy. Two types of contaminants were identified, one being cogenetic feldspar-dominated cumulates and the second one being sediments within the island crust. We propose that barium-rich trachytic magmas with positive europium anomalies are linked to melting of the feldspar cumulates left after extensive fractional crystallisation. The chemistry of such trachytes does not follow a liquid line of descent and contains reverse-zoned alkali-feldspars. The shift in silica saturation took less than 1 Ma and is marked by an increase in peralkalinity from 0.9 to 1.5 and a decrease in oxygen isotopes ratio from 7.0 to 5.0 ‰. We interpret these observations as the consequence of maturation of the shallow magma reservoir towards less sediment contamination. Such assimilation of sediments is limited thermally, and compositionally because the system should remain alumina deficient. Crustal assimilation in Gran Canaria did not produce voluminous silicic melts by itself but allowed the deviation of the differentiation trend of a more primitive, initially SiO<sub>2</sub>-undersaturated magma. The tightrope of differentiation is represented by the thermal divide between the granite and phonolite minima (i.e. feldspar join in petrogeny’s residua system). Contamination by sediments produces a transient SiO<sub>2</sub>-oversaturated system (Mogan Group). Cogenetic assimilation of cumulates by thermal rejuvenation of the reservoir attracts the magma towards the thermal divide (ubiquitous during the peralkaline stage). Armouring against sediment assimilation through time relaxes the system back to the initial SiO<sub>2</sub>-undersaturated conditions (Fataga Group).</p>

Continental Crust formation in the Archean vs modern times

<p>When subduction initiated and contributed to formation of Continental crust is uncertain. A crucial difference between subduction zones magma and e.g. plume related magmatism is the role of H2O in the magma formed. Subduction zones magma are frequently wet and follow a liquid line of descent (LLD) that differs from dry plume related magmas. We developed a qualitative hygrometer based on major elements that allow to distinguish between LLD formed at water saturated condition from those that formed at dry conditions. While arc magmas can by dry at times, plume related magmas are generally dry. So wet LLD are a hall mark of subduction. In this talk we will compare the modern arc record with the Archean rock record to investigate if Archean rocks formed due to a wet or dry LLD. </p>

Intra-eruptive trachyte-phonolite transition: Natural evidence and experimental constraints on the role of crystal mushes

The generation of silica undersaturated phonolite from silica saturated trachytes is uncommon, as it implies the crossing of the thermal barrier and critical plane of silica undersaturation. Nevertheless, a co-genetic suite displaying compositional transition from benmoreite-trachyte to phonolite has been observed within the Al Shaatha pyroclastic sequence in the Harrat Rahat Volcanic Field (Kingdom of Saudi Arabia). We performed crystallization experiments on benmoreite and trachyte starting compositions to simulate the pressure-temperature-volatile conditions that generated the observed liquid line of descent. The experimental conditions were 200–500 MPa, 850–1150 °C, 0–10 wt% H2O, 0.0–0.5 wt% CO2, and NNO+2 oxygen buffer. The experimental mineral assemblage consists of clinopyroxene, feldspar, and titanomagnetite, as well as glass in variable proportions. The degree of crystallinity of hydrous runs is lower than that of anhydrous ones at analogous pressure and temperature conditions. Clinopyroxene crystallizes with compositions diopside-augite and augite-hedenbergite, respectively, at 500 and 200 MPa. The saturation of feldspar is primarily controlled by temperature and volatile content, with the more potassic composition equilibrating at low temperature (850–900 °C) and anhydrous (for benmoreite) or hydrous (for trachyte) conditions. At low pressure (200 MPa), temperatures below 850 °C, and anhydrous conditions, the degree of crystallization is extremely high (>90%), and the residual glass obtained from trachyte experiments is characterized by peralkaline and sodic affinity. This finding is consistent with natural eruptive products containing interstitial phonolitic glass within an anorthoclase framework. The shift from trachyte to phonolite is therefore interpreted as the result of open system interaction between trachytic magma and intercumulus phonolitic melt, as well as of dissolution of anorthoclase from a crystal mush.

Bulk Liquid for the Skaergaard Intrusion and Its PGE-Au Mineralization: Composition, Correlation, Liquid Line of Descent, and Timing of Sulphide Saturation and Silicate–Silicate Immiscibility

Preferred and modelled bulk composition of the Skaergaard intrusion are compared to coeval basaltic compositions in East Greenland and found to relate to the second evolved cycle of Geikie Plateau Formation lavas and coeval Skaergaard-like dikes in major and trace element (Mg# ∼45, Ce/Nb ∼2·5, (Dy/Yb)N ∼1·35), and precious metal composition (Pd/Pt ∼3, Au/Pt ∼2) as well as in age (∼56 Ma). Successful comparisons of precious metal compositions only occur with Skaergaard models based on mass balance. The bulk liquid of the intrusion evolved along the liquid line of descent to immiscibility between Si- and Fe-rich silicate liquids after ∼90% of crystallization (F = ∼0·10) in agreement with experimental constraints. Immiscibility led to accumulation and fractionation of the Fe-rich silicate melt in the mushy floor of the intrusion and continued accumulation of granophyre component in the remaining bulk liquid. The composition of plagioclase in the precious metal mineralized gabbro and modelling of Pd/Pt and Au/Pt in first formed droplets of sulphide melt suggest that sulphide saturation was reached in interstitial melts in crystal mushes in the floor and roof and in bulk liquid with a composition equivalent to that of the bulk liquid at lower UZa times and after crystallization of 82–85% of the bulk liquid (F = 0·19–0·16). Prior to sulphide saturation in UZa type melt, the precious metals ratios of the bulk liquid were controlled by the loss of Pt relative to Pd and Au in agreement with the low empirical and experimental solubility of Pt of ∼9ppb compared to a much higher value for Pd and Au. The relative timing between sulphide saturation (F = ∼0·18) and immiscibility between silicate melts (F = ∼0·10) and modelled precious metal ratios underpin the proposed multi-stage model for the mineralization, advocating initial accumulation in the mushy floor of the magma chamber controlled by sulphide saturation in mush melts rather than bulk melt, followed by redistribution of precious metals in a macro-rhythmic succession of gabbroic layers of the upward migrating crystallization zone.

Crystallisation and zircon saturation of calc-alkaline tonalite from the Adamello Batholith at upper crustal conditions: an experimental study

The understanding of the geochemical and petrophysical evolution of magmas forming intermediate calc-alkaline batholiths at shallow crustal levels critically depends on knowledge of the phase equilibria relations along the liquid line of descent. Here, we present experimental results for a tonalitic system at a pressure of 200 MPa and under water-saturated conditions. Melting experiments were performed at temperatures between 700 and 1000 °C in externally heated HCM pressure vessels, with oxygen fugacity controlled close to the Ni–NiO buffer equilibrium (NNO) employing an argon–methane mixture as pressure medium and Co–Pd redox sensors to verify fO2 conditions. Natural rock powder of a medium-K tonalite from the Adamello Batholith in Northern Italy served as experimental starting material. Based on compositional data of stable phases in the run products and images of entire run charges, mass balance calculations as well as image processing were performed to investigate the evolution of the crystal/melt ratio with respect to temperature. Furthermore, compositional trends of minerals as well as the liquid line of descent of residual melts were obtained. Orthopyroxene, clinopyroxene and plagioclase were identified as near-liquidus phases (below 990 °C). At 900 °C, amphibole joins the solid-phase assemblage at the expense of clinopyroxene, indicating the existence of a peritectic relationship. After an initial near-linear decrease with temperature, residual melt fractions exhibit a plateau of 45–55 vol. % between 750 and 850 °C, followed by a rapid decrease coinciding with quartz saturation at 725 °C. Compositions of residual liquids evolve along a typical calc-alkaline differentiation trend with decreasing temperature (increasing SiO2 and decreasing TiO2, Al2O3, CaO, MgO and FeO contents) and become peraluminous below 900 °C. Intermediate to acidic rocks from the Adamello follow the experimental liquid line of descent indicating that the observed compositional spread of the natural intermediate composition rock record can be explained by low-pressure magma differentiation and liquid extraction. Experimentally determined zircon saturation levels are at low temperatures distinctly lower compared to existing and often used Zr-saturation models, but fully consistent with observed and modelled Zr-evolution trends from the natural rock record of the Southern Adamello Batholith inferring that zircon saturation in these intermediate to felsic plutonic rocks occurred at 800–830 °C corresponding to a melt fraction of about 50 vol. %.

Birkhin volcanoplutonic association, Ol’khon region, western baikal area: petrological criteria of comagmatic origin

This paper reports the results of thermodynamic modeling of the formation of the Birkhin volcanoplutonic association by means of geochemical thermometry. The obtained liquid line of descent for the magma chamber of the Birkhin massif indicates that the melt evolved into the field of subalkaline composition. The melts of the volcanics of the Tsagan-Zaba complex are identical to the melts in the magma chamber in both major components and REEs. It was concluded that the Birkhin and Tsagan-Zaba complexes are comagmatic. A scenario was proposed for the development of the Birkhin volcanoplutonic association involving multiple eruptions of volcanic rocks during its formation. It was shown that the intermediate rocks are not derivatives of basic magmas, but were produced by interaction of basic volcanic rocks with felsic intrusions cutting them.