scholarly journals A Carbazole-Functionalized Porous Aromatic Framework for Enhancing Volatile Iodine Capture via Lewis Electron Pairing

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5263
Author(s):  
Zhuojun Yan ◽  
Bo Cui ◽  
Ting Zhao ◽  
Yifu Luo ◽  
Hongcui Zhang ◽  
...  
Keyword(s):  
Nuclear Waste ◽  
Cross Coupling ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Electron Pairing ◽  
Design And Synthesis ◽  
Porous Networks ◽  
Porous Aromatic Framework ◽  
Binding Capability ◽  
Coupling Polymerization

Nitrogen-rich porous networks with additional polarity and basicity may serve as effective adsorbents for the Lewis electron pairing of iodine molecules. Herein a carbazole-functionalized porous aromatic framework (PAF) was synthesized through a Sonogashira–Hagihara cross-coupling polymerization of 1,3,5-triethynylbenzene and 2,7-dibromocarbazole building monomers. The resulting solid with a high nitrogen content incorporated the Lewis electron pairing effect into a π-conjugated nano-cavity, leading to an ultrahigh binding capability for iodine molecules. The iodine uptake per specific surface area was ~8 mg m−2 which achieved the highest level among all reported I2 adsorbents, surpassing that of the pure biphenyl-based PAF sample by ca. 30 times. Our study illustrated a new possibility for introducing electron-rich building units into the design and synthesis of porous adsorbents for effective capture and removal of volatile iodine from nuclear waste and leakage.

Poultry Manure as a Fertilizer

EDIS ◽  
2013 ◽  
Vol 2013 (11) ◽  
Author(s):  
Michael A. Davis ◽  
Doug R. Sloan ◽  
Gerald Kidder ◽  
R. D. Jacobs
Keyword(s):  
Organic Matter ◽  
Environmental Factors ◽  
Nitrogen Content ◽  
Soil Amendment ◽  
Poultry Manure ◽  
Nutrient Retention ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Animal Science ◽  
Fact Sheet

Animal manures have been used as natural crop fertilizers for centuries. Because of poultry manure’s high nitrogen content, it has long been recognized as one of the most desirable manures. Besides fertilizing crops, manures also supply other essential plant nutrients and serve as a soil amendment by adding organic matter, which helps improve the soil’s moisture and nutrient retention. Organic matter persistence will vary with temperature, drainage, rainfall, and other environmental factors. This 2-page fact sheet was written by Michael A. Davis, D.R. Sloan, Gerald Kidder, and R.D. Jacobs, and published by the UF Department of Animal Science, November 2013. http://edis.ifas.ufl.edu/aa205

Cross-Coupling Polymerization at Iodophenyl Thin Films Prepared by Spontaneous Grafting of a Diazonium Salt

2019 ◽  
Author(s):  
Nicholas Marshall ◽  
Andres Rodriguez
Keyword(s):  
Thin Films ◽  
Diazonium Salt ◽  
Cross Coupling ◽  
Coupling Polymerization

Development of a method for the surface-initiated Kumada cross-coupling polymerization based on 4-iodophenyldiazonium salt thin films, and use of this method to make very thick polythiophene brushes.<br>

Design and synthesis of 1,8-Naphthalimide Functionalized Benzothiadiazoles

2021 ◽  
Author(s):  
Rajneesh Misra ◽  
Yogjivan Rout
Keyword(s):  
Ring Opening ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Design And Synthesis ◽  
Cross Coupling Reaction ◽  
Ring Opening Reaction

A series of multi acceptor based push-pull derivatives BTD2–BTD5 were designed and synthesized via Pd-catalyzed Sonogashira cross-coupling reaction followed by [2+2] cycloaddition–electrocyclic ring-opening reaction in which benzothiadiazole (BTD, A1), naphthalimide...

scholarly journals How Does an Acidic Support Affect the Hydrotreatment of a Gas Oil with High Nitrogen Content?

2019 ◽  
Vol 33 (2) ◽  
pp. 1467-1472 ◽  
Author(s):  
Minh-Tuan Nguyen ◽  
Gerhard D. Pirngruber ◽  
Florian Albrieux ◽  
Fabien Chainet ◽  
Melaz Tayakout-Fayolle ◽  
...  
Keyword(s):  
Nitrogen Content ◽  
Gas Oil ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Acidic Support

NO x and N2O Emissions During Fluidized Bed Combustion of Leather Wastes

2005 ◽  
Vol 128 (2) ◽  
pp. 99-103 ◽  
Author(s):  
Alberto Bahillo ◽  
Lourdes Armesto ◽  
Andrés Cabanillas ◽  
Juan Otero
Keyword(s):  
Nitrogen Content ◽  
Fluidized Bed ◽  
Oxygen Content ◽  
N2o Emission ◽  
N2o Emissions ◽  
Fluidized Bed Combustion ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Leather Wastes ◽  
Leather Waste

Transformation of hide (animal skins) into leather is a complicated process during which significant amounts of wastes are generated. Fluidized bed combustion has been extended to burn different wastes that have problems with their disposal showing its technical feasibility. Considering the characteristics of the leather waste, especially the heating value (12.5-21MJ∕kg), it is a fairly good fuel. Moreover, leather waste has a high volatile matter, 65%, similar to other biomasses and unusual high nitrogen content, 14%. The aim of this work was to study leather wastes combustion in fluidized bed presenting experimental results regarding NOx and N2O emissions. A series of experiments were carried out in a fluidized bed pilot plant to understand the importance of operating parameters such as furnace temperature, oxygen content in gases, staged combustion and residence time on the NOx and N2O emission level. Despite having high nitrogen content, low conversion of N-fuel to NOx and N2O was measured during the combustion of leather waste in BFB. Bed temperature and oxygen content were found as the most important single parameters on N2O emission and only oxygen content has a significant influence on NOx emission. Leather waste exhibits a great NOx∕O2 trend; NOx emission decreases as the oxygen concentration decreases while the effect of combustion temperature on NOx is insignificant. Staged combustion does not give a reduction in NOx.

UTILIZATION OF GRASS SILAGE BY CATTLE: EFFECT OF BARLEY AND FISHMEAL SUPPLEMENTS

1985 ◽  
Vol 65 (4) ◽  
pp. 897-903 ◽  
Author(s):  
D. M. VEIRA ◽  
M. IVAN ◽  
G. BUTLER ◽  
J. G. PROULX
Keyword(s):  
Formic Acid ◽  
Nitrogen Content ◽  
Dry Matter ◽  
Dry Matter Intake ◽  
Beef Steers ◽  
Large Reduction ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Grass Silage ◽  
Ad Libitum

Following weaning at 6–7 mo of age, 36 beef steers were used to determine production responses when grass silage was supplemented with barley or fishmeal. The silage was made from direct-cut, formic- acid-treated grass harvested from a mixed sward and had a high nitrogen content but poor fermentation characteristics. The silage was fed ad libitum for 98 days either alone or supplemented with 500 g fishmeal or 500 g barley per day. Both fishmeal and barley increased total dry matter intake (P < 0.01) by an amount equivalent to the quantity of supplement offered but had no effect on silage intake (P > 0.05). Steers fed the fishmeal grew substantially faster than either the barley (0.53 kg/day) or unsupplemented (0.54 kg/day) groups (P < 0.01). Fishmeal supplementation resulted in a large reduction (35%) in the amount of feed required per kilogram of gain. Key words: Cattle, grass silage, fishmeal, growth

Design and synthesis of 3,3′-triazolyl biisoquinoline N,N’-dioxides via Hiyama cross-coupling of 4-trimethylsilyl-1,2,3-triazoles

2021 ◽  
Vol 81 ◽  
pp. 153338 ◽  
Author(s):  
Shiyu Sun ◽  
Carlyn Reep ◽  
Chenrui Zhang ◽  
Burjor Captain ◽  
Roberto Peverati ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Design And Synthesis

Highly Ordered Mesoporous Carbon Nitride Nanoparticles with High Nitrogen Content: A Metal-Free Basic Catalyst

2009 ◽  
Vol 48 (42) ◽  
pp. 7884-7887 ◽  
Author(s):  
Xin Jin ◽  
Veerappan V. Balasubramanian ◽  
Sakthivel T. Selvan ◽  
Dhanashri P. Sawant ◽  
Murugulla A. Chari ◽  
...  
Keyword(s):  
Nitrogen Content ◽  
Mesoporous Carbon ◽  
Carbon Nitride ◽  
Ordered Mesoporous Carbon ◽  
Basic Catalyst ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Metal Free ◽  
Ordered Mesoporous ◽  
Mesoporous Carbon Nitride

Cyclic strength of an austenitic corrosion-resistant steel with a high nitrogen content

2010 ◽  
Vol 2010 (4) ◽  
pp. 346-353
Author(s):  
V. F. Terent’ev ◽  
I. O. Bannykh ◽  
E. V. Blinov ◽  
M. E. Prutskov ◽  
A. G. Kolmakov ◽  
...  
Keyword(s):  
Nitrogen Content ◽  
Cyclic Strength ◽  
Corrosion Resistant Steel ◽  
Resistant Steel ◽  
High Nitrogen Content ◽  
High Nitrogen ◽  
Corrosion Resistant
Sign in / Sign up

Export Citation Format

Share Document