scholarly journals Synthesis of Three-Dimensional Carbon Nanostructure/Copper Nanowire for Additive Interface Layer of Ionic Polymer Metal Composite

Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 423
Author(s):  
Seongjun Park ◽  
Minjeong Park ◽  
Seonpil Kim ◽  
Minhyon Jeon

Additive interface materials for improved ionic polymer metal composite (IPMC) actuator performance are being investigated. In this study, three-dimensional carbon nanostructure/copper nanowire (3DC Cu-NW) with a novel structure was synthesized via low-pressure chemical vapor deposition. An IPMC actuator with a 3DC Cu-NW interface layer was fabricated, which exhibited improved actuation performance, long-term stability, and electrochemical properties. The proposed 3DC consists of carbon nanotubes (CNTs) and graphene, grown using an Fe catalyst and CH4 gas, respectively. We optimized the growth conditions (Fe catalyst: 12.5 mg/L, CH4: 20 sccm) to achieve a 3DC with an appropriate thickness and a large specific surface area. The 3DC Cu-NW benefited from a Cu oxidation prevention property and a large specific surface area. The electrochemical properties and actuation performance of the IPMC actuator improved with an increased 3DC Cu-NW concentration. An IPMC actuator with a 0.6 wt% 3DC Cu-NW interface layer exhibited 1.3- and 5.6-fold electrochemical property and actuation performance improvement, respectively, over an IPMC actuator with no 3DC Cu-NW interface layer. These results show that the proposed 3DC Cu-NW has potential as an IPMC actuator interface material, and that 3DC Cu-NW synthesis and application technology can be applied to future research on sensor, actuator, and flexible devices.

2011 ◽  
Vol 17 (1) ◽  
pp. 49-55 ◽  
Author(s):  
Mohammad Luqman ◽  
Jang-Woo Lee ◽  
Kwang-Kil Moon ◽  
Young-Tai Yoo

Author(s):  
Muhammad Farid ◽  
Zhao Gang ◽  
Tran Linh Khuong ◽  
Zhuang Zhi Sun ◽  
Naveed Ur Rehman ◽  
...  

Biomimetic is the field of engineering in which biological creatures and their functions are investigated and are used as the basis for the design and manufacturing of machines. Ionic Polymer Metal Composite (IPMC) is a smart material which has demonstrated a meaningful bending and tip force after the application of a low voltage. It is light-weighted, flexible, easily actuated, multi-directional applicable and requires simple manufacturing. Resultantly, IPMC has attracted scientists and researchers to analyze it further and consider it for any industrial and biomimetic applications. Presently, the research on IPMC is bi-directional oriented. A few groups of researchers are busy to find out the causes for the weaknesses of the material and to find out any remedy for them. The second class of scientists is exploring new areas of applications where IPMC material can be used. Although, the application zone of IPMC is ranging from micropumps diaphragms to surgical holding devices, this paper provides an overview of the IPMC application in biomimetic and biomedical field.


2009 ◽  
Vol 1190 ◽  
Author(s):  
Takuma Kobayashi ◽  
Takeshi Kuribayashi ◽  
Masaki Omiya

AbstractWe built up the way of fabricating IPMC actuator with palladium electrodes and we found that it showed large bending response than Au-plated IPMC actuator. An ionic polymer-metal composite (IPMC) consisting of a thin perfuorinated ionomer membrane, electrodes plated on both faces, undergoes large bending motion when a small electric field is applied across its thickness in a hydrated state. The characteristics of IPMC are ease of miniaturization, low density, and mechanical flexibility. Therefore, it is considered to have a wide range of applications from MEMS sensor to artificial muscle. However, there are problems on IPMC. First, its mechanical and electric characteristics have not been clarified because of the complex mechanism of the deformation. Second, it is high-priced because most of IPMC actuators use gold or platinum as electrodes. In order for IPMC actuator to be widely put to practical use, we should solve these problems. Hence, this research focuses on fabrication of IPMC actuator with palladium electrode, which is cheaper than gold or platinum, and evaluation of its mechanical properties such as its tip displacement. We fabricated IPMC consisting of a thin Nafion® membrane, which is the film with fluorocarbon back-bones and mobile cations, sandwiched between two thin palladium plates. The surface resistivity was 2.88±0.18Ω/sq., so it could be said to be enough small. Then, we observed its cross section by using FE-SEM. As a result, palladium plates were evenly coated and its thickness was about 30μm. Also, we carried out an actuation test for two kinds of IPMCs: one was fabricated by using Nafion®117 (thickness 183μm), the other was by Nafion®115 (thickness 127μm). In this test, the relationship between voltage (0˜4V) across its thickness and tip displacement for the cantilevered strip of the IPMC was measured. Then we found that IPMCs showed large bending motion under a low electric field. When Nafion®117 sample was subjected to voltage of 1.5V, the ratio of the tip displacement to the sample length was 0.35, which was lager bending than Au-plated IPMC actuator, whose ratio of the tip displacement to the sample length was 0.12 [1]. When Nafion®115 sample was applied to 1.5V, the ratio of the tip displacement to the sample length was 0.22. Then, we found that Nafion®117 bended in a larger way than Nafion®115. Reference [1]Sia Nemat-Nesser and Yongxian Wu,”Comparative experimental study of ionic polymer-metal composites with different backbone ionomers and in various cation forms”, Journal of Applied Physics,93,5255 (2003)


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