scholarly journals Facile Synthesis of Triphenylamine Based Hyperbranched Polymer for Organic Field Effect Transistors

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1787 ◽  
Author(s):  
Chinna Bathula ◽  
Alfred Appiagyei ◽  
Hemraj Yadav ◽  
Ashok K. ◽  
Sivalingam Ramesh ◽  
...  

In this study, we reported the synthesis and characterization of a novel hyperbranched polymer (HBPs) tris[(4-phenyl)amino-alt-4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b’]dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b’]dithiophene (BDT) and triphenyleamine (TPA) constituent subunits by A3 + B2 type Stille’s reaction. An estimated optical band gap of 1.69 eV with HOMO and LUMO levels of −5.29 eV and −3.60 eV, respectively, as well as a high thermal stability up to 398 °C were characterized for the synthesized polymer. PTPABDT fabricated as an encapsulated top gate/bottom contact (TGBC), organic field effect transistors (OFET) exhibited a p-type behavior with maximum field-effect mobility (µmax) and an on/off ratio of 1.22 × 10−3 cm2 V−1 s−1 and 7.47 × 102, respectively.

2021 ◽  
Author(s):  
Suman Yadav ◽  
Shivani Sharma ◽  
Satinder K Sharma ◽  
Chullikkattil P. Pradeep

Solution-processable organic semiconductors capable of functioning at low operating voltages (~5 V) are in demand for organic field-effect transistor (OFET) applications. Exploration of new classes of compounds as organic thin-film...


2003 ◽  
Author(s):  
Beynor A. Paez ◽  
Matthias Bartzsch ◽  
Georgeta Salvan ◽  
Reinhard Scholz ◽  
Thorsten U. Kampen ◽  
...  

2005 ◽  
Vol 97 (8) ◽  
pp. 083714 ◽  
Author(s):  
Th. B. Singh ◽  
N. Marjanović ◽  
P. Stadler ◽  
M. Auinger ◽  
G. J. Matt ◽  
...  

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