scholarly journals Effect of Post-Thermal Annealing on the Performance and Charge Photogeneration Dynamics of PffBT4T-2OD/PC71BM Solar Cells

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 408 ◽  
Author(s):  
Wei Zhang ◽  
Rong Hu ◽  
Xiaokang Zeng ◽  
Xiaojun Su ◽  
Zhifeng Chen ◽  
...  

In this work, we studied influence of post thermal annealing on the performance and charge photogeneration processes of PffBT4T-2OD/PC71BM solar cells. As-prepared device exhibits a high-power conversion efficiency of 9.5%, much higher than that after thermal annealing. To understand this phenomenon, we studied charge photogeneration processes in these solar cells by means of time resolved spectroscopy. We associate the degradation of solar cell performance with the reduction of exciton dissociation efficiency and with increased bimolecular recombination of photogenerated charges as a result of annealing. We correlate the generation of localized PffBT4T-2OD polarons observed via spectro-electrochemical measurements with enhancement of the bimolecular charge recombination of annealed solar cells.

2014 ◽  
Vol 2 (45) ◽  
pp. 19282-19289 ◽  
Author(s):  
Zhenggang Huang ◽  
Elisa Collado Fregoso ◽  
Stoichko Dimitrov ◽  
Pabitra Shakya Tuladhar ◽  
Ying Woan Soon ◽  
...  

The performance of bulk heterojunction solar cells based on a novel donor polymer DPP-TT-T was optimised by tuning molecular weight and thermal annealing.


2016 ◽  
Vol 846 ◽  
pp. 292-297
Author(s):  
Nasehah Syamin Sabri ◽  
Chi Chin Yap ◽  
Muhammad Yahaya ◽  
Muhamad Mat Salleh ◽  
Mohammad Hafizuddin Haji Jumali

This paper reports the effect of perovskite layer on enhancing the inverted type hybrid organic solar cell performance. The mixtures of methylammonium iodide (CH3NH3I) and lead (II) chloride (PbCl2) were dissolved in N,N-Dimethylformamide (DMF) solvent and was spin-coated onto fluorine-doped tin oxide (FTO) glass substrate coated with zinc oxide nanorod arrays (ZnONRAs). The poly (3-hexylthiophene-2,5-diyl) (P3HT) film was then spin-coated onto CH3NH3I(3-x)PbClx perovskite layer, followed by silver (Ag) deposition using magnetron sputtering technique. The FTO/ZnO seed/ZnONRAs/CH3NH3PbI(3-x)Clx /P3HT/Ag device was fabricated. A device without perovskite layer was also fabricated for comparison. A power conversion efficiency (PCE) of 0.56% was achieved with the introduction of perovskite layer. The PCE was approximately six times greater than the device without perovskite layer, as a result of wider light absorption range and higher exciton dissociation efficiency.


2014 ◽  
Vol 1 (9) ◽  
pp. 682-688 ◽  
Author(s):  
M. Alaaeddine ◽  
Q. Zhu ◽  
D. Fichou ◽  
G. Izzet ◽  
J. E. Rault ◽  
...  

Thick layers of the Wells–Dawson K6[P2W18O62] highly ordered were obtained and integrated at the anodic interface of organic solar cells to reach high power conversion efficiency.


2014 ◽  
Vol 2 (37) ◽  
pp. 7715-7721 ◽  
Author(s):  
Kejia Jiao ◽  
Xueliang Wang ◽  
Yu Wang ◽  
Yunfa Chen

Interface tailoring is an effective approach towards high performance Graphene/Silicon Schottky-barrier solar cells. Inserting a thin graphene oxide (GO) interfacial layer can improve the efficiency of graphene/silicon solar cells by >100%. Further performance optimization leads to 12.3% of power conversion efficiency (PCE). To date, a record PCE has been achieved on the same device level.


2018 ◽  
Vol 6 (34) ◽  
pp. 16347-16354 ◽  
Author(s):  
Meiyue Liu ◽  
Ziming Chen ◽  
Qifan Xue ◽  
Sin Hang Cheung ◽  
Shu Kong So ◽  
...  

Vacuum-assisted thermal annealing not only could improve film morphology and crystallinity, but also could accelerate the sublimation of undesired MACl. With the help of this process, we obtain a highly efficient low-bandgap CH3NH3Sn0.5Pb0.5IxCl3−x perovskite solar cell with a power conversion efficiency of 12.3%.


2016 ◽  
Vol 09 (02) ◽  
pp. 1650018 ◽  
Author(s):  
Yi Guo ◽  
Xiang Zhang ◽  
Yanhong Li ◽  
Yanmei Li ◽  
Chunli Hu ◽  
...  

We report a facile and cheap route to the fabrication of ZnO/CdS and ZnO/CdSe based on commercial ZnO particles. The obtained product can be directly brush printed as solar paint. The results show that the solar cell based on the mixture of ZnO/CdS and ZnO/CdSe have a better light absorption and electron transport ability, and a high power conversion efficiency (PCE) of 1.36% was obtained, which is the highest PCE reported for inorganic paint-based solar cells to date. This method greatly simplifies the process of the solar cell fabrication and opens a door toward the cheap and printable solar paint based on commercial available materials.


2017 ◽  
Vol 5 (34) ◽  
pp. 18044-18052 ◽  
Author(s):  
Shun-Hsiang Chan ◽  
Ming-Chung Wu ◽  
Kun-Mu Lee ◽  
Wei-Cheng Chen ◽  
Tzu-Hao Lin ◽  
...  

The power conversion efficiency of perovskite solar cells can be enhanced by using Ba2+-doped perovskite films.


2019 ◽  
Vol 3 (6) ◽  
pp. 1085-1096 ◽  
Author(s):  
Leiping Duan ◽  
Xianyi Meng ◽  
Yu Zhang ◽  
Haimang Yi ◽  
Ke Jin ◽  
...  

The ternary organic solar cell is a promising technology towards high power conversion efficiency.


2014 ◽  
Vol 2 (39) ◽  
pp. 16429-16433 ◽  
Author(s):  
Sun Hye Hwang ◽  
Jongmin Roh ◽  
Jungsup Lee ◽  
Jaehoon Ryu ◽  
Juyoung Yun ◽  
...  

The effects of scaffold layers composed of SiO2NPs with diameters of 15, 30, 50, 70, and 100 nm on the properties of a perovskite film were investigated . Among the various sizes of SiO2NPs, the performance of a 50 nm diameter SiO2NP based perovskite solar cell presented a high power-conversion efficiency (PCE) of 11.45%.


Sign in / Sign up

Export Citation Format

Share Document