scholarly journals Radiation Processing and Characterization of Some Ethylene-propylene-diene Terpolymer/Butyl (Halobutyl) Rubber/Nanosilica Composites

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2431
Author(s):  
Elena Manaila ◽  
Anton Airinei ◽  
Maria Daniela Stelescu ◽  
Maria Sonmez ◽  
Laurentia Alexandrescu ◽  
...  

Composites based on ethylene–propylene–diene terpolymer (EPDM), butyl/halobutyl rubber and nanosilica were prepared by melt mixing and subjected to different doses of electron beam irradiation. The effect of irradiation dose on the mechanical properties, morphology, glass transition temperature, thermal stability and water uptake was investigated. The efficiency of the crosslinking by electron beam irradiation was analyzed by Charlesby–Pinner parameter evaluation and crosslink density measurements. The scanning electron microscopy data showed a good dispersion of nanosilica in the rubber matrix. An improvement in hardness and 100% modulus was revealed by increasing irradiation dose up to 150 kGy. The interaction between polymer matrix and nanosilica was analyzed using the Kraus equation. Additionally, these results indicated that the mechanical properties, surface characteristics, and water uptake were dependent on crosslink characteristics.

2021 ◽  
Vol 294 ◽  
pp. 126300
Author(s):  
Imane Belyamani ◽  
Joachim Maris ◽  
Sylvie Bourdon ◽  
Jean-Michel Brossard ◽  
Laurent Cauret ◽  
...  

2021 ◽  
Vol 7 (8) ◽  
pp. 79528-79537
Author(s):  
Pedro Marcio Munhoz ◽  
Fernando Codelo Nascimento ◽  
Leonardo Gondim de Andrade e Silva ◽  
Julio Harada ◽  
Wilson Aparecido Parejo Calvo

The aim of this research was to evaluate the changes in the mechanical properties of poly(butylene adipate co-terephthalate)/poly(lactic acid) (PBAT/PLA) polymeric blend after the radiation process at different radiation doses. The irradiation was performed in an electron beam accelerator, with 1.5 MeV of energy and 25 mA electric current. The samples were irradiated with doses of 5, 10, 15, 25, 50, 65 and 80 kGy. Both irradiated and non-irradiated samples were characterized by Izod pendulum impact resistance and tensile strength at rupture. The results showed an increase of 44% in relation to Izod impact resistance at a dose of 65 kGy. However, the module of elasticity decreased 56% and tensile strength at rupture decreased 55% at the same radiation dose. In relation to elongation, significant alterations caused by electron beam irradiation was not observed. Therefore, it can be concluded that irradiated blends could be used to make environmentally friendly products, which could absorb impact energy. 


2020 ◽  
Vol 141 ◽  
pp. 103265 ◽  
Author(s):  
Seyed Mohammad Razavi ◽  
Seyed Javad Ahmadi ◽  
Peyman Rahmani Cherati ◽  
Mina Hadi ◽  
Seyed Amir Reza Ahmadi

Nukleonika ◽  
2015 ◽  
Vol 60 (3) ◽  
pp. 679-682 ◽  
Author(s):  
Magdalena Ptaszek ◽  
Leszek B. Orlikowski ◽  
Wojciech Migdał ◽  
Urszula Gryczka

Abstract Effectiveness of electron beam irradiation was evaluated against Phytophthora nicotianae var. nicotianae, the causal agent of stem base and root rot of tomato. In laboratory trials, irradiation of 7-day-old Phytophthora cultures growing on potato-dextrose-agar (PDA) medium with 1 kGy resulted in the disintegration of the pathogen’s hyphae. Increasing the irradiation dose to 3 kGy caused decay of the hyphae. Irradiation of infested stonewool with 5 kGy caused decrease of the pathogen population about 5 times. Application of 20 kGy completely eliminated the pathogen from stonewool. Irradiation of substratum resulted in significant increase of tomato seedlings healthiness, especially when the dose 20 kGy was applied.


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