scholarly journals UV-Protected Polyurethane/f-Oil Fly Ash-CeO2 Coating: Effect of Pre-Mixing f-Oil Fly Ash-CeO2 with Monomers

Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3232
Author(s):  
Mohammad Mizanur Rahman ◽  
Md. Hasan Zahir ◽  
Aasif Helal ◽  
Rami K. Suleiman ◽  
Bashirul Haq ◽  
...  

A series of UV-protected coatings were prepared using cerium-oxide-functionalized oil fly ash (f-OFA-CeO2) in waterborne polyurethane (WBPU) dispersions. Three monomers, namely, poly(tetramethyleneoxide glycol) (PTMG), polydimethylsiloxane-hydroxy terminated (PDMS) and 4,4-dicyclohexylmethane diisocyanate (H12MDI), were used to pre-mix with f-OFA-CeO2 separately, followed by the synthesis of WBPU/f-OFA-CeO2 dispersions. The f-OFA-CeO2 distribution and enrichment into any part (top/bottom/bulk) of the coating was strongly affected by the pre-mixing of f-OFA-CeO2. The f-OFA-CeO2 was densely distributed in the top, bottom and bulk when the f-OFA-CeO2 was pre-mixed with PDMS, H12MDI and PTMG, respectively. Only an f-OFA-CeO2-enriched top surface showed excellent UV protection. The lowest UV-degraded exposed coating was found when the top surface of the coating was f-OFA-CeO2-enriched.

1997 ◽  
Vol 9 (6) ◽  
pp. 541-565 ◽  
Author(s):  
Cheryl R. Killingsworth ◽  
Francesca Alessandrini ◽  
G. G. Krishna Murthy ◽  
Paul J. Catalano ◽  
Joseph D. Paulauskis ◽  
...  

2011 ◽  
Vol 18 (6) ◽  
pp. 2275-2284 ◽  
Author(s):  
Muhammad J. Khan ◽  
Abdulhadi A. Al-Juhani ◽  
Reyad Shawabkeh ◽  
Anwar Ul-Hamid ◽  
Ibnelwaleed A. Hussein

2013 ◽  
Vol 266 ◽  
pp. 118-125 ◽  
Author(s):  
Ali L. Yaumi ◽  
Ibnelwaleed A. Hussien ◽  
Reyad A. Shawabkeh

2011 ◽  
Vol 122 (4) ◽  
pp. 2486-2496 ◽  
Author(s):  
Muhammad J. Khan ◽  
Abdulhadi A. Al-Juhani ◽  
Anwar Ul-Hamid ◽  
Reyad Shawabkeh ◽  
Ibnelwaleed A. Hussein

Author(s):  
Mohammed Dahim ◽  
Musab Abuaddous ◽  
Hashem Al-Mattarneh ◽  
Andan Rawashdeh ◽  
Rabah Ismail

1999 ◽  
Vol 277 (3) ◽  
pp. L498-L510 ◽  
Author(s):  
Janice A. Dye ◽  
Kenneth B. Adler ◽  
Judy H. Richards ◽  
Kevin L. Dreher

Particulate matter (PM) metal content and bioavailability have been hypothesized to play a role in the health effects epidemiologically associated with PM exposure, in particular that associated with emission source PM. Using rat tracheal epithelial cells in primary culture, the present study compared and contrasted the acute airway epithelial effects of an emission source particle, residual oil fly ash (ROFA), with that of its principal constitutive transition metals, namely iron, nickel, and vanadium. Over a 24-h period, exposure to ROFA, vanadium, or nickel plus vanadium, but not to iron or nickel, resulted in increased epithelial permeability, decreased cellular glutathione, cell detachment, and lytic cell injury. Treatment of vanadium-exposed cells with buthionine sulfoximine further increased cytotoxicity. Conversely, treatment with the radical scavenger dimethylthiourea inhibited the effects in a dose-dependent manner. RT-PCR analysis of RNA isolated from ROFA-exposed rat tracheal epithelial cells demonstrated significant macrophage inflammatory protein-2 and interleukin-6 gene expression as early as 6 h after exposure, whereas gene expression of inducible nitric oxide synthase was maximally increased 24 h postexposure. Again, vanadium (not nickel) appeared to be mediating the effects of ROFA on gene expression. Treatment with dimethylthiourea inhibited both ROFA- and vanadium-induced gene expression in a dose-dependent manner. Corresponding effects were observed in interleukin-6 and macrophage inflammatory protein-2 synthesis. In summary, generation of an oxidative stress was critical to induction of the ROFA- or vanadium-induced effects on airway epithelial gene expression, cytokine production, and cytotoxicity.


2018 ◽  
Vol 69 (2) ◽  
pp. 246-257 ◽  
Author(s):  
Zaheer Aslam ◽  
Ibnelwaleed A. Hussein ◽  
Reyad A. Shawabkeh ◽  
Mohammad Anwar Parvez ◽  
Waqar Ahmad ◽  
...  

2017 ◽  
Vol 78 ◽  
pp. 97-104 ◽  
Author(s):  
Numan Salah ◽  
Ahmed Alshahrie ◽  
M.Sh. Abdel-wahab ◽  
Najlaa D. Alharbi ◽  
Zishan H. Khan

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