scholarly journals Pyrolytic Behavior of Polyvinyl Chloride: Kinetics, Mechanisms, Thermodynamics, and Artificial Neural Network Application

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4359
Author(s):  
Mohammed Al-Yaari ◽  
Ibrahim Dubdub

Pyrolysis of waste polyvinyl chloride (PVC) is considered a promising and highly efficient treatment method. This work aims to investigate the kinetics, and thermodynamics of the process of PVC pyrolysis. Thermogravimetry of PVC pyrolysis at three heating rates (5, 10, and 20 K/min) showed two reaction stages covering the temperature ranges of 490–675 K, and 675–825 K, respectively. Three integral isoconversional models, namely Flynn-Wall-Qzawa (FWO), Kissinger-Akahira-Sunose (KAS), and Starink, were used to obtain the activation energy (Ea), and pre-exponential factor (A) of the PVC pyrolysis. On the other hand, the Coats-Redfern non-isoconversional model was used to determine the most appropriate solid-state reaction mechanism/s for both stages. Values of Ea, and A, obtained by the isoconversional models, were very close and the average values were, for stage I: Ea = 75 kJ/mol, A = 1.81 × 106 min−1; for stage II: Ea = 140 kJ/mol, A = 4.84 × 109 min−1. In addition, while the recommended mechanism of the first stage reaction was P2, F3 was the most suitable mechanism for the reaction of stage II. The appropriateness of the mechanisms was confirmed by the compensation effect. Thermodynamic study of the process of PVC pyrolysis confirmed that both reactions are endothermic and nonspontaneous with promising production of bioenergy. Furthermore, a highly efficient artificial neural network (ANN) model has been developed to predict the weight left % during the PVC pyrolysis as a function of the temperature and heating rate. The 2-10-10-1 topology with TANSIG-LOGSIG transfer function and feed-forward back-propagation characteristics was used.

2008 ◽  
Vol 33 (6) ◽  
pp. 1213-1222 ◽  
Author(s):  
Dean Charles Hay ◽  
Akinobu Wakayama ◽  
Ken Sakamura ◽  
Senshi Fukashiro

Estimation of energy expenditure in daily living conditions can be a tool for clinical assessment of health status, as well as a self-measure of lifestyle and general activity levels. Criterion measures are either prohibitively expensive or restricted to laboratory settings. Portable devices (heart rate monitors, pedometers) have gained recent popularity, but accuracy of the prediction equations remains questionable. This study applied an artificial neural network modeling approach to the problem of estimating energy expenditure with different dynamic inputs (accelerometry, heart rate above resting (HRar), and electromyography (EMG)). Nine feed-forward back-propagation models were trained, with the goal of minimizing the mean squared error (MSE) of the training datasets. Model 1 (accelerometry only) and model 2 (HRar only) performed poorly and had significantly greater MSE than all other models (p < 0.001). Model 3 (combined accelerometry and HRar) had overall performance similar to EMG models. Validation of all models was performed by simulating untrained datasets. MSE of all models increased when tested with validation data. While models 1 and 2 again performed poorly, model 3 MSE was lower than all but 2 EMG models. Squared correlation coefficients of measured and predicted energy expenditure for models 3 to 9 ranged from 0.745 to 0.817. Analysis of mean error within specific movement categories indicates that EMG models may be better at predicting higher-intensity energy expenditure, but combined accelerometry and HRar provides an economical solution, with sufficient accuracy.


2011 ◽  
Vol 94 (1) ◽  
pp. 322-326
Author(s):  
Mohammadreza Khanmohammadi ◽  
Amir Bagheri Garmarudi ◽  
Mohammad Babaei Rouchi ◽  
Nafiseh Khoddami

Abstract A method has been established for simultaneous determination of sodium sulfate, sodium carbonate, and sodium tripolyphosphate in detergent washing powder samples based on attenuated total reflectance Fourier transform IR spectrometry in the mid-IR spectral region (800–1550 cm−1). Genetic algorithm (GA) wavelength selection followed by feed forward back-propagation artificial neural network (BP-ANN) was the chemometric approach. Root mean square error of prediction for BP-ANN and GA-BP-ANN was 0.0051 and 0.0048, respectively. The proposed method is simple, with no tedious pretreatment step, for simultaneous determination of the above-mentioned components in commercial washing powder samples.


2010 ◽  
Vol 152-153 ◽  
pp. 1700-1703 ◽  
Author(s):  
Suchada Piriyaprasarth ◽  
Pornsak Sriamornsak ◽  
Maneerat Juttulapa ◽  
Satit Puttipipatkhachorn

The objective of this study was to model the drug release property in terms of process variables of microwave-assisted modification of arrowroot starch using artificial neural network (ANN). The water content, microwave power and heating time were used as process variables for modification of arrowroot starch and the mean dissolution time was used as dependent variable. The correlation between process variables and dependent variable was examined using feed-forward back-propagation neural networks. The ANN model was optimized by considering goodness-of-fit and crossvalidated predictability. A “leave-one-out” cross-validation revealed that the neural network model could predict MDT values from matrix tablets with a reasonable accuracy (predictive r2 of 0.824 and predictive root mean square error of 19.53). The predictive ability of these models was validated by a set of 4 formulations that were not included in the training set. The predicted and observed MDT were well correlated.


2012 ◽  
Vol 576 ◽  
pp. 91-94 ◽  
Author(s):  
Erry Yulian Triblas Adesta ◽  
Muataz H.F. Al Hazza ◽  
M.Y. Suprianto ◽  
Muhammad Riza

Machining of hardened steel at high cutting speeds produces high temperatures in the cutting zone, which affects the surface quality and cutting tool life. Thus, predicting the temperature in early stage becomes utmost importance. This research presents a neural network model for predicting the cutting temperature in the CNC end milling process. The Artificial Neural Network (ANN) was applied as an effective tool for modeling and predicting the cutting temperature. A set of sparse experimental data for finish end milling on AISI H13 at hardness of 48 HRC have been conducted to measure the cutting temperature. The artificial neural network (ANN) was applied to predict the cutting temperature. Twenty hidden layer has been used with feed forward back propagation hierarchical neural networks were designed with Matlab2009b Neural Network Toolbox. The results show a high correlation between the predicted and the observed temperature which indicates the validity of the models.


2015 ◽  
Vol 19 (1) ◽  
pp. 85-93 ◽  
Author(s):  
Ehsan Momeni ◽  
Ramli Nazir ◽  
Danial Jahed Armaghani ◽  
Harnedi Maizir

<p class="MsoNormal" style="text-align: justify; line-height: 200%;">Axial bearing capacity (ABC) of piles is usually determined by static load test (SLT). However, conducting SLT is costly and time-consuming. High strain dynamic pile testing (HSDPT) which is provided by pile driving analyzer (PDA) is a more recent approach for predicting the ABC of piles. In comparison to SLT, PDA test is quick and economical. Implementing feed forward back-propagation artificial neural network (ANN) for solving geotechnical problems has recently gained attention mainly due to its ability in finding complex nonlinear relationships among different parameters. In this study, an ANN-based predictive model for estimating ABC of piles and its distribution is proposed. For network construction purpose, 36 PDA tests were performed on various concrete piles in different project sites. The PDA results, pile geometrical characteristics as well as soil investigation data were used for training the ANN models. Findings indicate the feasibility of ANN in predicting ultimate, shaft and tip bearing resistances of piles. The coefficients of determination, R², equal to 0.941, 0.936, and 0.951 for testing data reveal that the shaft, tip and ultimate bearing capacities of piles predicted by ANN-based model are in close agreement with those of HSDPT. By using sensitivity analysis, it was found that the length and area of the piles are dominant factors in the proposed predictive model.</p><p class="MsoNormal" style="text-align: justify; line-height: 200%;"> </p><p class="MsoNormal" style="text-align: justify; line-height: 200%;"><strong>Resumen</strong></p><p class="MsoNormal" style="text-align: justify; line-height: 200%;">La Capacidad Axial de Soporte (ABC, en inglés) de un pilote de construcción se determina usualmente a través de una Prueba de Carga Estática (SLT, inglés). Sin embargo, estas pruebas son costosas y demandan tiempo. La evaluación de las Dinámicas de Alto Esfuerzo de Pilotes (HSDPT, inglés), que la provee el programa de Análisis de Excavación (PDA, inglés), es una forma de aproximación más reciente para preveer la Capacidad Axial de Soporte. En comparación con la Prueba de Cargas Estática, la evaluación PDA es rápida y económica. La implementación de Redes Neuronales Arficiales (ANN, en inglés) que permita resolver problemas geotécnicos ha ganado atención recientemente debido a su posibilidad de hallar relaciones no lineales entre los diferentes parámetros. En este estudio se propone un modelo predictivo ANN para estimar la Capacidad Axial de Soporte de pilotes y su distribución. Para fines de una red de construcción se realizaron 36 pruebas PDA en pilotes de diferentes proyectos. Los resultados de los Análisis de Excavación, las características geométricas de los pilotes, al igual que los datos de investigación del suelo se utilizaron para probar los modelos ANN. Los resultados indican la viabilidad del modelo ANN en predecir la resistencia de los pilotes. Los coeficientes de correlación, R², que alcanzaron 0.941, 09.36 y 0.951 para la evaluación de los datos, revelan que la capacidad del pilotaje en el último rodamiento, en el cojinete del eje y en la punta que se predijeron con el modelo ANN concuerda con las establecidas a través del HSDPT. A través del análisis de respuesta se determinó que la longitud y el área de los pilotes son factores dominantes en el modelo predictivo propuesto.</p>


2017 ◽  
Vol 68 (11) ◽  
pp. 2070 ◽  
Author(s):  
Manh-Ha Bui ◽  
Thanh-Luu Pham ◽  
Thanh-Son Dao

An artificial neural network (ANN) model was used to predict the cyanobacteria bloom in the Dau Tieng Reservoir, Vietnam. Eight environmental parameters (pH, dissolved oxygen, temperature, total dissolved solids, total nitrogen (TN), total phosphorus, biochemical oxygen demand and chemical oxygen demand) were introduced as inputs, whereas the cell density of three cyanobacteria genera (Anabaena, Microcystis and Oscillatoria) with microcystin concentrations were introduced as outputs of the three-layer feed-forward back-propagation ANN. Eighty networks covering all combinations of four learning algorithms (Bayesian regularisation (BR), gradient descent with momentum and adaptive learning rate, Levenberg–Mardquart, scaled conjugate gradient) with two transfer functions (tansig, logsig) and 10 numbers of hidden neurons (6–16) were trained and validated to find the best configuration fitting the observed data. The result is a network using the BR learning algorithm, tansig transfer function and nine neurons in the hidden layer, which shows satisfactory predictions with the low values of error (root mean square error=0.108) and high correlation coefficient values (R=0.904) between experimental and predicted values. Sensitivity analysis on the developed ANN indicated that TN and temperature had the most positive and negative effects respectively on microcystin concentrations. These results indicate that ANN modelling can effectively predict the behaviour of the cyanobacteria bloom process.


Author(s):  
Nicholas Christakis ◽  
Michael Politis ◽  
Panagiotis Tirchas ◽  
Minas Achladianakis ◽  
Eleftherios Avgenikou ◽  
...  

Covid-19 is the most recent strain from the corona virus family that its rapid spread across the globe has caused a pandemic, resulting in over 200,000,000 infections and over 4,000,000 deaths so far. Many countries had to impose full lockdowns, with serious effects in all aspects of everyday life (economic, social etc.). In this paper, a computational framework is introduced, aptly named COVID-LIBERTY, in order to assist the study of the pandemic in Europe. Initially, the mathematics and details of the computational engine of the framework, a feed-forward, back-propagation Artificial Neural Network are presented. 5 European countries with similar population numbers were chosen and we examined the main factors that influence the spread of the virus, in order to be taken into consideration in the simulations. In this way lockdown, seasonal variability and virus effective reproduction were considered. The effectiveness of lockdown in the spread of the virus was examined and the Lockdown Index was introduced. Moreover, the relation of Covid- 19 to seasonal variability was demonstrated and the parametrization of seasonality presented.


2020 ◽  
Vol 1 (2) ◽  
pp. 59-64
Author(s):  
Hu Weighuo ◽  
Hu He

This paper reviews the qualities of a good flood forecasting model such as timeliness, accuracy, and reliability. The article reviews the current forecasting models which are based on fuzzy logic, artificial neural network, as well as combination. The combination approach is gaining popularity and is found to be more flexible, accurate, reliable, and highly efficient in terms of development and output.


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