scholarly journals Highly Active CuO/KCC−1 Catalysts for Low-Temperature CO Oxidation

Processes ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 145
Author(s):  
Yiwei Luo ◽  
Yonglong Li ◽  
Conghui Wang ◽  
Jing Wang ◽  
Wenming Liu ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Active Oxygen Species ◽  
Copper Catalysts ◽  
High Dispersion ◽  
Impregnation Method ◽  
Active Components ◽  
Highly Active ◽  
Low Temperature Co Oxidation ◽  
Oxidation Performance ◽  
The Stability

Copper catalysts have been extensively studied for CO oxidation at low temperatures. Previous findings on the stability of such catalysts, on the other hand, revealed that they deactivated badly under extreme circumstances. Therefore, in this work, a series of KCC−1-supported copper oxide catalysts were successfully prepared by impregnation method, of which 5% CuO/KCC−1 exhibited the best activity: CO could be completely converted at 120 °C. The 5% CuO/KCC−1 catalyst exhibited better thermal stability, which is mainly attributed to the large specific surface area of KCC−1 that facilitates the high dispersion of CuO species, and because the dendritic layered walls can lengthen the movement distances from particle-to-particle, thus helping to slow down the tendency of active components to sinter. In addition, the 5% CuO/KCC−1 has abundant mesoporous and surface active oxygen species, which are beneficial to the mass transfer and promote the adsorption of CO and the decomposition of Cu+–CO species, thus improving the CO oxidation performance of the catalyst.

scholarly journals Synergistic Effects of Co3O4-CeO2 Nanoparticles towards Catalytic Oxidation of Aromatic Hydrocarbons: A Study in Association with Carbon Monoxide and Humidity

2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Trung Dang-Bao ◽  
Hong Phuong Phan ◽  
Phung Anh Nguyen ◽  
Pham Phuong Trang Vo ◽  
Van Tien Huynh ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
Synergistic Effects ◽  
Active Oxygen Species ◽  
High Dispersion ◽  
High Catalytic Activity ◽  
Impregnation Method ◽  
Temperature Programmed ◽  
The Stability

In this study, a series of Co3O4-CeO2 nanocomposites with various Co3O4 loading were fabricated by the impregnation method using cobalt(II) acetate as the cobalt precursor for the treatment of benzene, toluene, ethylbenzene, and xylene (BTEX). The as-prepared Co3O4-CeO2 nanocomposites were thoroughly characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brumauer-Emmett-Teller (BET), hydrogen temperature-programmed reduction (H2-TPR), and temperature-programmed desorption (O2-TPD). The excellent reproduction of active oxygen species caused by the high dispersion of Co3O4 crystals on the CeO2 supports was established. In addition, the reduction peaks of Co3O4-CeO2 nanocomposites were found at much lower temperatures compared to pure CeO2, considering their unique redox property influencing on the high catalytic activity. Among the characterized materials, the 5.0 wt.% Co3O4 supported on CeO2 (5.0Co–Ce) was the best system for catalytic oxidation of xylene, along with excellent performances in the cases of benzene, ethylbenzene, and toluene. Its catalytic activity increased in the order: benzene < xylene < ethylbenzene < toluene . Furthermore, the addition of carbon monoxide (CO) as a coreactant permitted to improve the catalytic performances in such oxidations as well as the stability of as-prepared catalysts, even under humid conditions.

Highly active PdCeOx composite catalysts for low-temperature CO oxidation, prepared by plasma-arc synthesis

2014 ◽  
Vol 147 ◽  
pp. 132-143 ◽  
Author(s):  
R.V. Gulyaev ◽  
E.M. Slavinskaya ◽  
S.A. Novopashin ◽  
D.V. Smovzh ◽  
A.V. Zaikovskii ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co Oxidation ◽  
Plasma Arc ◽  
Composite Catalysts ◽  
Highly Active ◽  
Low Temperature Co Oxidation

scholarly journals Correction: Activity enhancement of Pt/MnOx catalyst by novel β-MnO2 for low-temperature CO oxidation: study of the CO–O2 competitive adsorption and active oxygen species

2020 ◽  
Vol 10 (20) ◽  
pp. 7067-7067
Author(s):  
Ningqiang Zhang ◽  
Lingcong Li ◽  
Rui Wu ◽  
Liyun Song ◽  
Lirong Zheng ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co Oxidation ◽  
Competitive Adsorption ◽  
Active Oxygen Species ◽  
Active Oxygen ◽  
Oxygen Species ◽  
Oxidation Study ◽  
Low Temperature Co Oxidation ◽  
Activity Enhancement

Correction for ‘Activity enhancement of Pt/MnOx catalyst by novel β-MnO2 for low-temperature CO oxidation: study of the CO–O2 competitive adsorption and active oxygen species’ by Ningqiang Zhang et al., Catal. Sci. Technol., 2019, 9, 347–354, DOI: 10.1039/C8CY01879K.

scholarly journals CO Oxidation over Metal Oxide (La2O3, Fe2O3, PrO2, Sm2O3, and MnO2) Doped CuO-Based Catalysts Supported on Mesoporous Ce0.8Zr0.2O2 with Intensified Low-Temperature Activity

Catalysts ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 724 ◽  
Author(s):  
Yan Cui ◽  
Leilei Xu ◽  
Mindong Chen ◽  
Chufei Lv ◽  
Xinbo Lian ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Metal Oxide ◽  
Metal Oxides ◽  
Co Oxidation ◽  
Active Sites ◽  
Earth Metal ◽  
High Dispersion ◽  
Impregnation Method ◽  
X Ray

CuO-based catalysts are usually used for CO oxidation owing to their low cost and excellent catalytic activities. In this study, a series of metal oxide (La2O3, Fe2O3, PrO2, Sm2O3, and MnO2)-doped CuO-based catalysts with mesoporous Ce0.8Zr0.2O2 support were simply prepared by the incipient impregnation method and used directly as catalysts for CO catalytic oxidation. These mesoporous catalysts were systematically characterized by X-ray powder diffraction (XRD), N2 physisorption, transmission electron microscopy (TEM), energy-dispersed spectroscopy (EDS) mapping, X-ray photoelectron spectroscopy (XPS), and H2 temperature programmed reduction (H2-TPR). It was found that the CuO and the dopants were highly dispersed among the mesoporous framework via the incipient impregnation method, and the strong metal framework interaction had been formed. The effects of the types of the dopants and the loading amounts of the dopants on the low-temperature catalytic performances were carefully studied. It was concluded that doped transition metal oxides could regulate the oxygen mobility and reduction ability of catalysts, further improving the catalytic activity. It was also found that the high dispersion of rare earth metal oxides (PrO2, Sm2O3) was able to prevent the thermal sintering and aggregation of CuO-based catalysts during the process of calcination. In addition, their presence also evidently improved the reducibility and significantly reduced the particle size of the CuO active sites for CO oxidation. The results demonstrated that the 15CuO-3Fe2O3/M-Ce80Zr20 catalyst with 3 wt. % of Fe2O3 showed the best low-temperature catalytic activity toward CO oxidation. Overall, the present Fe2O3-doped CuO-based catalysts with mesoporous nanocrystalline Ce0.8Zr0.2O2 solid solution as support were considered a promising series of catalysts for low-temperature CO oxidation.

scholarly journals {CeO2/Bi2Mo1−xRuxO6} and {Au/Bi2Mo1−xRuxO6} Catalysts for Low-Temperature CO Oxidation

Catalysts ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 947 ◽  
Author(s):  
Edson Edain González ◽  
Ricardo Rangel ◽  
Javier Lara ◽  
Pascual Bartolo-Pérez ◽  
Juan José Alvarado-Gil ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Photoelectron Spectroscopy ◽  
Supported Catalysts ◽  
Pollutant Emissions ◽  
Impregnation Method ◽  
Wet Impregnation ◽  
X Ray ◽  
Low Temperature Co Oxidation ◽  
Carbon Dioxide Co2 ◽  
Wet Impregnation Method

Nowadays, one of the most important challenges that humanity faces is to find alternative ways of reducing pollutant emissions. CeO2/Bi2Mo1−xRuxO6 and Au/Bi2Mo1−xRuxO6 catalysts were prepared to efficiently transform carbon monoxide (CO) to carbon dioxide (CO2) at low temperatures. The systems were prepared in a two-step process. First, Bi2Mo1−xRuxO6 supports were synthesized through the hydrothermal procedure under microwave heating. Then, CeO2 was deposited on Bi2Mo1−xRuxO6 using the wet impregnation method, while the incipient impregnation method was selected to deposit gold nanoparticles. The CeO2/Bi2Mo1−xRuxO6 and Au/Bi2Mo1−xRuxO6 catalysts were characterized using SEM microscopy and XRD. Furthermore, energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy were used. Tests were carried out for the supported catalysts in CO oxidation, and high conversion values, nearing 100%, was observed in a temperature range of 100 to 250 °C. The results showed that the best system was the Au/Bi2Mo0.95Ru0.05O6 catalyst, with CO oxidation starting at 50 °C and reaching 100% conversion at 186 °C.

Effects of CO2 on the stability of Pd/CeO2–TiO2 catalyst for low-temperature CO oxidation

2009 ◽  
Vol 10 (5) ◽  
pp. 737-740 ◽  
Author(s):  
Feixue Liang ◽  
Huaqing Zhu ◽  
Zhangfeng Qin ◽  
Guofu Wang ◽  
Jianguo Wang
Keyword(s):  
Low Temperature ◽  
Co Oxidation ◽  
Tio2 Catalyst ◽  
Low Temperature Co Oxidation ◽  
The Stability

Highly water-resistant carbon nanotube supported PdCl2–CuCl2 catalysts for low temperature CO oxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 66553-66563 ◽  
Author(s):  
Fanyun Zhou ◽  
Xuexun Du ◽  
Jun Yu ◽  
Dongsen Mao ◽  
Guanzhong Lu
Keyword(s):  
Carbon Nanotube ◽  
Low Temperature ◽  
Physicochemical Properties ◽  
Co Oxidation ◽  
Catalytic Performance ◽  
Impregnation Method ◽  
Low Temperature Co Oxidation

PdCl2–CuCl2/CNT was prepared by the two-step impregnation method, and the effects of the Pd and Cu loadings on its physicochemical properties and catalytic performance for low-temperature CO oxidation in the presence of H2O were investigated.

scholarly journals Regulation of Cu Species in CuO/SiO2 and Its Structural Evolution in Ethynylation Reaction

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 842 ◽  
Author(s):  
Haitao Li ◽  
Lijun Ban ◽  
Zhipeng Wang ◽  
Pingfan Meng ◽  
Yin Zhang ◽  
...  
Keyword(s):  
Structural Evolution ◽  
High Dispersion ◽  
Impregnation Method ◽  
Initial Activity ◽  
Optimal Service ◽  
Nano Catalyst ◽  
Large Particles ◽  
Low Exposure ◽  
The Stability

A Cu-based nano-catalyst has been widely used in the ethynylation of formaldehyde; however, the effects of the presence of Cu on the reaction have not yet been reported. CuO/SiO2 catalysts with different Cu species were prepared by impregnation (IM), deposition–precipitation (DP), and ammonia evaporation (AE). The structural evolution of the Cu species in different states of the ethynylation reaction and the structure–activity relationship between the existence state of the Cu species and the catalytic properties of the ethynylation reaction were studied. The results show that the Cu species in the CuO/SiO2 (IM), prepared using the impregnation method, are in the form of bulk CuO, with large particles and no interactions with the support. The bulk CuO species are transformed into Cu+ with a low exposure surface at the beginning of the reaction, which is easily lost. Thus, this approach shows the lowest initial activity and poor cycle stability. A high dispersion of CuO and copper phyllosilicate exists in CuO/SiO2 (DP). The former makes the catalyst have the best initial activity, while the latter slows release, maintaining the stability of the catalyst. There is mainly copper phyllosilicate in CuO/SiO2 (AE), which is slowly transformed into a highly dispersed and stable Cu+ center in the in situ reaction. Although the initial activity of the catalyst is not optimal, it has the optimal service stability.

scholarly journals Atomically Dispersed Pd–O Species on CeO2(111) as Highly Active Sites for Low-Temperature CO Oxidation

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 6887-6891 ◽  
Author(s):  
Giulia Spezzati ◽  
Yaqiong Su ◽  
Jan P. Hofmann ◽  
Angelica D. Benavidez ◽  
Andrew T. DeLaRiva ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co Oxidation ◽  
Active Sites ◽  
Highly Active ◽  
Low Temperature Co Oxidation
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