Synthesis and Characterization of New Cyclam-Based Zr(IV) Alkoxido Derivatives

In this study, new mono- and di-alkoxido zirconium(IV) complexes supported by tetradentate dianionic cyclam ligands were synthesized and characterized. These compounds were obtained by reaction of the parent Zr(IV) dichlorido species with one or two equivalents of the corresponding lithium alkoxido, whereas (3,5-Me2Bn2Cyclam)Zr(OPh)2 was prepared by protonolysis of the orthometallated species (3,5-Me-C6H4CH2)2Cyclam)Zr with phenol. The solid-state molecular structures of (Bn2Cyclam)ZrCl(OtBu) and (4-tBuBn2Cyclam)Zr(OiPr)2 show a trigonal prismatic geometry around the metal centers. (Bn2Cyclam)Zr(SPh)(OtBu) and (Bn2Cyclam)ZrMe(OiPr) were prepared by reaction of (Bn2Cyclam)ZrCl(OR) (R = iPr, tBu) with one equivalent of LiSPh or MeMgCl, respectively. The reactions of (Bn2Cyclam)Zr(OiPr)2 and (4-tBuBn2Cyclam)Zr(OiPr)2 with carbon dioxide suggested the formation of species that correspond to the addition of four CO2 molecules.

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Synthesis and Characterization of a New Class of μ3-OH-Bridged Trimers That Contain Octahedrally Coordinated Divalent Metal Ions Bridged by Three Acetate Ligands and a Unique Catecholate Ligand. Solid State Molecular Structures of the [(py)5MII3(OAc)3(μ3-OH)((cat)] Complexes (M = Mn(II), Fe(II), Co(II), Ni(II))

Inorganic Chemistry ◽

10.1021/ic960097j ◽

1996 ◽

Vol 35 (10) ◽

pp. 2721-2722 ◽

Cited By ~ 47

Author(s):

R. A. Reynolds ◽

W. O. Yu ◽

W. R. Dunham ◽

D. Coucouvanis

Keyword(s):

Solid State ◽

Metal Ions ◽

Divalent Metal ◽

Molecular Structures ◽

Synthesis And Characterization ◽

Divalent Metal Ions ◽

New Class

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Synthesis and Characterization of a New Class of Asymmetric Aqua-Acetate Bridged Dimers. Solid State Molecular Structures of the [M2(.mu.-H2O)(.mu.-OAc)2(OAc)3(Py)2]- Anions (M = Mn(II), Fe(II), Co(II)). A Structural Model for the Fe2 Site in Methane Monooxygenase

Journal of the American Chemical Society ◽

10.1021/ja00133a041 ◽

1995 ◽

Vol 117 (28) ◽

pp. 7570-7571 ◽

Cited By ~ 39

Author(s):

D. Coucouvanis ◽

R. A. Reynolds ◽

W. R. Dunham

Keyword(s):

Solid State ◽

Structural Model ◽

Methane Monooxygenase ◽

Molecular Structures ◽

Synthesis And Characterization ◽

New Class

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Synthesis and characterization of intramolecularly coordinated alanes with new sterically demanding trisyl-based ligands

Canadian Journal of Chemistry ◽

10.1139/v07-063 ◽

2007 ◽

Vol 85 (7-8) ◽

pp. 483-490 ◽

Cited By ~ 2

Author(s):

Clinton L Lund ◽

Olimpiu Stanga ◽

J Wilson Quail ◽

Jens Müller

Keyword(s):

Solid State ◽

Molecular Structures ◽

Synthesis And Characterization ◽

Ortho Position ◽

Donor Group ◽

Pyridyl Group ◽

X Ray ◽

Sterically Demanding ◽

Derivatives Of

Five new intramolecularly coordinated aluminum species, whose molecular structures have been elucidated in solution by NMR spectroscopy and in the solid state by single crystal X-ray analysis, are described. All species are equipped with a trisyl-based ligand with a pyridyl donor group [Pytsi stands for -C(SiMe3)2SiMe2(2-C5H4N)]. While the compound (Pytsi)AlMeCl was accessible either from Li(THF)(Pytsi) and MeAlCl2 or from (Pytsi)AlCl2 and LiMe, the tert-butyl derivative (Pytsi)AltBuCl could only be obtained from Li(THF)(Pytsi) and tBuAlCl2. Attempted synthesis of (Pytsi)AltBuCl from (Pytsi)AlCl2 and LitBu or from (Pytsi)AlCl2 and tBuMgCl failed. Three other compounds (3-5) were synthesized and can be described as derivatives of (Pytsi)AlMe2 with additional groups in the ortho position of the pyridyl group. Compound 3 carried a Me group in the ortho position, while compounds 4 and 5 were equipped with Ph and 2,6-diisopropylphenyl moieties, respectively.Key words: aluminum, trisyl ligands, methyl alanes.

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Synthesis and Characterization of Temperature Controlled SnO2 Nanoparticles by Solid-state Reaction Method

Journal of Nano- and Electronic Physics ◽

10.21272/jnep.12(4).04004 ◽

2020 ◽

Vol 12 (4) ◽

pp. 04004-1-04004-6

Author(s):

Vijay Garg ◽

◽

Harsh Sharma ◽

Divya Rehani ◽

Renu Kumari ◽

...

Keyword(s):

Solid State ◽

Solid State Reaction ◽

Sno2 Nanoparticles ◽

Solid State Reaction Method ◽

Synthesis And Characterization ◽

Reaction Method ◽

Temperature Controlled

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Solid-state synthesis and characterization of two-dimensional hexagonal BCN nanosheet using a free template method

Diamond and Related Materials ◽

10.1016/j.diamond.2021.108350 ◽

2021 ◽

Vol 115 ◽

pp. 108350

Author(s):

Majid Mirzaee ◽

Alimorad Rashidi ◽

Ashkan Zolriasatein ◽

Majid Rezaei Abadchi

Keyword(s):

Solid State ◽

Solid State Synthesis ◽

Synthesis And Characterization ◽

Template Method ◽

Two Dimensional

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Synthesis and Characterization of a Composite Zeolite-Metglas Carbon Dioxide Sensor

Advanced Functional Materials ◽

10.1002/adfm.200400515 ◽

2005 ◽

Vol 15 (7) ◽

pp. 1165-1170 ◽

Cited By ~ 30

Author(s):

I. G. Giannakopoulos ◽

D. Kouzoudis ◽

C. A. Grimes ◽

V. Nikolakis

Keyword(s):

Carbon Dioxide ◽

Synthesis And Characterization ◽

Carbon Dioxide Sensor

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Synthesis and characterization of LAGP-glass-ceramics-based composite solid polymer electrolyte for solid-state Li-ion battery application

Journal of Non-Crystalline Solids ◽

10.1016/j.jnoncrysol.2021.120654 ◽

2021 ◽

Vol 558 ◽

pp. 120654

Author(s):

Anurup Das ◽

Madhumita Goswami ◽

Kavya Illath ◽

T.G. Ajithkumar ◽

A. Arya ◽

...

Keyword(s):

Solid State ◽

Solid Polymer Electrolyte ◽

Glass Ceramics ◽

Solid Polymer ◽

Synthesis And Characterization ◽

Li Ion Battery ◽

Li Ion ◽

Composite Solid ◽

Battery Application

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Synthesis and Characterization of the Hole-Conducting Silica/Polymer Nanocomposites and Application in Solid-State Dye-Sensitized Solar Cell

ACS Applied Materials & Interfaces ◽

10.1021/am4001858 ◽

2013 ◽

Vol 5 (10) ◽

pp. 4155-4161 ◽

Cited By ~ 65

Author(s):

Wen Yuan ◽

Hui Zhao ◽

Heyi Hu ◽

Shen Wang ◽

Gregory L. Baker

Keyword(s):

Solar Cell ◽

Solid State ◽

Polymer Nanocomposites ◽

Dye Sensitized Solar Cell ◽

Synthesis And Characterization ◽

Dye Sensitized

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Mechanochemical solid state synthesis and characterization of CdxZn1−xS nanocrystals

Solid State Ionics ◽

10.1016/j.ssi.2008.03.020 ◽

2008 ◽

Vol 179 (21-26) ◽

pp. 1242-1245 ◽

Cited By ~ 31

Author(s):

Erika Dutková ◽

Peter Baláž ◽

Parviz Pourghahramani ◽

Anh V. Nguyen ◽

Vladimír Šepelák ◽

...

Keyword(s):

Solid State ◽

Solid State Synthesis ◽

Synthesis And Characterization

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Synthesis and characterization of the binuclear diamido titanium chalcogenides [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, Te)

Canadian Journal of Chemistry ◽

10.1139/v02-052 ◽

2002 ◽

Vol 80 (11) ◽

pp. 1524-1529 ◽

Cited By ~ 2

Author(s):

Tianle Zhang ◽

Warren E Piers ◽

Masood Parvez

Keyword(s):

Solid State ◽

Key Words ◽

Synthesis And Characterization ◽

Catalyst Precursor ◽

Tellurium Atom ◽

Titanium Complex ◽

X Ray ◽

X Ray Crystallography ◽

Atom Source

Reaction of McConville's chelating amido titanium complex [(Ar)NCH2CH2CH2N(Ar)]Ti(CH3)2 (Ar = 2,6-i-Pr2C6H3) with either elemental Se or the tellurium atom source Te=PBu3 resulted in the formation of bis-µ-chalcogenido dimers [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, 2; Te, 3) with concommitant loss of EMe2. The dimers 2 and 3 were characterized spectroscopically and via X-ray crystallography. The two compounds are isostructural in the solid state. The tellurido dimer 3 may also be synthesized by reduction of the diamido dichloride [(Ar)NCH2CH2CH2N(Ar)]2TiCl2 with NaHg amalgam followed by treatment with Te=PBu3. This dimer is unreactive toward further Te=PBu3 or stannanes such as HSnBu3. Unlike decamethyltitanocene derivatives, the diamido complex is not an effective catalyst precursor for the heterohydrodecoupling of Te=PBu3 and HSnBu3.Key words: diamido titanium complexes, selenides, tellurides.

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