scholarly journals Quantification of Polychlorinated Biphenyl (PCB) Concentration in San Francisco Bay Using Satellite Imagery

2018 ◽  
Vol 10 (7) ◽  
pp. 1110 ◽  
Author(s):  
Annette Hilton ◽  
Jesse Bausell ◽  
Raphael Kudela

The U.S. Environmental Protection Agency banned the use of polychlorinated biphenyls (PCBs) in 1979, due to the high environmental and public health risks with which they are associated. However, PCBs continue to persist in the San Francisco Bay (SFB), often at concentrations deemed unsafe for humans. In situ PCB monitoring within the SFB is extremely limited, due in large part to the high monetary costs associated with sampling. Here we offer a cost effective alternative to in situ PCB monitoring by demonstrating the feasibility of indirectly quantifying PCBs in the SFB via satellite remote sensing using a two-step approach. First, we determined the relationship between in situ PCB concentrations and suspended sediment concentrations (SSC) in the SFB. We then correlated in situ SSC with spatially and temporally consistent Landsat 8 and Sentinel 2A reflectances. We demonstrate strong relationships between SSC and PCBs in all three SFB sub-embayments (R2 > 0.28–0.80, p < 0.01), as well as a robust relationship between SSC and satellite measurements for both Landsat 8 and Sentinel 2A (R2 > 0.72, p < 0.01). These relationships held regardless of the atmospheric correction regime that we applied. The end product of these relationships is an empirical two-step relationship capable of deriving PCBs from satellite imagery. Our approach of estimating PCBs in the SFB by remotely sensing SSC is extremely cost-effective when compared to traditional in situ techniques. Moreover, it can also be utilized to generate PCB concentration maps for the SFB. These maps could one day serve as an important tool for PCB remediation in the SFB, as they can provide valuable insight into the spatial distribution of PCBs throughout the bay, as well as how this distribution changes over time.

2021 ◽  
Vol 13 (1) ◽  
pp. 143
Author(s):  
Ksenia Nazirova ◽  
Yana Alferyeva ◽  
Olga Lavrova ◽  
Yuri Shur ◽  
Dmitry Soloviev ◽  
...  

The paper presents the results of a comparison of water turbidity and suspended particulate matter concentration (SPM) obtained from quasi-synchronous in situ and satellite remote-sensing data. Field measurements from a small boat were performed in April and May 2019, in the northeastern part of the Black Sea, in the mouth area of the Mzymta River. The measuring instruments and methods included a turbidity sensor mounted on a CTD (Conductivity, Temperature, Depth), probe, a portable turbidimeter, water sampling for further laboratory analysis and collecting meteorological information from boat and ground-based weather stations. Remote-sensing methods included turbidity and SPM estimation using the C2RCC (Case 2 Regional Coast Color) and Atmospheric correction for OLI ‘lite’ (ACOLITE) ACOLITE processors that were run on Landsat-8 Operational Land Imager (OLI) and Sentinel-2A/2B Multispectral Instrument (MSI) satellite data. The highest correlation between the satellite SPM and the water sampling SPM for the study area in conditions of spring flooding was achieved using C2RCC, but only for measurements undertaken almost synchronously with satellite imaging because of the high mobility of the Mzymta plume. Within the few hours when all the stations were completed, its boundary could shift considerably. The ACOLITE algorithms overestimated by 1.5 times the water sampling SPM in the low value range up to 15 g/m3. For SPM over 20–25 g/m3, a high correlation was observed both with the in situ measurements and the C2RCC results. It was demonstrated that quantitative turbidity and SPM values retrieved from Landsat-8 OLI and Sentinel-2A/2B MSI data can adequately reflect the real situation even using standard retrieval algorithms, not regional ones, provided the best suited algorithm is selected for the study region.


2021 ◽  
Vol 13 (10) ◽  
pp. 1927
Author(s):  
Fuqin Li ◽  
David Jupp ◽  
Thomas Schroeder ◽  
Stephen Sagar ◽  
Joshua Sixsmith ◽  
...  

An atmospheric correction algorithm for medium-resolution satellite data over general water surfaces (open/coastal, estuarine and inland waters) has been assessed in Australian coastal waters. In situ measurements at four match-up sites were used with 21 Landsat 8 images acquired between 2014 and 2017. Three aerosol sources (AERONET, MODIS ocean aerosol and climatology) were used to test the impact of the selection of aerosol optical depth (AOD) and Ångström coefficient on the retrieved accuracy. The initial results showed that the satellite-derived water-leaving reflectance can have good agreement with the in situ measurements, provided that the sun glint is handled effectively. Although the AERONET aerosol data performed best, the contemporary satellite-derived aerosol information from MODIS or an aerosol climatology could also be as effective, and should be assessed with further in situ measurements. Two sun glint correction strategies were assessed for their ability to remove the glint bias. The most successful one used the average of two shortwave infrared (SWIR) bands to represent sun glint and subtracted it from each band. Using this sun glint correction method, the mean all-band error of the retrieved water-leaving reflectance at the Lucinda Jetty Coastal Observatory (LJCO) in north east Australia was close to 4% and unbiased over 14 acquisitions. A persistent bias in the other strategy was likely due to the sky radiance being non-uniform for the selected images. In regard to future options for an operational sun glint correction, the simple method may be sufficient for clear skies until a physically based method has been established.


2019 ◽  
Vol 11 (15) ◽  
pp. 1744 ◽  
Author(s):  
Daniel Maciel ◽  
Evlyn Novo ◽  
Lino Sander de Carvalho ◽  
Cláudio Barbosa ◽  
Rogério Flores Júnior ◽  
...  

Remote sensing imagery are fundamental to increasing the knowledge about sediment dynamics in the middle-lower Amazon floodplains. Moreover, they can help to understand both how climate change and how land use and land cover changes impact the sediment exchange between the Amazon River and floodplain lakes in this important and complex ecosystem. This study investigates the suitability of Landsat-8 and Sentinel-2 spectral characteristics in retrieving total (TSS) and inorganic (TSI) suspended sediments on a set of Amazon floodplain lakes in the middle-lower Amazon basin using in situ Remote Sensing Reflectance (Rrs) measurements to simulate Landsat 8/OLI (Operational Land Imager) and Sentinel 2/MSI (Multispectral Instrument) bands and to calibrate/validate several TSS and TSI empirical algorithms. The calibration was based on the Monte Carlo Simulation carried out for the following datasets: (1) All-Dataset, consisting of all the data acquired during four field campaigns at five lakes spread over the lower Amazon floodplain (n = 94); (2) Campaign-Dataset including samples acquired in a specific hydrograph phase (season) in all lakes. As sample size varied from one season to the other, n varied from 18 to 31; (3) Lake-Dataset including samples acquired in all seasons at a given lake with n also varying from 17 to 67 for each lake. The calibrated models were, then, applied to OLI and MSI scenes acquired in August 2017. The performance of three atmospheric correction algorithms was also assessed for both OLI (6S, ACOLITE, and L8SR) and MSI (6S, ACOLITE, and Sen2Cor) images. The impact of glint correction on atmosphere-corrected image performance was assessed against in situ glint-corrected Rrs measurements. After glint correction, the L8SR and 6S atmospheric correction performed better with the OLI and MSI sensors, respectively (Mean Absolute Percentage Error (MAPE) = 16.68% and 14.38%) considering the entire set of bands. However, for a given single band, different methods have different performances. The validated TSI and TSS satellite estimates showed that both in situ TSI and TSS algorithms provided reliable estimates, having the best results for the green OLI band (561 nm) and MSI red-edge band (705 nm) (MAPE < 21%). Moreover, the findings indicate that the OLI and MSI models provided similar errors, which support the use of both sensors as a virtual constellation for the TSS and TSI estimate over an Amazon floodplain. These results demonstrate the applicability of the calibration/validation techniques developed for the empirical modeling of suspended sediments in lower Amazon floodplain lakes using medium-resolution sensors.


2018 ◽  
Vol 10 (11) ◽  
pp. 1841 ◽  
Author(s):  
Quang Pham ◽  
Nguyen Ha ◽  
Nima Pahlevan ◽  
La Oanh ◽  
Thanh Nguyen ◽  
...  

Analyzing the trends in the spatial distribution of suspended sediment concentration (SSC) in riverine surface water enables better understanding of the hydromorphological properties of its watersheds and the associated processes. Thus, it is critical to identify an appropriate method to quantify spatio-temporal variability in SSC. This study aims to estimate SSC in a highly turbid river, i.e., the Red River in Northern Vietnam, using Landsat 8 (L8) images. To do so, in situ radiometric data together with SSC at 60 sites along the river were measured on two different dates during the dry and wet seasons. Analyses of the in situ data indicated strong correlations between SSC and the band-ratio of green and red channels, i.e., r-squared = 0.75 and a root mean square error of ~0.3 mg/L. Using a subsample of in situ radiometric data (n = 30) collected near-concurrently with one L8 image, four different atmospheric correction methods were evaluated. Although none of the methods provided reasonable water-leaving reflectance spectra (ρw), it was found that the band-ratio of the green-red ratio is less sensitive to uncertainties in the atmospheric correction for mapping SSC compared to individual bands. Therefore, due to its ease of access, standard L8 land surface reflectance products available via U.S. Geological Survey web portals were utilized. With the empirical relationship derived, we produced Landsat-derived SSC distribution maps for a few images collected in wet and dry seasons within the 2013–2017 period. Analyses of image products suggest that (a) the Thao River is the most significant source amongst the three major tributaries (Lo, Da and Thao rivers) providing suspended load to the Red River, and (b) the suspended load in the rainy season is nearly twice larger than that in the dry season, and it correlates highly with the runoff (correlation coefficient = 0.85). Although it is demonstrated that the atmospheric correction in tropical areas over these sediment-rich waters present major challenges in the retrievals of water-leaving reflectance spectra, the study signifies the utility of band-ratio techniques for quantifying SSC in highly turbid river waters. With Sentinel-2A/B data products combined with those of Landsat-8, it would be possible to capture temporal variability in major river systems in the near future.


Author(s):  
Iryna Piestova ◽  
Mykola Lubskyi ◽  
Mykhailo Svideniuk ◽  
Stanislav Golubov ◽  
Oleksandr Laptiev

The aim of this research is to enhance approaches existing for the assessment of cities thermal conditions under climate change impact by using multispectral satellite data for Kyiv city area. This paper describes the method and results of the Earth’s surface temperature (LST) and thermal emissivity calculation. Particularly, the thermal distribution was estimated based on spectral densities according to Planck’s law for “grey bodies” by using the Landsat-8 TIRS and Sentinel-2 MSI satellite imagery. Furthermore, the result was calibrated by ground data collected during the ground-truth measurements of the typical city surfaces temperature and thermal emissivity. The spatial resolution of the LST images obtained was enhanced by using the approach of subpixel processing, that is the pairs of invariant images shifted with subpixel accuracy. As a result, such an approach allowed to enhance the spatial resolution of the image up 46%, which is much higher than the potential performance of the thermal imaging sensors existing. The interrelation between the Earth’s surface type and the temperature was revealed by the results of the Sentinel-2A MSI image of 21 August 2017 supervised classification. Thus, the image was divided into the six major classes of the urban environment: building’s rooftops, roads surface, bare soil, grass, wood, and water. As a result, surfaces with vegetation much more cool next to artificial ones. The time-series analysis of 18 thermal images (Landsat TM and Landsat-8 TIRS) of Kyiv for the period from 6 Jun 1985 till 1 June 2018 was done for spatiotemporal changes investigation. Therefore, the sites of the LST thermal anomalies caused by landscape changes were developed. Among them are the sites of increased LST where thw “Olimpiyskiy” national sport center and adjacent parking was built and the site of decreased LST where the tram depot was liquidated and the territory was flooded.


2004 ◽  
Vol 4 (5) ◽  
pp. 6645-6665
Author(s):  
E. C. Wood ◽  
T. H. Bertram ◽  
P. J. Wooldridge ◽  
R. C. Cohen

Abstract. We report in situ measurements of N2O5, NO2, and O3 in Contra Costa County, California during January 2004. Mixing ratios of N2O5, an intermediate compound in the atmosphere's nocturnal cleansing process, ranged up to 200 pmol/mol at night. The highest N2O5 concentrations were correlated with low O3 and high NO2 concentrations. The calculated steady state lifetime for N2O5 ranged from 5 to 30 min. The total HNO3 produced by N2O5 hydrolysis over a 14 h night was comparable to ambient NO2 concentrations, and is estimated to be a factor of nine bigger than the HNO3 produced during the day.


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