scholarly journals Experimental Study on the Interplay between Different Brine Types/Concentrations and CO2 Injectivity for Effective CO2 Storage in Deep Saline Aquifers

2022 ◽  
Vol 14 (2) ◽  
pp. 986
Author(s):  
Donatus Ephraim Edem ◽  
Muhammad Kabir Abba ◽  
Amir Nourian ◽  
Meisam Babaie ◽  
Zainab Naeem
Keyword(s):  
Carbon Storage ◽  
Oil Recovery ◽  
Co2 Storage ◽  
Saline Aquifers ◽  
Core Flooding ◽  
Salt Precipitation ◽  
Co2 Solubility ◽  
Mixed Salt ◽  
Sandstone Sample ◽  
Deep Saline Aquifers

Salt precipitation during CO2 storage in deep saline aquifers can have severe consequences on injectivity during carbon storage. Extensive studies have been carried out on CO2 solubility with individual or mixed salt solutions; however, to the best of the authors’ knowledge, there is no substantial study to consider pressure decay rate as a function of CO2 solubility in brine, and the range of brine concentration for effective CO2 storage. This study presents an experimental core flooding of the Bentheimer sandstone sample under simulated reservoir conditions to examine the effect of four different types of brine at a various ranges of salt concentration (5 to 25 wt.%) on CO2 storage. Results indicate that porosity and permeability reduction, as well as salt precipitation, is higher in divalent brines. It is also found that, at 10 to 20 wt.% brine concentrations in both monovalent and divalent brines, a substantial volume of CO2 is sequestered, which indicates the optimum concentration ranges for storage purposes. Hence, the magnitude of CO2 injectivity impairment depends on both the concentration and type of salt species. The findings from this study are directly relevant to CO2 sequestration in deep saline aquifers as well as screening criteria for carbon storage with enhanced gas and oil recovery processes.

scholarly journals Chemistry of Reservoir Fluids in the Aspect of CO2 Injection for Selected Oil Reservoirs in Poland

Energies ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 6456
Author(s):  
Ewa Knapik ◽  
Katarzyna Chruszcz-Lipska
Keyword(s):  
Oil Recovery ◽  
Carbon Capture ◽  
Co2 Storage ◽  
Carbon Capture And Storage ◽  
Oil Reservoirs ◽  
Co2 Injection ◽  
Oil Composition ◽  
Co2 Solubility ◽  
Geological Co2 Storage ◽  
Reservoir Conditions

Worldwide experiences related to geological CO2 storage show that the process of the injection of carbon dioxide into depleted oil reservoirs (CCS-EOR, Carbon Capture and Storage—Enhanced Oil Recovery) is highly profitable. The injection of CO2 will allow an increasing recovery factor (thus increasing CCS process profitability) and revitalize mature reservoirs, which may lead to oil spills due to pressure buildups. In Poland, such a solution has not yet been implemented in the industry. This work provides additional data for analysis of the possibility of the CCS-EOR method’s implementation for three potential clusters of Polish oil reservoirs located at a short distance one from another. The aim of the work was to examine the properties of reservoir fluids for these selected oil reservoirs in order to assure a better understanding of the physicochemical phenomena that accompany the gas injection process. The chemical composition of oils was determined by gas chromatography. All tested oils represent a medium black oil type with the density ranging from 795 to 843 g/L and the viscosity at 313 K, varying from 1.95 to 5.04 mm/s. The content of heavier components C25+ is up to 17 wt. %. CO2–oil MMP (Minimum Miscibility Pressure) was calculated in a CHEMCAD simulator using the Soave–Redlich–Kwong equation of state (SRK EoS). The oil composition was defined as a mixture of n-alkanes. Relatively low MMP values (ca. 8.3 MPa for all tested oils at 313 K) indicate a high potential of the EOR method, and make this geological CO2 storage form more attractive to the industry. For reservoir brines, the content of the main ions was experimentally measured and CO2 solubility under reservoir conditions was calculated. The reservoir brines showed a significant variation in properties with total dissolved solids contents varying from 17.5 to 378 g/L. CO2 solubility in brines depends on reservoir conditions and brine chemistry. The highest calculated CO2 solubility is 1.79 mol/kg, which suggest possible CO2 storage in aquifers.

A Laboratory and Numerical-Simulation Study of Co-Optimizing CO2 Storage and CO2 Enhanced Oil Recovery

SPE Journal ◽  
2015 ◽  
Vol 20 (06) ◽  
pp. 1227-1237 ◽  
Author(s):  
Fatemeh Kamali ◽  
Furqan Hussain ◽  
Yildiray Cinar
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Co2 Storage ◽  
Immiscible Displacement ◽  
Sandstone Sample ◽  
Miscible Displacements ◽  
Gravity Effects ◽  
Optimization Function ◽  
Carbon Dioxide Co2 ◽  
And Storage

Summary This paper presents experimental observations that delineate co-optimization of carbon dioxide (CO2) enhanced oil recovery (EOR) and storage. Pure supercritical CO2 is injected into a homogeneous outcrop sandstone sample saturated with oil and immobile water under various miscibility conditions. A mixture of hexane and decane is used for the oil phase. Experiments are run at 70°C and three different pressures (1,300, 1,700, and 2,100 psi). Each pressure is determined by use of a pressure/volume/temperature simulator to create immiscible, near-miscible, and miscible displacements. Oil recovery, differential pressure, and compositions are recorded during experiments. A co-optimization function for CO2 storage and incremental oil is defined and calculated using the measured data for each experiment. A compositional reservoir simulator is then used to examine gravity effects on displacements and to derive relative permeabilities. Experimental observations demonstrate that almost similar oil recovery is achieved during miscible and near-miscible displacements whereas approximately 18% less recovery is recorded in the immiscible displacement. More heavy component (decane) is recovered in the miscible and near-miscible displacements than in the immiscible displacement. The co-optimization function suggests that the near-miscible displacement yields the highest CO2-storage efficiency and displays the best performance for coupling CO2 EOR and storage. Numerical simulations show that, even on the laboratory scale, there are significant gravity effects in the near-miscible and miscible displacements. It is revealed that the near-miscible and miscible recoveries depend strongly on the endpoint effective CO2 permeability.

scholarly journals Modeling of Carbon Dioxide Leakage from Storage Aquifers

Fluids ◽  
2018 ◽  
Vol 3 (4) ◽  
pp. 80 ◽  
Author(s):  
Parvaneh Heidari ◽  
Hassan Hassanzadeh
Keyword(s):  
Driving Forces ◽  
Mechanistic Model ◽  
Co2 Storage ◽  
Transport Processes ◽  
Saline Aquifers ◽  
Storage Site ◽  
Geological Storage ◽  
Co2 Leakage ◽  
Deep Saline Aquifers ◽  
The Impact

Long-term geological storage of CO2 in deep saline aquifers offers the possibility of sustaining access to fossil fuels while reducing emissions. However, prior to implementation, associated risks of CO2 leakage need to be carefully addressed to ensure safety of storage. CO2 storage takes place by several trapping mechanisms that are active on different time scales. The injected CO2 may be trapped under an impermeable rock due to structural trapping. Over time, the contribution of capillary, solubility, and mineral trapping mechanisms come into play. Leaky faults and fractures provide pathways for CO2 to migrate upward toward shallower depths and reduce the effectiveness of storage. Therefore, understanding the transport processes and the impact of various forces such as viscous, capillary and gravity is necessary. In this study, a mechanistic model is developed to investigate the influence of the driving forces on CO2 migration through a water saturated leakage pathway. The developed numerical model is used to determine leakage characteristics for different rock formations from a potential CO2 storage site in central Alberta, Canada. The model allows for preliminary analysis of CO2 leakage and finds applications in screening and site selection for geological storage of CO2 in deep saline aquifers.

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