scholarly journals Produced Water Desalination via Pervaporative Distillation

Water ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3560
Author(s):  
Jingbo Wang ◽  
Dian Tanuwidjaja ◽  
Subir Bhattacharjee ◽  
Arian Edalat ◽  
David Jassby ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Produced Water ◽  
Operating Mode ◽  
Porous Membrane ◽  
Membrane Distillation ◽  
Operating Conditions ◽  
Water Desalination ◽  
Feed Water ◽  
Water Composition ◽  
Salt Passage

Herein, we report on the performance of a hybrid organic-ceramic hydrophilic pervaporation membrane applied in a vacuum membrane distillation operating mode to desalinate laboratory prepared saline waters and a hypersaline water modeled after a real oil and gas produced water. The rational for performing “pervaporative distillation” is that highly contaminated waters like produced water, reverse osmosis concentrates and industrial have high potential to foul and scale membranes, and for traditional porous membrane distillation membranes they can suffer pore-wetting and complete salt passage. In most of these processes, the hard to treat feed water is commonly softened and filtered prior to a desalination process. This study evaluates pervaporative distillation performance treating: (1) NaCl solutions from 10 to 240 g/L at crossflow Reynolds numbers from 300 to 4800 and feed-temperatures from 60 to 85 °C and (2) a real produced water composition chemically softened to reduce its high-scale forming mineral content. The pervaporative distillation process proved highly-effective at desalting all feed streams, consistently delivering <10 mg/L of dissolved solids in product water under all operating condition tested with reasonably high permeate fluxes (up to 23 LMH) at optimized operating conditions.

An Eco-Friendly and Low Carbon Footprint Water Treatment Technology for Produced Water Recycling

2021 ◽  
Author(s):  
Abdulrahman Aljedaani ◽  
Mohammed AlOtaibi ◽  
Subhash Ayirala ◽  
Ali Al-Yousef
Keyword(s):  
Oil And Gas ◽  
Produced Water ◽  
Waste Heat ◽  
Operating Cost ◽  
Water Desalination ◽  
Oil Fields ◽  
Feed Water ◽  
Low Carbon ◽  
Gas Wells ◽  
Oil And Gas Wells

Abstract Many challenges and limitations are experienced while treating the produced water in oil fields, due to large volumes of water produced together with oil. In this paper, we propose a new method to treat produced water, by integrating humidification and de-humidification desalination (HDH) unit with waste heat, extracted from abandoned oil and gas wells. This solution is based on circulating the produced water through abandoned wells (both vertical and horizontal wells) and heat them up to 60-80°C so that the heated water can be directly used as hot feed water into the HDH unit. This eliminates either electricity or power requirements from an external source thereby significantly lowering the energy requirements. The direct use of hot produced water at the desired temperature range allows for better performance of the HDH desalination unit, while reducing the operating cost, besides minimizing CO2 emissions to the environment. The use of heat extracted from abandoned oil and gas wells in the form of geothermal energy enables the utilization of waste heat associated with existing wells, which is already available in most of the oil fields. The proposed method therefore provides a sustainable renewable energy solution for produced water desalination using HDH processes.

scholarly journals Highly Saline Water Desalination Using Direct Contact Membrane Distillation (DCMD): Experimental and Simulation Study

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1575 ◽  
Author(s):  
Noor A. Mohammad Ameen ◽  
Salah S. Ibrahim ◽  
Qusay F. Alsalhy ◽  
Alberto Figoli
Keyword(s):  
Mass Transfer ◽  
Direct Contact ◽  
Saline Water ◽  
Membrane Distillation ◽  
Operating Conditions ◽  
Water Desalination ◽  
System Of Nonlinear Equations ◽  
Transfer Model ◽  
Transfer Resistance ◽  
Direct Contact Membrane Distillation

The path for water molecules transported across a membrane in real porous membranes has been considered to be a constant factor in the membrane distillation (MD) process (i.e., constant tortuosity); as such, its effect on membrane performance at various operating conditions has been ignored by researchers. Therefore, a simultaneous heat and mass transfer model throughout the direct contact membrane distillation (DCMD) module was developed in this study by taking into account the hypothetical path across the membrane as a variable factor within the operating conditions because it exhibits the changes to the mass transfer resistance across the membrane under the DCMD run. The DCMD process was described by the developed model using a system of nonlinear equations and solved numerically by MATLAB software. The performance of the poly-tetra-fluoroethylene (PTFE) membrane was examined to treat 200 g/L NaCl saline at various operating conditions. The simulation results in the present work showed that the hypothetical proposed path across the membrane has a variable value and was affected by changing the feed temperature and feed concentration. The results estimated by the developed model showed an excellent conformity with the experimental results. The salt rejection remained high (greater than 99.9%) in all cases. The temperature polarization coefficient for the DCMD ranged between 0.88 and 0.967, and the gain output ratio (GOR) was 0.893. The maximum thermal efficiency of the system was 84.5%.

Membrane Distillation Desalination System With Gap Circulation and Cooling Using a Built-in Heat Exchanger

2020 ◽  
Vol 143 (1) ◽  
Author(s):  
Atia E. Khalifa
Keyword(s):  
Energy Consumption ◽  
Heat Exchanger ◽  
Specific Energy Consumption ◽  
Membrane Distillation ◽  
Operating Conditions ◽  
Water Desalination ◽  
Module Design ◽  
Membrane Surfaces ◽  
Best Value ◽  
Feed Temperature

Abstract A comprehensive experimental investigation is conducted to evaluate the performance of a new flux-enhanced compact water gap membrane distillation (WGMD) module design with gap circulation and cooling for water desalination. The new design uses a separate circulation loop to circulate the gap water, and a built-in heat exchanger coil implanted inside the coolant stream channel for cooling the circulated gap water. The WGMD modules with circulation and with circulation and cooling are compared with conventional WGMD without circulation. Variations of distillate flux, temperatures, and energy consumption are presented at different design operating conditions. Circulation and cooling of the gap water greatly enhance the output flux due to gap water motion and increase the temperature difference between membrane surfaces. However, the enhancement in flux was achieved at the expense of energy consumption. Circulation and cooling of gap water are more effective with bigger gap widths. Feed flowrate showed significant effects with gap water circulation and cooling. The electrical specific energy consumption (SEC) showed the best value of 7.9 and 8.8 kWh/m3 at a feed temperature of 70 °C for both conventional WGMD and WGMD with circulation modules, while the best value of SEC for the WGMD module with gap circulation and cooling was 9.4 kWh/m3 at a feed temperature of 80 °C.

scholarly journals An Experimental and Theoretical Study on Separations by Vacuum Membrane Distillation Employing Hollow-Fiber Modules

Water ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 947 ◽  
Author(s):  
Anthoula Karanasiou ◽  
Margaritis Kostoglou ◽  
Anastasios Karabelas
Keyword(s):  
Process Model ◽  
Flow Direction ◽  
Membrane Distillation ◽  
Water Desalination ◽  
Solution Temperature ◽  
Feed Water ◽  
System Productivity ◽  
Capillary Membrane ◽  
Vacuum Membrane Distillation ◽  
By Products

Vacuum membrane distillation (VMD) is an attractive variant of the novel membrane distillation process, which is promising for various separations, including water desalination and bioethanol recovery through fermentation of agro-industrial by-products. This publication is part of an effort to develop a capillary membrane module for various applications, as well as a model that would facilitate VMD process design. Experiments were conducted in a laboratory pilot VMD unit, comprising polypropylene capillary-membrane modules. Performance data, collected at modest temperatures (37 °C to 65 °C) with deionized and brackish water, confirmed the improved system productivity with increasing feed-water temperature; excellent salt rejection was obtained. The recovery of ethanol from ethanol-water mixtures and from fermented winery by-products was also studied, in continuous, semi-continuous, and batch operating modes. At low-feed-solution temperature (27–47 °C), ethanol-solution was concentrated 4 to 6.5 times in continuous operation and 2 to 3 times in the semi-continuous mode. Taking advantage of the small property variation in the module axial-flow direction, a simple VMD process model was developed, satisfactorily describing the experimental data. This VMD model appears to be promising for practical applications, and warrants further R&D work.

scholarly journals Desalination of Produced Water by Membrane Distillation: Effect of the Feed Components and of a Pre-treatment by Fenton Oxidation

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Francesco Ricceri ◽  
Mattia Giagnorio ◽  
Giulio Farinelli ◽  
Giulia Blandini ◽  
Marco Minella ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Produced Water ◽  
Membrane Distillation ◽  
Fenton Oxidation ◽  
Produced Waters ◽  
Pre Treatment ◽  
High Concentrations ◽  
Membrane Wetting ◽  
By Products

Abstract The treatment of produced waters (by-products of oil and gas extraction) with the innovative process of membrane distillation is challenging, because these highly saline streams contain high concentrations of organic compounds and hydrocarbons that cause membrane wetting and impairment of performance. To design the most compact treatment scheme and with the aim of obtaining an easier management of produced water for reuse purposes, Fenton oxidation is here investigated as a feed pre-treatment that may produce an effluent easily handled by membrane distillation. In high-recovery membrane distillation tests, we systematically investigate the detrimental effects of individual contaminants in a synthetic produced water mimicking the composition of a real sample. The recovery rate depends strongly on the initial salinity, which eventually causes scaling and pore blocking. Surfactants are found to be mainly responsible for membrane wetting, but volatile and hydrophobic organics also spoil the quality of the product water. A Fenton oxidation pre-treatment is thus performed to degrade the target organics, with the aim of enhancing the effectiveness of the following membrane distillation and to improve the quality of the final product. The combined oxidation-membrane distillation scheme has both advantages and limitations, which need to be carefully evaluated and further investigated.

scholarly journals Performance evaluation of the different nano-enhanced polysulfone membranes via membrane distillation for produced water desalination in Sert Basin-Libya

2020 ◽  
Vol 13 (4) ◽  
pp. 5118-5136
Author(s):  
Osamah M.A. Shahlol ◽  
Heba Isawi ◽  
Mohamed G. El-Malky ◽  
Abd El-Hameed M. Al-Aassar ◽  
Adel El zwai
Keyword(s):  
Performance Evaluation ◽  
Produced Water ◽  
Membrane Distillation ◽  
Water Desalination ◽  
Polysulfone Membranes

scholarly journals Resistance of Polypropylene Membrane to Oil Fouling during Membrane Distillation

Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 552
Author(s):  
Marek Gryta
Keyword(s):  
Membrane Distillation ◽  
Water Desalination ◽  
Feed Water ◽  
Permeate Flux ◽  
Feed Composition ◽  
Oil Emulsion ◽  
Thermally Induced ◽  
Polypropylene Membrane ◽  
Capillary Membranes ◽  
The Impact

The influence of oil emulsion presence in the water on the course of water desalination by membrane distillation was studied. The feed water was contaminated by oil collected from the bilge water. The impact of feed composition on the wetting resistance of hydrophobic polypropylene membranes was evaluated during long-term studies. Two types of the capillary membranes fabricated by thermally induced phase separation method were tested. It has been found that these membranes were non-wetted during the separation of NaCl solutions over a period of 500 h of modules exploitation. The addition of oil (5–100 mg/L) to the feed caused a progressive decline of the permeate flux up to 30%; however, the applied hydrophobic membranes retained their non-wettability for the consecutive 2400 h of the process operation. It was indicated that several compounds containing the carbonyl group were formed on the membranes surface during the process. These hydrophilic compounds facilitated the water adsorption on the surface of polypropylene which restricted the oil deposition on the membranes used.

scholarly journals Initial recognition of the possibilities of use abandoned oil and gas wells to desalinate produced water

2020 ◽  
Vol 154 ◽  
pp. 05002
Author(s):  
Magdalena Tyszer ◽  
Anna Chmielowska ◽  
Barbara Tomaszewska
Keyword(s):  
Oil And Gas ◽  
Produced Water ◽  
Production Method ◽  
High Energy ◽  
Water Desalination ◽  
World Knowledge ◽  
Gas Wells ◽  
New Production ◽  
Geothermal Heat ◽  
Oil And Gas Wells

Diminishing water resources, population growth and utilization energy intense processes for drinking water production lead to seek new methods of water acquisition. Desalination of seawater or/and geothermal water and also water acquisition with the utilization of abandoned oil and gas wells potentially represents promising new production method of freshwater streams. Abandoned oil and gas wells potentially can be a source of geothermal heat which can be used as a heat source for water desalination. In many countries, among others in Poland area, there are hundreds, and even thousands of abandoned exploration, research or oil/gas wells which can be adapted for other purposes, including water desalination. The aim of this paper is to conduct preliminary recognition of current world knowledge on the possibility of using abandoned oil and gas wells for geothermal purposes, including desalination of produced waters (also for drinking purposes) based on selected examples (Iran and USA). This technique is environmental-friendly and provides enough amount of energy for high-energy desalination processes (e.g. reverse osmosis), along with reducing gas emissions and consumption of conventional fuels. Based on world experience, a comprehensive assessment of the possibility of using abandoned wells for geothermal purposes in Poland should be carried out.

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