Chemicals used for treatment of water intended for human consumption. Chlorine dioxide

2000 ◽  
Author(s):  
C. Lasagna ◽  
E. Raffo ◽  
M. Bianchi ◽  
L. Pocaterra

Since the 1970s it has been well known that, though water for human consumption is generally disinfected before being distributed along the network, the use of chemicals results in the formation of many different Disinfection By-Products (DBPs). In the case of chlorine dioxide, the most important and represented DBPs are chlorite and chlorate: after an introduction concerning the current Italian regulation on this subject, in the experimental part the results of a 7-year minitoring campaign, concerning water of different origin collected from taps in various Italian regions, are shown. The analytical technique used for the determination of chlorite and chlorate was Ion Chromatography. The result obtained are finally discussed.


2020 ◽  
Author(s):  
Mohammed A Mostajo-Radji

The COVID-19 pandemic has affected the economic and political landscape of the world (Greer et al., 2020). Low- and middle-income countries (LMICs) have been particularly vulnerable to the effects of the disease (Breevoort et al., 2020; Dahab et al., 2020; Elhadi, et al., 2020; Loayza and Pennings, 2020). In many regions, including Africa and Latin America, the role of traditional media, as well as social media has been important to disseminate information related to disease containment and treatment (Hopman et al., 2020). Yet, these tools have also been used to spread misinformation and support pseudoscientific ideals masked as “miracle cures” for COVID-19 (Malinverni and Brigagão 2020; Oliveira et al., 2020; Pereira et al., 2020).Chlorine dioxide is a disinfectant commonly used to clean medical equipment and treat residual waters (Smith et al., 2001). At high concentrations and non-physiological pH, it has been shown that treating surfaces with chlorine dioxide effectively inhibits microbial and viral activity (Hauchman et al., 1986; Zoffoli et al., 2005). To date, no controlled studies have been done to evaluate the toxicity of this compound in human subjects. However, exposing rats and nonhuman primates to chlorine dioxide resulted in dose-dependent nonchronic toxicity through thyroid suppression (Abdel-Rahman et al., 1984; Bercz et al., 1982; Harrington et al., 1986; Orme et al., 1985), as well as DNA damage and neurotoxicity in the cerebral cortex (Toth et al, 1990). It is therefore understood that chlorine dioxide is not safe for human consumption. In a self-published book, chlorine dioxide proponent Jim Humble has taunted the use of this compound to treat at variety of diseases, ranging from cancer to HIV, calling it “Miracle Mineral Solution” (MMS) (Humble, 2006). More recently, chlorine dioxide has been suggested to be an inexpensive preventive and treatment for COVID-19 (Burela et al., 2020; Galloso, 2020; Karnik-Henry, 2020; Oliveira et al., 2020). Yet, no scientific evidence has ever been provided to support any of these claims (Burela et al., 2020; Galloso, 2020). On the contrary, several studies have reported a series of concerning symptoms due to MMS intoxication (Bathina et al., 2003; Daniel et al., 2014; Hulshof et al., 2019; Lardieri et al., 2020; Li and Lim, 1993; Loh and Shafi, 2014). These studies highlight the importance of caution in adopting unproven therapies, particularly in regions with weak medical systems.Here I use chlorine dioxide as an example of dissemination of pseudoscience in Latin America in the context of COVID-19. I then describe the adoption and manipulation of chlorine dioxide in Bolivia, where it was used by a political party as a tool to destabilize the constitutional government in view of the 2020 presidential elections.


2016 ◽  
Vol 2 (1) ◽  
pp. 22-25
Author(s):  
Nur Amalina binti Mustafa ◽  
Muhammad Ashraf bin Redzuan ◽  
Muhamad Hazim bin Zuraimi ◽  
Muhamad Shuhaimi bin Shuib ◽  
Shahnaz Majeed ◽  
...  

Objective: Owing to the habit of consuming ready food among the citizens of Malaysia a study was conducted to evaluate 20 samples of canned soya milk for the presence of possible microbial content. The samples were collected randomly from shopping malls, restaurants and kiosk in Ipoh Malaysia. Methods: All samples collected across Ipoh, were subjected to test for presence bacteria in nutrient agar, blood agar and macConkey media. The possible microbial load was swapped from surface and soya milk content with a sterile cotton and streaked on nutrient agar, blood agar and macConkey culture media. The streaked petri plates were incubated for 48 hours at 37oC. Results: The study revealed negative microbial growth in all except two samples from the surface and soya milk content collected from a restaurant in nutrient agar and blood agar medium. The presence of microbes was conformed as gram positive staphylococcus sp. through gram staining. The positive growth may be imputed to poor storage condition at the restaurant. Conclusion: It can be computed from the study that the majority of the samples were free from bacterial growth, suggesting strong in house quality control mechanism at the processing unit and exquisite storage conditions in malls and kiosk suggesting that soya milk available in malls and kiosk are fit for human consumption.


TAPPI Journal ◽  
2013 ◽  
Vol 12 (10) ◽  
pp. 33-41 ◽  
Author(s):  
BRIAN N. BROGDON

This investigation evaluates how higher reaction temperatures or oxidant reinforcement of caustic extraction affects chlorine dioxide consumption during elemental chlorine-free bleaching of North American hardwood pulps. Bleaching data from the published literature were used to develop statistical response surface models for chlorine dioxide delignification and brightening sequences for a variety of hardwood pulps. The effects of higher (EO) temperature and of peroxide reinforcement were estimated from observations reported in the literature. The addition of peroxide to an (EO) stage roughly displaces 0.6 to 1.2 kg chlorine dioxide per kilogram peroxide used in elemental chlorine-free (ECF) bleach sequences. Increasing the (EO) temperature by Δ20°C (e.g., 70°C to 90°C) lowers the overall chlorine dioxide demand by 0.4 to 1.5 kg. Unlike what is observed for ECF softwood bleaching, the presented findings suggest that hot oxidant-reinforced extraction stages result in somewhat higher bleaching costs when compared to milder alkaline extraction stages for hardwoods. The substitution of an (EOP) in place of (EO) resulted in small changes to the overall bleaching cost. The models employed in this study did not take into account pulp bleaching shrinkage (yield loss), to simplify the calculations.


TAPPI Journal ◽  
2015 ◽  
Vol 14 (11) ◽  
pp. 689-694
Author(s):  
QINGZHI MA ◽  
QI WANG ◽  
CHU WANG ◽  
NIANJIE FENG ◽  
HUAMIN ZHAI

The effect of oxygen (O2)-delignified pine kraft pulp pretreatment by high-purity, thermostable, and alkaline-tolerant xylanases on elemental chlorine free (ECF) bleaching of O2-delignification kraft pulp was studied. The study found that xylanase pretreatment preserved the intrinsic viscosity and yield of O2-delignified pulp while causing about 7% of delignification with high delignification selectivity. The xylanases with high purity, higher thermostability (75°C~80°C) in highly alkaline media (pH 8.0~9.5) could be applied on an industrial scale. Pulp pretreatment by the high-purity, thermostable, and alkaline tolerant xylanases could improve pulp brightness or reduce the chlorine dioxide (ClO2) consumption. In a D0ED1D2 bleaching sequence using the same amount of ClO2, the xylanase-pretreated pulp obtained a higher brightness (88.2% vs. 89.7% ISO) at the enzyme dose of 2 U/g pulp; or for the same brightness as control (88.2% ISO), the ClO2 dosage in the D0 stage was reduced by 27%, which represents a 16% savings in total ClO2 used for bleaching.


TAPPI Journal ◽  
2010 ◽  
Vol 9 (9) ◽  
pp. 47-53 ◽  
Author(s):  
BRIAN N. BROGDON

Our previous investigation [1] re-analyzed the data from Basta and co-workers (1992 TAPPI Pulping Conference) to demonstrate how oxidative alkaline extraction can be augmented and how these changes affect chlorine dioxide consumption with elemental chlorine-free (ECF) sequences. The current study manipulates extraction delignification variables to curtail bleaching costs with a conventional U.S. Southern softwood kraft pulp. The economic advantages of ~0.35% to 0.65% H2O2 peroxide reinforcement in a 70°C (EOP)-stage versus 90°C (EO)-stage are predisposed to the brightness targets, to short or long bleach sequences, and to mill energy costs. Minimized bleaching costs are generally realized when a 90°C (EO) is employed in D0(EO)D1 bleaching, whereas a 70°C (EOP) is economically advantageous for D0(EOP)D1E2D2 bleaching. The findings we disclose here help to clarify previous ECF optimization studies of conventional softwood kraft pulps.


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