Beta-21S titanium alloy is ranked among the most important advanced materials for a
variety of technological applications, due to its combination of a high strength/weight ratio, good
corrosion behavior and oxidation resistance. However, in many of these technological applications,
this alloy is exposed to environments which can act as sources of hydrogen, and consequently, severe
problems may arise. The objective of this paper is to investigate the influence of high fugacity
hydrogen on Beta-21S alloy in as-received (mill-annealed and hot-rolled) condition. Hydrogen effects
on the microstructure are studied using X-ray diffraction and electron microscopy, while the
absorption and desorption characteristics are determined respectively by means of a hydrogen
determinator and thermal desorption spectroscopy. Preliminary results at room temperature revealed
hydrogen-induced straining and expansion of the lattice parameters. However, neither second phases
formation (hydrides), nor hydrogen-induced cracking, were observed after hydrogenation. The main
characteristics of hydrogen absorption/desorption behavior, as well as hydrogen-induced
microstructural changes in both microstructures are discussed in detail.