scholarly journals A Green Synthesis of Grpahene Based Composite for Energy Storage Application

In this study, graphene-molybdenum oxide composite materials were prepared via green hydrothermal synthesis method and evaluated as supercapacitor electrodes. The morphology and structure of the composite were examined by using Scanning Electron Microscopy (SEM), Raman spectroscopy. The electrochemical performances of the composite were evaluated by cyclic voltammetry (CV), galvanostatic chargedischarge (CD) method, and electrochemical impedance spectroscopy (EIS). The electrochemical results show that the composite electrodes possess improved specific capacitance of 122 F/g at a scan rate of 5 mV/s, which is about 22% higher that of pure graphene. Additionally, the composite electrodes exhibit good capacitive properties and a high specific energy with superior capacitive retention after 1000 cycles. In contrast to the previously reported systems that are usually complicated and costly, the present work potentially provides a readily scalable technological platform for economic mass production of energy storage devices.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 372
Author(s):  
Liyang Lin ◽  
Susu Chen ◽  
Tao Deng ◽  
Wen Zeng

The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.



2022 ◽  
Vol 9 ◽  
Author(s):  
Adriana M. Navarro-Suárez ◽  
Milo S. P. Shaffer

Structural energy storage devices (SESDs), designed to simultaneously store electrical energy and withstand mechanical loads, offer great potential to reduce the overall system weight in applications such as automotive, aircraft, spacecraft, marine and sports equipment. The greatest improvements will come from systems that implement true multifunctional materials as fully as possible. The realization of electrochemical SESDs therefore requires the identification and development of suitable multifunctional structural electrodes, separators, and electrolytes. Different strategies are available depending on the class of electrochemical energy storage device and the specific chemistries selected. Here, we review existing attempts to build SESDs around carbon fiber (CF) composite electrodes, including the use of both organic and inorganic compounds to increase electrochemical performance. We consider some of the key challenges and discuss the implications for the selection of device chemistries.



2013 ◽  
Vol 78 (12) ◽  
pp. 2141-2164 ◽  
Author(s):  
Vladimir Panic ◽  
Aleksandar Dekanski ◽  
Branislav Nikolic

Porous electrochemical supercapacitive materials, as an important type of new-generation energy storage devices, require a detailed analysis and knowledge of their capacitive performances upon different charging/discharging regimes. The investigation of the responses to dynamic perturbations of typical representatives, noble metal oxides, carbonaceous materials and RuO2-impregnated carbon blacks, by electrochemical impedance spectroscopy (EIS) is presented. This presentation follows a brief description of supercapacitive behavior and origin of pseudocapacitive response of noble metal oxides. For all investigated materials, the electrical charging/discharging equivalent of the EIS response was found to obey the transmission line model envisaged as so-called ?resistor/capacitor (RC) ladder?. The ladder features are correlated to material physicochemical properties, its composition and the composition of the electrolyte. Fitting of the EIS data of different supercapacitive materials to appropriate RC ladders enables the in-depth profiling of the capacitance and pore resistance of their porous thin-layers and finally the complete revelation of capacitive energy storage issues.



2015 ◽  
Vol 15 (1) ◽  
pp. 703-708 ◽  
Author(s):  
M. S. Soumya ◽  
G. Binitha ◽  
P. Praveen ◽  
K. R. V. Subramanian ◽  
Y. S. Lee ◽  
...  






RSC Advances ◽  
2014 ◽  
Vol 4 (50) ◽  
pp. 26378-26382 ◽  
Author(s):  
Yanli Yin ◽  
Changhong Liu ◽  
Shoushan Fan

CNT/PANI supercapacitor electrodes were “directly-inserted” into lead-acid battery to assemble new hybrid energy storage devices, which showed notably improved electrochemical performances.



2020 ◽  
Author(s):  
Ruhul Amin ◽  
Petla Ramesh Kumar ◽  
Ilias Belharouak

Carbon nanotubes (CNTs) are an extraordinary discovery in the area of science and technology. Engineering them properly holds the promise of opening new avenues for future development of many other materials for diverse applications. Carbon nanotubes have open structure and enriched chirality, which enable improvements the properties and performances of other materials when CNTs are incorporated in them. Energy storage systems have been using carbon nanotubes either as an additive to improve electronic conductivity of cathode materials or as an active anode component depending upon structural and morphological specifications. Furthermore, they have also been used directly as the electrode material in supercapacitors and fuel cells. Therefore, CNTs demand a huge importance due to their underlying properties and prospective applications in the energy storage research fields. There are different kinds of carbon nanotubes which have been successfully used in batteries, supercapacitors, fuel cells and other energy storage systems. This chapter focuses on the role of CNTs in the different energy storage and conversion systems and impact of their structure and morphology on the electrochemical performances and storage mechanisms.





2019 ◽  
Vol 8 (5) ◽  
pp. 4227-4238 ◽  
Author(s):  
Sivalingam Ramesh ◽  
Hemraj M. Yadav ◽  
K. Karuppasamy ◽  
Dhanasekaran Vikraman ◽  
Hyun-Seok Kim ◽  
...  


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