scholarly journals INVOLVEMENT OF RESIDUAL GAS OF MEMBRANE HYDROGEN SEPARATION UNIT IN RAW OF STEAM CONVERSION

Author(s):  
Egor Shvalev ◽  
Igor' Kuzora ◽  
Dmitriy Dubrovskiy

For a more qualified use of the residual gas formed during the separation of hydro gen from a hydrogen-containing gas, a scheme was proposed for its processing together with hydro carbon gases (HCG) in the process of steam conversion. At the same time, it became possible to re pair the HCG pipeline without stopping production, was reached HCG savings and received additional amount of hydrogen, the products (split gas) corresponded to standards.

Author(s):  
Richard E. Hartman ◽  
Roberta S. Hartman ◽  
Peter L. Ramos

The action of water and the electron beam on organic specimens in the electron microscope results in the removal of oxidizable material (primarily hydrogen and carbon) by reactions similar to the water gas reaction .which has the form:The energy required to force the reaction to the right is supplied by the interaction of the electron beam with the specimen.The mass of water striking the specimen is given by:where u = gH2O/cm2 sec, PH2O = partial pressure of water in Torr, & T = absolute temperature of the gas phase. If it is assumed that mass is removed from the specimen by a reaction approximated by (1) and that the specimen is uniformly thinned by the reaction, then the thinning rate in A/ min iswhere x = thickness of the specimen in A, t = time in minutes, & E = efficiency (the fraction of the water striking the specimen which reacts with it).


Author(s):  
Heinz Gross ◽  
Katarina Krusche ◽  
Peter Tittmann

Freeze-drying followed by heavy metal shadowing is a long established and straight forward approach to routinely study the structure of dehydrated macromolecules. Very thin specimens such as isolated membranes or single macromolecules are directly adsorbed on C-coated grids. After rapid freezing the grids are transferred into a suitable vacuum equipment for freeze-drying and heavy metal shadowing.To improve the resolution power of shadowing films we introduced shadowing at very low specimen temperature (−250°C). To routinely do that without the danger of contamination we developed in collaboration with Balzers an UHV (p≤10-9 mbar) machine (BAF500K, Fig.2). It should be mentioned here that at −250°C the specimen surface acts as effective cryopump for practically all impinging residual gas molecules from the residual gas atmosphere.Common high resolution shadowing films (Pt/C, Ta/W) have to be protected from alterations due to air contact by a relatively thick C-backing layer, when transferred via atmospheric conditions into the TEM. Such an additional C-coat contributes disturbingly to the contrast at high resolution.


1997 ◽  
Author(s):  
Q. He ◽  
Pon Ponnappan ◽  
J. Brown ◽  
Q. He ◽  
Pon Ponnappan ◽  
...  

1981 ◽  
Vol 46 (11) ◽  
pp. 2640-2649 ◽  
Author(s):  
Otakar Söhnel

Porosity of the filtration cake, formed at filtration of model suspensions of CaCO3, BaCrO4 and ZnO is not a function of suspension concentration as long as the solid phase forming the suspension is of the same granulometric composition. The calculated surface area of the solid phase, effective as concerns filtration at ΔP = 30 kPa, is smaller than the actual surface area determined by absorption of nitrogen. Porosity of the filtration cake formed at filtration of suspensions of Mg(OH)2, CaCO3, SrCO3 and BaCO3 prepared by precipitation is a linear function of the initial concentration of precipitated solutions since it is affected by the size and polydispersity of originating particles in dependence on concentration of precipitated solutions. The cakes formed at filtration of precipitated suspensions of CaCO3, SrCO3 and BaCO3 aged for up to 2 hours from the instant of their preparation have a constant porosity which is independent of the time of suspension aging.


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