Texture, Crystal Structure, and Composition of Fluorapatites From Iron Oxide-Apatite (Ioa) Deposits, Eastern Adirondack Mountains, New York

2017 ◽  
Vol 55 (3) ◽  
pp. 399-417 ◽  
Author(s):  
Marian V. Lupulescu ◽  
John M. Hughes ◽  
Jeffrey R Chiarenzelli ◽  
David G. Bailey
Minerals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 65 ◽  
Author(s):  
Sean Regan ◽  
Marian Lupulescu ◽  
Michael Jercinovic ◽  
Jeffrey Chiarenzelli ◽  
Michael Williams ◽  
...  

Monazite crystals, intergrown with allanite, fluorapatite, and quartz from the Cheever Mine iron oxide-apatite (IOA-type) deposit in Essex County, New York, USA, display rare symplectite textures. Electron probe wavelength-dispersive spectrometry (WDS) mapping and major and trace element characterization of these features reveal a natural experiment in fluid-mediated monazite recrystallization. Two types of monazite with symplectite intergrowths have been recognized (Type I and II). Both types of symplectite development are associated with a decrease in HREE, Si, Ca, Th, and Y, but an increase in both La and Ce in monazite. Electron microprobe Th-U-total Pb analysis of Type I monazite with suitable ThO2 concentrations yielded a weighted mean age of 980 ± 5.8 Ma (MSWD: 3.3), which is interpreted as the age of monazite formation and the onset of symplectite development. Both types of monazite formed during a series of reactions from fluorapatite, and possibly britholite, to produce the final assemblage of monazite, allanite, and fluorapatite. Monazite formation was likely a response to evolving fluid conditions, which favored monazite stability over fluorapatite at ca. 980 Ma, possibly a NaCl brine. A subsequent transition to a Ca-dominated fluid may have then promoted the consumption of monazite to produce another generation of allanite and fluorapatite. Our results indicate that recrystallized monazite formed during fluid-mediated processes that, over time, trended towards an increasingly pure end-member composition. Regionally, these data are consistent with a magmatic-origin followed by fluid-mediated remobilization of select phases at subsolidus conditions for the Adirondack IOA deposits.


2002 ◽  
pp. 11-18 ◽  
Author(s):  
Masanao ORIHARA ◽  
Suminori TANAKA ◽  
Sigeo KAWAKAMI ◽  
Kazunori NAKAGAWA ◽  
Masahiro KATO ◽  
...  

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Ryosuke Sinmyo ◽  
Elena Bykova ◽  
Sergey V. Ovsyannikov ◽  
Catherine McCammon ◽  
Ilya Kupenko ◽  
...  

Abstract Iron oxides are fundamentally important compounds for basic and applied sciences as well as in numerous industrial applications. In this work we report the synthesis and investigation of a new binary iron oxide with the hitherto unknown stoichiometry of Fe7O9. This new oxide was synthesized at high-pressure high-temperature (HP-HT) conditions, and its black single crystals were successfully recovered at ambient conditions. By means of single crystal X-ray diffraction we determined that Fe7O9 adopts a monoclinic C2/m lattice with the most distorted crystal structure among the binary iron oxides known to date. The synthesis of Fe7O9 opens a new portal to exotic iron-rich (M,Fe)7O9 oxides with unusual stoichiometry and distorted crystal structures. Moreover, the crystal structure and phase relations of such new iron oxide groups may provide new insight into the cycling of volatiles in the Earth’s interior.


1981 ◽  
Vol 38 (12) ◽  
pp. 1701-1707 ◽  
Author(s):  
Dwight A. Webster ◽  
William A. Flick

Eleven year-classes of wild, domestic, and wild × domestic hybrid strains of brook trout (Salvelinus fontinalis) were stocked in a 0.19-ha Adirondack pond. Comparative survival and growth were assessed upon drainage in early fall. Rearing native wild strains to maturity in a hatchery, or domestic strains in a natural environment, did not consistently or materially affect survival of progeny, suggesting that superior performance of wild strains was largely inherent. Interstrain hybrids of wild × domestic showed survivals equivalent to the wild parents, but hybrids of two Canadian strains gave evidence of heterosis in both survival and net yield. Supplementary observations in other waters also indicated that one strain (Assinica) may be less adaptable to Adirondack conditions than the other (Temiscamie).Key words: brook trout, wild trout, domesticated trout, interstrain hybrid trout, survival, growth, heterosis, hybrid vigor


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