Improving the reactivity of phenylacetylene macrocycles toward topochemical polymerization by side chains modification
2014 ◽
Vol 10
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pp. 1613-1619
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Keyword(s):
X Ray
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The synthesis and self-assembly of two new phenylacetylene macrocycle (PAM) organogelators were performed. Polar 2-hydroxyethoxy side chains were incorporated in the inner part of the macrocycles to modify the assembly mode in the gel state. With this modification, it was possible to increase the reactivity of the macrocycles in the xerogel state to form polydiacetylenes (PDAs), leading to a significant enhancement of the polymerization yields. The organogels and the PDAs were characterized using Raman spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM).
2012 ◽
Vol 27
(2)
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pp. 131-136
2016 ◽
Vol 16
(4)
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pp. 3617-3621
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2014 ◽
Vol 602-603
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pp. 463-466
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2013 ◽
Vol 300-301
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pp. 1385-1388