scholarly journals Fluoride-driven ‘turn on’ ESPT in the binding with a novel benzimidazole-based sensor

2015 ◽  
Vol 11 ◽  
pp. 563-567 ◽  
Author(s):  
Kai Liu ◽  
Xiaojun Zhao ◽  
Qingxiang Liu ◽  
Jianzhong Huo ◽  
Bolin Zhu ◽  
...  

A novel fluorescence sensor (BIP) bearing NH and OH subunits displayed a highly selective and sensitive recognition property for fluoride over other anions. Fluoride-driven ESPT, poorly used in anion recognition and sensing, was suggested to be responsible for the fluorescence enhancement with a blue shift of 35 nm in the emission spectrum.

Talanta ◽  
2020 ◽  
Vol 219 ◽  
pp. 121280 ◽  
Author(s):  
Shumei Qu ◽  
Qi Cao ◽  
Jiutong Ma ◽  
Qiong Jia

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3102 ◽  
Author(s):  
Bin Li ◽  
Datong Zhang ◽  
Ruibing An ◽  
Yaling Zhu

In this work, a novel 7-hydroxybenzoxazinone-based fluorescent probe (PBD) for the selective sensing of biothiols is reported. Upon treatment with biothiols, PBD shows a strong fluorescence enhancement (up to 70-fold) and a large Stokes shift (155 nm). Meanwhile, this probe exhibits high resistance to interference from other amino acids and competing species. PBD features good linearity ranges with a low detection limit of 14.5 nM for glutathione (GSH), 17.5 nM for cysteine (Cys), and 80.0 nM for homocysteine (Hcy), respectively. Finally, the potential utility of this probe for biothiol sensing in living HeLa cells is demonstrated.


2019 ◽  
Vol 43 (30) ◽  
pp. 12032-12041 ◽  
Author(s):  
Tiziana Pivetta ◽  
Sebastiano Masuri ◽  
Maria Grazia Cabiddu ◽  
Claudia Caltagirone ◽  
Anna Pintus ◽  
...  

6-Methoxy-3-(pyridin-2-yl)-2H-chromen-2-one exhibited fluorescence enhancement in the presence of Fe(iii). This molecule was a selective fluorescent chemosensor for Fe(iii).


2018 ◽  
Vol 47 (6) ◽  
pp. 2079-2085 ◽  
Author(s):  
Moustafa T. Gabr ◽  
F. Christopher Pigge

A Co(ii) complex based on an AIE-active tetraarylethylene ligand displays selective fluorescence enhancement in the presence of cyanide anion in aqueous solution.


2021 ◽  
Vol 327 ◽  
pp. 128864
Author(s):  
Goutam Chakraborty ◽  
Alok. K. Ray ◽  
Prabhat K. Singh ◽  
Haridas Pal

Sign in / Sign up

Export Citation Format

Share Document