scholarly journals Pine-derived Biochar as Option for Adsorption of Сu, Zn, Cr, Pb, Ni and Decreasing of BOD5 in Landfill Leachate

2017 ◽  
Vol 9 (4) ◽  
pp. 406-412 ◽  
Author(s):  
Valeriia Chemerys ◽  
Edita Baltrėnaitė

Landfill leachate is a highly toxic and hazardous form of wastewater due to its complex composition characteristics, e.g. ammonia, metals, organic compounds. Landfill leachate treatment technologies, such as flotation, coagulation/flocculation, precipitation, oxidation, micro-, ultra-, nanofiltration, reverse osmosis, are too expensive, because they require frequent regeneration of the media or generate secondary brine wastes that may pose a disposal problem. In the present study removal of Zn, Ni, Cr, Pb, Cu from Kazokiškės landfill leachate was studied. Kazokiškės landfill is the main site for disposal of Vilnius region municipal wastes. Operator of the landfill is interested in the alternative ways for the primary treatment of the landfill leachate for reducing the load on the expensive reverse osmosis. One of the proposed options for the primary landfill leachate treatment was adsorption by biochar. Due to the high specific surface area, well-developed porous structure and surface functionality biochar has been used as low-cost adsorbent for adsorption of PTEs from aqueous solutions. Biochar was produced from Scots pine (Pinus sylvestris L.) trunk wood (after debarking) by pyrolysis at the highest heating temperature of 700 °C for 45 min in the low-oxygen environment. Laboratory analysis showed that PTEs, such as Zn, Ni, Cr, Pb, Cu, were present in the landfill leachate before water treatment plant. Thus, the aim of the study was to evaluate PTEs (Zn, Ni, Cr, Pb, Cu) removal efficiency by adsorption by pine-derived biochar. Factors, affecting adsorption efficiency, such as biochar particle size (1, 2.5, 4, 5 mm) and dosage of the biochar (1.01, 3.5, 6.05, 9.45, 13.25, 17.82 g/100 ml of leachate) were studied. Effects of the biochar on pH of the landfill leachate, BOD5, PTEs adsorption were analyzed. The findings showed that optimal parameters for decreasing of BOD5 and retention of Cr and Pb were particle size 1 mm and dosage 6.05 g/100 ml of leachate and 1 mm and more than 13.25 g/100 ml of leachate, respectively. No positive effect on Cu and Zn was observed.

2016 ◽  
Vol 701 ◽  
pp. 138-142 ◽  
Author(s):  
Mohamat Yusuff Soleha ◽  
Keat Khim Ong ◽  
Wan Yunus Wan Md Zin ◽  
Ahmad Mansor ◽  
Fitrianto Anwar ◽  
...  

Use of alum as a coagulant in drinking water treatment process generates an alum sludge as a waste product. Since the amount of this sludge is huge, it is crucial for a water work management to properly handle and dispose of this sludge. Reuse of this alum sludge as a solid adsorbent is one of the proposed applications for this material but modification and characterization are needed to alter and identify its properties so that optimum benefits are obtained. This paper reports characterization of raw and thermally treated alum sludge. The raw alum sludge was collected from a local water treatment plant and heated at 300 °C and 800 °C for 7 hours using a furnace before characterization using scanning electron microscopy energy (SEM), thermogravimetric (TGA), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The results showed that surface morphology, thermal properties, microstructure, surface area and porosity of the sludge were affected by heating temperature whereby increase the heating temperature resulted in improved thermal stability of the sludge. The results also revealed that both raw and thermally treated alum sludge were mesoporous materials and mainly compose of quartz and kaolinite. It can be said that the sludge could be a good candidate as low cost adsorbent.


2019 ◽  
pp. 347-352
Author(s):  
Lina Gelaziene

Around 6 million tons of non- hazardous waste and some 1 30-1 70 000 tons of hazardous waste is generated in Lithuania every year. Most of non-hazardous wastes are organic (2. 1 millions tons) or domestic (1.7 million ton). Since no general waste incineration is used in Lithuania, the overall used method of waste disposal is landfilling. Most of the landfills are not designed or located properly. They pose a threat for both surface and groundwater in Lithuania. The Lithuanian government has made environmental protection a priority concern in recent years. Bilateral and multilateral donors have made funding available for environmental projects. Until 1998 no landfill in Lithuania had a landfill leachate treatment plant. Leachate was kept in the special storage places in the landfill, or collected and recirculated. In Vilnius, the capital of Lithuania, part of the landfill leachate is taken to the city's waste water treatment plant and part of it is recirculated. Competition for the landfill leachate plant was announced and hopefully in the near future Vilnius will have a real project for the landfill leachate treatment. Recirculation was carried out in Kaunas Lapes landfill too till the leachate treatment plant was built. Leachate is collected and kept in the ditches in the other three biggest cities of Lithuania - Klaipeda, Siauliai and Panevezys. Klaipeda, as all other cities, is looking for a cost effective solution for the leachate treatment and Panevezys is thinking to clean the leachate in the city's waste water treatment plant. Biological leachate treatment is the idea of Siauliai municipality.


2019 ◽  
pp. 239-242
Author(s):  
Harri Terase ◽  
Juri Haller

HistoryLegislationTechnical datasNitrogen removing problemsTartu landfill leachate treatment possibilities


1996 ◽  
Vol 68 (7) ◽  
pp. 1179-1186 ◽  
Author(s):  
Stephen D. J. Booth ◽  
Daniel Urfer ◽  
Gerard Pereira ◽  
Karl J. Caber

Author(s):  
Gang Chen ◽  
Peter Grasel ◽  
Gary Millington ◽  
John Hallas ◽  
Hafiz Ahmad ◽  
...  

Besides organic contaminants, nutrients and heavy metals, high concentrations of chloride have also been observed in landfills accepting ash deposition from waste-to-energy applications, which is difficult be removed in wastewater treatment processes. Chloride may percolate and cause surface salt formation and soil alkalinity increase, thereby resulting in loss of soil. In plants, chloride tends to accumulate in the tissues, especially the leaves. Conventional removal techniques are not feasible from the cost perspective. In this research, the ultra-high lime with aluminum process was evaluated for chloride removal from landfill leachate by precipitation as calcium chloroaluminate (Ca4Al2Cl2(OH)12) in the presence of calcium and aluminum at high pH. Chloride removal was found to be a function of both aluminum concentration and pH. Chloride removal increased with the increase of alum addition until 20 mg/L, after which the chloride removal became moderate. With the increase of pH, obviously more chloride was removed. At pH of 10, the removal reached 90%. To save the chemical costs, alum sludge from a drinking water treatment plant was tested for the removal of chloride from the landfill leachate. The results showed that the supernatant of the alum sludge was more efficient than that of alum sludge suspension in chloride removal. The usage of alum sludge can dramatically save the chemical costs.


2020 ◽  
Vol 37 (10) ◽  
pp. 702-714
Author(s):  
Zubeda Ukundimana ◽  
Mehmet Kobya ◽  
Philip Isaac Omwene ◽  
Erhan Gengec ◽  
Orhan Taner Can

1986 ◽  
Vol 18 (1) ◽  
pp. 31-42 ◽  
Author(s):  
E. A. Shpirt ◽  
K. T. Alben

The particle size distribution at different bed depths of a fixed bed of granular activated carbon (GAC) has been monitored during 50 weeks of a pilot column run at the Waterford, New York potable water treatment plant. Initial backwashing resulted in significant stratification of GAC in the column: larger particles (average diameter 1.18 mm) settled in the bottom of the column (105 cm), and smaller particles (average diameter 0.97 mm) were concentrated near the top (24 cm), compared to samples of unstratified virgin Calgon F400 (average diameter 1.09 mm). During column loading and initial backwashing, more fines were created than were present in the virgin GAC (average 6.5% of GAC fines in the > 40 mesh fraction, compared to only 0.3% in the > 40 mesh fraction for virgin Calgon F400). After 50 weeks of service there was an overall trend toward a smaller average particle size (0.9 mm) with development of a more regular pattern of bed stratification (1.08 mm at the bottom and 0.75 mm at the top). These changes are attributed to breaking of large particles (12-20 mesh) and creation of intermediate size particles (20-30 and 30-40 mesh).


1996 ◽  
Vol 34 (7-8) ◽  
pp. 445-453 ◽  
Author(s):  
G. Baumgarten ◽  
C. F. Seyfried

The leachate treatment plant of the landfill in Mechernich including biological pretreatment, reverse osmosis and evaporation and drying of the concentrate has been in operation since the beginning of 1994. Originally the plant was designed for a capacity of 130 m3/d. In the future, an average leachate amount of ca. 280 m3/d and even considerably higher montly peaks must be assumed. The necessary enlargement of the biological pretreatment will be realized by a second biological contactor plant. Corresponding to the operation of the existing plant a large amount of the ammonium can be eliminated under aerobic conditions by deammonification so no enlargement of the denitrification stage is needed. by simply replacing the reverse osmosis membranes by nanofiltration membranes, an operational capacity of ca. 280 m3/d may easily be achieved at the existing physical post-treatment stage. With the aid of this enlargement conception, the relatively high operational costs at present will be reduced considerably.


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