Photo-Catalytic Activity of Fe3+/Sn4+ Co-Doped Titanium Dioxide Nano-Crystalline Thin Films for Methyl Orange Degradation

Author(s):  
Yun Ping Di ◽  
Wen Li Zhang ◽  
Li Hua Xu ◽  
Chang An Wang ◽  
Ren Bin Shi
2007 ◽  
Vol 336-338 ◽  
pp. 1956-1959
Author(s):  
Yun Ping Di ◽  
Wen Li Zhang ◽  
Li Hua Xu ◽  
Chang An Wang ◽  
Ren Bin Shi

The uniform and transparent nano-crystalline thin films of pure and co-doped with Fe3+/Sn4+ titanium dioxide photo-catalysts were prepared via sol-gel dip-coating process, and were loaded firmly on the surface of glass substrates. The structure and surface morphology of films were characterized by X-ray diffraction (XRD) and atomic force microscopy (AFM). In particular, the photo-catalytic activity of films was measured by ultraviolet-visible (UV-VIS) spectrophotometer. Methyl orange was used as a model compound to study the photo-catalytic activity of films. The effects of the concentrations of doping ions and the number of layers on photo-catalytic degradation of methyl orange solutions were investigated. Experimental results showed clearly that the co-doping of iron and tin ions exhibited a synergistic effect, which increased significantly the photo-catalytic activity of titanium dioxide. Especially, the photo-catalytic activity of nano-crystalline titanium dioxide thin films co-doped with 0.1 mol%Fe3+ and 11.41mol%Sn4+ was 2.0 times higher than that of those un-doped for photo-degradation of methyl orange solutions under the 125W self-ballasted fluorescent high-pressure mercury lamp irradiation.


2014 ◽  
Vol 955-959 ◽  
pp. 112-115
Author(s):  
Li Wang ◽  
Dong Mei Jia ◽  
Zeng Qiang Zhao

Titanium dioxide (TiO2) coating was prepared through dipping stainless steel net into titanium dioxide sol and then extracting it. The photocatalytic activities for all titanium dioxide coatings were tested by methyl orange degradation under ultraviolet and visible light irradiation. The photo-absorption property was determined by UV-Vis spectrophotometer. The titanium dioxide coating is photo-catalytically reactive for the degradation of methyl orange. The photo-catalytic activity is influenced by extraction times, degradation time, doping element and light source. La-doped titanium dioxide exhibits the best photocatalytic activity in comparison with undoped, V-doped and La-V-codoped ones. The degradation rate of methyl orange by La-doped titanium dioxide coating reaches 92% after 70 minutes irradiation under ultraviolet light.


2016 ◽  
Vol 32 (1-2) ◽  
pp. 49
Author(s):  
Jemal Mohammed Yasin ◽  
O. P. Yadav ◽  
Abi M. Taddesse

Nano-size Ag-N co-doped ZnO-CuO composites have been synthesized and tested for their photo-catalytic activity towards degradation of methyl orange in aqueous solution under visible as well as UV radiations. Crystal structure, surface functional groups, metallic composition and band structure of as-synthesized nano-material were investigated using XRD, FTIR, AAS and UV-Vis spectroscopic techniques, respectively. Ag-N co-doped ZnO-CuO photocatalyst showed higher photo-catalytic activity than Ag- or N-doped and undoped composite photocatalysts. The observed highest activity of Ag-N co-doped ZnO-CuO among the studied photo-catalysts, is attributed to the cumulative effects of lowering of band-gap energy and decrease of recombination rate of photo-generated electrons and holes owing to doped N and Ag, respectively. Effects of photo-catalyst load, solution pH and substrate initial concentration on the degradation of methyl orange have also been studied.


2013 ◽  
Vol 815 ◽  
pp. 523-528
Author(s):  
Wan Qing Xiong ◽  
Quan Xin Zhu ◽  
Jian Lei ◽  
Wen Xiang Ye ◽  
Xue Hong Liao

In this paper, Ce4+ and Fe3+co-doped titanium dioxide nanocomposite was prepared by iron nitrate, cerium sulfate and titanium sulfate as raw materials and sodium dodecyl sulfate as surfactant under microwave irradiation. The x-ray diffraction (XRD) results show that as-prepared sample of direct adding doped cerium and iron content were 0.2% and 0.5% of titanium sulfate amount of substance calcined at 500°C for 2 h is anatase. We also studied the photocatalytic activity of the as-prepared Fe3+ and Ce4+ co-doped TiO2 nanocomposite by using degradation of methyl orange solution. The effect conditions of photo-catalytic activities of the composite were investigated, such as different ratios of direct adding doped iron and cerium content, different dosage of hydrogen peroxide, different pH value, and different dosage of nanocomposite. When the catalyst is 1.0 g/L, pH value is 4.3, C(H2O2) is 3 mL/L, the effect of the visible light catalytic activity was the best, in 20 min, the degradation rate of 20 mg/L methyl orange solution was more than 90%. Obviously, as-prepared Fe3+ and Ce4+ co-doped titanium dioxide nanocomposite as photocatalysts for degradation methyl orange, has a significant effect. Moreover, the operation was simple, and there was no secondary pollution. In a word, it has a good prospect.


2003 ◽  
Vol 441 (1-2) ◽  
pp. 130-134 ◽  
Author(s):  
Wu Xiaohong ◽  
Jiang Zhaohua ◽  
Liu Huiling ◽  
Xin Shigang ◽  
Hu Xinguo

AIP Advances ◽  
2015 ◽  
Vol 5 (12) ◽  
pp. 127212 ◽  
Author(s):  
Subodh K. Gautam ◽  
Naina Gautam ◽  
R. G. Singh ◽  
S. Ojha ◽  
D. K. Shukla ◽  
...  

2021 ◽  
Vol 26 ◽  
pp. 102101
Author(s):  
Vaishali Kale ◽  
Y.M. Hunge ◽  
Shalaka A. Kamble ◽  
Madhuri Deshmukh ◽  
S.V. Bhoraskar ◽  
...  

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