Bioactive and Stability of Calcium Phosphate-Polypyrrole Composite Coatings by Electrochemical Deposition

Author(s):  
Mu Qin Li ◽  
Li Jie Qu ◽  
Chen Ma ◽  
Shi Qin Yang
2008 ◽  
Vol 368-372 ◽  
pp. 1198-1200 ◽  
Author(s):  
Mu Qin Li ◽  
Li Jie Qu ◽  
Chen Ma ◽  
Shi Qin Yang

This study examined the bioactive and stability of calcium phosphate- polypyrrole(ppy) composite coatings on titanium alloys by electrochemically deposition in simulated body fluid (SBF). Change of coatings mass and SBF pH during coatings soaked in SBF indicated that ppy reduces the decomposition of coatings. The surface morphology of coatings characterized by SEM showed that the stability of composition coating was superior to that of single coating. XRD indicated that ppy induces CO3 2- enter calcium phosphate coating, which showed that the composite coatings possess better bioactive. Thus, this electrochemical deposition provides an effective method of ppy incorporation at physiological temperature, which can offer excellent bioactive and stability of coatings, with a potential for sustained release of therapeutic agents as required for metallic implant fixation.


2002 ◽  
Vol 83 (9) ◽  
pp. 1970-1977 ◽  
Author(s):  
Gouri Smitha Akundy ◽  
Ramakrishnan Rajagopalan ◽  
Jude O. Iroh

2001 ◽  
Vol 218-220 ◽  
pp. 653-656 ◽  
Author(s):  
P. Becker ◽  
P. Zeggel ◽  
Frank Lüthen ◽  
Barbara Nebe ◽  
Joachim Rychly ◽  
...  

2013 ◽  
Vol 785-786 ◽  
pp. 872-876
Author(s):  
Yong Huang ◽  
Shu Guang Han ◽  
Ya Jing Yan ◽  
Xiao Feng Pang

This work elucidated corrosion resistance of the electrodeposited MgO/calcium phosphate (Ca-P/MgO) films on titanium (Ti). The microstructure, phase composition, and corrosion resistance of the films were studied. Results revealed that The Ca-P/MgO composite coatings were rough and inhomogeneous, the upper layer was floral-like crystals or flakes agglomerates morphology, and the lower layer was needle-like crystals which were mutually cross linked. The coating was very dense, and the content of Mg was about 0.3 wt%. Potentiodynamic polarization test manifested that the Ca-P/MgO-coated surface exhibited superior corrosion resistance than the bare titanium.


2009 ◽  
Vol 618-619 ◽  
pp. 319-323 ◽  
Author(s):  
Parama Chakraborty Banerjee ◽  
Tao Sun ◽  
Jonathan H.W. Wong ◽  
Min Wang

To improve the biocompatibility and bioactivity of NiTi shape memory alloy (SMA), apatite/collagen composite coatings were fabricated on the surface of NiTi SMA at room temperature using the electrochemical deposition technique. Spherical apatite particles and fibrous collagen that formed the composite coating were visible under scanning electron microscope (SEM). The Ca/P ratio of the apatite component in the coating, as determined by energy dispersive X-ray spectroscopy (EDX), was about 1.38 which is slightly higher than that of octocalcium phosphate (OCP). X-ray diffraction result showed that the apatite was amorphous, which was due to the low temperature (i.e., room temperature) deposition process. The structure of the composite coatings was further characterized using Fourier transform infrared reflection spectroscopy (FTIR). It was also found that, compared to bare NiTi SMA samples, the wettability of as-deposited samples was increased because of the formation of the composite coating.


2008 ◽  
Vol 368-372 ◽  
pp. 1194-1197 ◽  
Author(s):  
Chen Ma ◽  
Ying Hui Wang ◽  
Mu Qin Li ◽  
Li Jie Qu

Rare earth/calcium phosphate composite coatings were fabricated on the surface of Ti-6Al-4V by micro-arc oxidation (MAO) technique. The wear properties and corrosion resistant of rare earth/ calcium phosphate composite coatings in the simulated body fluid (SBF) have been investigated and the bioactivity of the composite coatings were evaluated. The results show that the friction coefficient of the composite coatings in the SBF is only 0.15~0.18 and the anode polarization potential of the coating has been obviously enhanced about 0.18V compared with that of coatings of calcium phosphate coatings. So the composite coatings have excellent wear and corrosion resistant properties. XRD analysis indicates that the composite coatings can induce hydroxyapatite to form on its surface after soaked in SBF for 9d, which shows that the composite coatings own good bioactivity.


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