Study on the Rubrene Emission Sensitized by a Phosphorescent Ir Compound in the Host of CBP

2011 ◽  
Vol 110-116 ◽  
pp. 4512-4517
Author(s):  
Deng Hui Xu ◽  
Xiong Li

To obtain the maximum luminous efficiency from an organic material, it is necessary to harness both the spin-symmetric and anti-symmetric molecular excitations (bound electron–hole pairs, or excitons) that result from electrical pumping. Here, we demonstrate that this deficiency can be overcome by using a phosphorescent sensitizer to excite a fluorescent dye. The photoluminescence and sensitization effect between tris (2-phenylpyridine) iridium (Ir (ppy) 3) and 5,6,11,12-tetraphenylnaphthacene (rubrene) in the host of 4,4'-N,N-dicarbazole-biphenyl (CBP) were investigated. The energy transfer characteristics in the electroluminescent process of the system of CBP, Ir (ppy) 3 and Rubrene has been discuss in this article. The Ir (ppy) 3 sensitizer affords an effective way to improve the device performance. In the organic light-emitting diodes based on the Ir (ppy) 3, rubrene and CBP system, both the singlet and triplet excitons can be used.

2008 ◽  
Vol 8 (9) ◽  
pp. 4579-4583
Author(s):  
You-Hyun Kim ◽  
Su-Hwan Lee ◽  
Hyun-Soo Yoon ◽  
Jae-Yoon Choi ◽  
Sung Sik Shin ◽  
...  

Efficiency improvement and color optimization of white organic light-emitting diodes (WOLEDs) were achieved via employing blue host DPVBi doped with blue fluorescent, BCzVBi. The structure of high efficient WOLED device was composed of ITO/NPB/DPVBi:BCzVBi-6%/MADN:DCM2-0.5%/Bphen/Liq/Al. WOLED doped by blue fluorescent BCzVBi exhibits 6.19 cd/A of luminous efficiency and 15400 cd/m2 of maximum luminescence. It also performs 480 cd/m2 of luminance at 5.7 V and 15,400 cd/m2 at 12.9 V with CIEx,y coordinates of (0.33, 0.32) and (0.32, 0.32), respectively. Hole carrier and energy transfer from DPVBi to BCzVBi are proposed to explain the observed phenomena.


2012 ◽  
Vol 65 (9) ◽  
pp. 1244 ◽  
Author(s):  
Prashant Sonar ◽  
Sonsoles Garcia Santamaria ◽  
Ting Ting Lin ◽  
Alan Sellinger ◽  
Henk Bolink

The synthesis and characterisation of 2,5-bis(5′-hexyl-[2,2′-bithiophen]-5-yl)pyridine (Th4PY) and its use as a blue emitter in organic light emitting diodes (OLEDs) is reported. Th4PY was synthesised in high yield using a straightforward Suzuki coupling route with commercially available starting materials. As Th4PY is both soluble and has low molecular weight, blue OLEDs were fabricated using both spin-coating and vacuum deposition thin film processing techniques to study the effect of processing on device performance. OLED devices using a spin-coated layer consisting of 4′,4′′-tris(N-carbazolyl)triphenylamine (TCTA) and 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD) as a host matrix together with Th4PY as emitter exhibited highly efficient sky-blue emission with a low turn-on voltage of 3 V, a maximum brightness close to 15000 cd m–2 at 8 V, and a maximum luminous efficiency of 7.4 cd A–1 (6.3 lm W–1) with CIE coordinates of x = 0.212, y = 0.320. The device performance characteristics are compared using various matrices and processing techniques. The promising sky-blue OLED performance, solution processability, and ambient stability make Th4PY a promising blue emitter for application in OLEDs.


Author(s):  
Nicholle R. Wallwork ◽  
Masashi Mamada ◽  
Atul Shukla ◽  
Sarah K. M. McGregor ◽  
Chihaya Adachi ◽  
...  

Hyperfluorescent organic light-emitting diodes (OLEDs) has allowed remarkable device performances to be achieved using fluorescent emitters. Superior device performance has been realised using thermally evaporated emissive layers. However, for future...


Author(s):  
Soo-Ghang Ihn ◽  
Eun Suk Kwon ◽  
Yongsik Jung ◽  
Jong Soo Kim ◽  
Sungho Nam ◽  
...  

We present a high-performance blue phosphorescent organic light-emitting diode exhibiting a low operating voltage (4.1 V), high external quantum efficiency (23.4%, at 500 cd m-2) with a low efficiency roll-off...


Author(s):  
Hyunchul Kang ◽  
Han-Jin Ahn ◽  
Gyeong-Woo Kim ◽  
Ji-Eun Jeong ◽  
Han Young Woo ◽  
...  

Understanding the exciton energy transfer and bi-exciton annihilation processes in the emitting layers (EMLs) of thermally activated delayed fluorescence (TADF)-based organic light-emitting diodes (OLEDs) is essential for improving their internal...


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