New Unsymmetrically Substituted Benzothiadiazole-Based Luminophores: Synthesis, Optical, Electrochemical Studies, Charge Transport, and Electroluminescent Characteristics

Three new benzothiadiazole (BTD)-containing luminophores with different configurations of aryl linkers have been prepared via Pd-catalyzed cross-coupling Suzuki and Buchwald–Hartwig reactions. Photophysical and electroluminescent properties of the compounds were investigated to estimate their potential for optoelectronic applications. All synthesized structures have sufficiently high quantum yields in film. The BTD with aryl bridged carbazole unit demonstrated the highest electrons and holes mobility in a series. OLED with light-emitting layer (EML) based on this compound exhibited the highest brightness, as well as current and luminous efficiency. The synthesized compounds are not only luminophores with a high photoluminescence quantum yield, but also active transport centers for charge carriers in EML of OLED devices.

Fabrication and electroluminescence properties of alloyed CdSxSe1-x quantum dots-based LEDs

We report the facile synthesis of alloyed CdSxSe1-x QDs via one-pot method using simultaneous injection of Se and S source into a solution of the Cd precursor dissolved in a coordinating mixture of hexadecylamine and trioctylphosphine, during which the formation of CdSxSe1-x nanocrystals was controlled by growth time at a certain temperature of 260 oC. In particular, emission peak and full width at half maximum of photoluminescence (PL) of alloyed CdSxSe1-x QDs were tunable in a range of 588 - 604 nm and 36 - 38 nm, respectively, with a PL quantum yield up to 55 % by a reaction time of 60 min. Importantly, the structural advantage of alloyed CdSxSe1-x QDs based LEDs have been fabricated and their electroluminescence properties were characterized. A good performance device with a maximum luminance and luminous efficiency of 761 cd/m2 and 0.82 cd/A was obtained, respectively.

Applying calcium fluoride and silica particles: A solution to improve color homogeneity of pc-WLEDS

<span>This article focuses on enhancing the lighting efficiency of pc-WLEDs, a new and advanced lighting solution that has received lots of attention. To adapt to the demand of modern lighting, the lighting performance of pc-WLEDs must be improved, especially the color homogeneity and luminous flux, two of the most important quality indicators of pc-WLEDs. Through experiments, this article proposes using the scattering enhancement particles (SEPs) such as CaF₂and SiO₂with yellow phosphor Y₃Al₅O₁₂:Ce³⁺ in pc-WLEDs configuration. The pc-WLEDs model is created by using the LightTools program and set at 8500 K correlated color temperature, while the experimental results yielded from this simulation will be verified by Mie-scattering theory. The information from this article reveals the scattering coefficients of SEPs at 455 nm and 595 nm wavelengths. Moreover, it is confirmed that the employment of CaF₂is effective in promoting the color but may damage the luminous efficiency if the concentration is too high while the SEP material, SiO₂, exhibits high luminous efficiency at all concentration.</span>

Micro-Prism Patterned Remote Phosphor Film for Enhanced Luminous Efficiency and Color Uniformity of Phosphor-Converted Light-Emitting Diodes

In this work, we propose micro-prism patterned remote phosphor (RP) films to enhance both luminous efficiency and color uniformity (CU) of remote phosphor-converted light-emitting diodes (rpc-LEDs) simultaneously. On the incident surface of the RP film, one micro-prism film is used to extract backward light by double reflection. On the exit surface, the other micro-prism film is adopted to retain blue light inside the RP film, thus enhancing the phosphor excitation. Experimental results show that double prism-patterned RP (DP-RP) film configuration shows a luminous flux of 55.16 lm, which is 45.1% higher than that of RP film configuration at 300 mA. As regards the CU, the DP-RP film configuration reduces the angular CIE-x and CIE-y standard variations by 68% and 69.32%, respectively, compared with the pristine device. Moreover, the DP-RP film configuration shows excellent color stability under varying driving currents. Since micro-prism films can be easily fabricated by a roll-to-roll process, the micro-prism patterned RP film can be an alternative to a conventional RP layer to enable the practical application of rpc-LEDs.

Dimming Techniques Focusing on the Improvement in Luminous Efficiency for High-Brightness LEDs

The pulse width modulation (PWM) dimming mode features good dimming linearity and has been widely used for driving high-brightness light-emitting diodes (HBLEDs), in which the brightness change is reached by modulating the duty cycle of the dimming signal to regulate the average current flowing through LEDs. However, the current-illuminance characteristic curve of most LEDs is nonlinear in nature. Namely, under the same lighting power fed, the conventional PWM dimming cannot make the LED exert its best luminous efficiency (LE) specified in datasheets. This paper focuses on the study of further improving LED luminous efficacy via dimming manipulation. Thereby, two multilevel current dimming techniques with varied dimming signal voltage and varied current sensing resistance are presented. With limited dimming capability, the proposed dimming strategies can efficiently raise the luminous flux ratio without increasing the power consumption. A prototype constructed for a 115 W HBLED driver is developed and the devised dimming schemes are realized by a digital signal controller (DSC). Experimental results exhibited with illuminance-power curves and CIE1931 and CIE1976 chromaticity diagrams are given to validate the theoretical derivation and effectiveness. Compared with conventional PWM dimming, under the same illuminance, the driver average output power is respectively reduced by 17.08% and 13.17%; the improvement in average illuminance under the same output power is 13.66% and 11.17%, respectively. In addition, the entire average LE boost has respectively increased by 21.36% and 16.37%.