Kinetic Compensation Effect of Kinetic Parameters of Thermal Explosion Test

2012 ◽  
Vol 184-185 ◽  
pp. 1408-1417
Author(s):  
Ying Hui Shao ◽  
Zi Ru Liu ◽  
Xiao Ning Ren ◽  
Shu Yun Heng ◽  
Pu Yue ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Thermal Explosion ◽  
Energetic Materials ◽  
Compensation Effect ◽  
Energetic Material ◽  
Regression Equation ◽  
Kinetic Temperature ◽  
Single Compound ◽  
Main Component ◽  
Explosion Test

The kinetic parameters of thermal explosion tests with five-second delay for 273 energetic materials were analyzed. The compensation effect exists between the two thermal explosion kinetic parameters of these energetic materials, e.g. lnA and Eb. The kinetic parameters of these energetic materials can be expressed by a single linear regression equation for the single compound or mixture under all conditions. The slopes of the regression equation for various systems are in the range from 0.1952 to 0.2413 (mol•kJ-1). The regression equation for single compound or mixture with one type of energetic material as main component has better linearity. Therefore, their “iso-kinetic temperature” Tik is close to their thermal explosion temperature Tb and the “iso-kinetic delay period”τik is also close to the 5 seconds.

scholarly journals Continuous Monitoring of Shelf Lives of Materials by Application of Data Loggers with Implemented Kinetic Parameters

Molecules ◽  
2019 ◽  
Vol 24 (12) ◽  
pp. 2217 ◽  
Author(s):  
Bertrand Roduit ◽  
Charles Albert Luyet ◽  
Marco Hartmann ◽  
Patrick Folly ◽  
Alexandre Sarbach ◽  
...  
Keyword(s):  
Shelf Life ◽  
Kinetic Parameters ◽  
Energetic Materials ◽  
Kinetic Temperature ◽  
Order Kinetic ◽  
Perishable Goods ◽  
Data Loggers ◽  
Temperature Ranges ◽  
Comparison Of The Results ◽  
Climate Fluctuation

The evaluation of the shelf life of, for example, food, pharmaceutical materials, polymers, and energetic materials at room or daily climate fluctuation temperatures requires kinetic analysis in temperature ranges which are as similar as possible to those at which the products will be stored or transported in. A comparison of the results of the evaluation of the shelf life of a propellant and a vaccine calculated by advanced kinetics and simplified 0th and 1st order kinetic models is presented. The obtained simulations show that the application of simplified kinetics or the commonly used mean kinetic temperature approach may result in an imprecise estimation of the shelf life. The implementation of the kinetic parameters obtained from advanced kinetic analyses into programmable data loggers allows the continuous online evaluation and display on a smartphone of the current extent of the deterioration of materials. The proposed approach is universal and can be used for any goods, any methods of shelf life determination, and any type of data loggers. Presented in this study, the continuous evaluation of the shelf life of perishable goods based on the Internet of Things (IoT) paradigm helps in the optimal storage/shipment and results in a significant decrease of waste.

Introduction of the acylamino group to bridged bis(nitroamino-1,2,4-triazole): a strategy for tuning the sensitivity of energetic materials

2021 ◽  
Vol 45 (38) ◽  
pp. 18059-18064
Author(s):  
Dongxu Chen ◽  
Jiangshan Zhao ◽  
Hongwei Yang ◽  
Hao Gu ◽  
Guangbin Cheng
Keyword(s):  
Energetic Materials ◽  
Energetic Material

Introduction of the acylamino group into energetic material compounds will contribute to balancing the sensitivity and the energy.

Achieving tunable chemical reactivity through photo-initiation of energetic materials at metal oxide surfaces

2020 ◽  
Vol 22 (43) ◽  
pp. 25284-25296
Author(s):  
Maija M. Kuklja ◽  
Roman Tsyshevsky ◽  
Anton S. Zverev ◽  
Anatoly Mitrofanov ◽  
Natalya Ilyakova ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Chemical Reactions ◽  
Energetic Materials ◽  
Chemical Reactivity ◽  
Energetic Material ◽  
Oxide Surfaces ◽  
Oxide Interfaces ◽  
Metal Oxide Surfaces

Photo-stimulated chemical reactions in energetic materials can be highly controlled by selectively designing energetic material – metal oxide interfaces with tailored properties.

Solidification Heat Transfer and Base Separation Analysis in the Casting of an Energetic Material in a Projectile

2005 ◽  
Author(s):  
Dawei Sun ◽  
S. Ravi Annapragada ◽  
Suresh V. Garimella ◽  
Sanjeev Sing
Keyword(s):  
Heat Transfer ◽  
Finite Element ◽  
Numerical Model ◽  
Residual Stresses ◽  
Energetic Materials ◽  
Energetic Material ◽  
Complex Geometries ◽  
Experimental Measurements ◽  
Linear Temperature ◽  
High Prandtl Number

This paper investigates the problem of base separation in the casting of energetic materials in a projectile. Special challenges that arise in casting high Prandtl number energetic materials in projectiles of complex geometries are addressed. A comprehensive numerical model is developed by integrating finite volume and finite element methods to analyze the thermal and flow fields as well as the residual stresses. The predictions, which are confirmed by experimental measurements, suggest that sustenance of a linear temperature profile along the projectile axis can eliminate base separation, and also reduce residual stresses in the final casting.

Towards a predictive thermal explosion model for energetic materials

2005 ◽  
Vol 10 (3) ◽  
pp. 175-189 ◽  
Author(s):  
Jack J. Yoh ◽  
Matthew A. McClelland ◽  
Jon L. Maienschein ◽  
Jeffrey F. Wardell
Keyword(s):  
Thermal Explosion ◽  
Energetic Materials ◽  
Thermal Explosion Model

scholarly journals Nanostructured Energetic Materials with Sol-gel Methods

2003 ◽  
Vol 800 ◽  
Author(s):  
Alexander E. Gash ◽  
Joe H. Satcher ◽  
Randall L. Simpson ◽  
Brady J. Clapsaddle
Keyword(s):  
Thermal Properties ◽  
Energetic Materials ◽  
Energetic Material ◽  
Sol Gel ◽  
Small Scale ◽  
Fine Grained ◽  
Electron Microscopies ◽  
Burn Rate ◽  
Scanning Electron

AbstractThe utilization of sol-gel chemical methodology to prepare nanostructured energetic materials as well as the concepts of nanoenergetics is described. The preparation and characterization of two totally different compositions is detailed. In one example, nanostructured aerogel and xerogel composites of sol-gel iron (III) oxide and ultra fine grained aluminum (UFG Al) are prepared, characterized, and compared to a conventional micron-sized Fe2O3/Al thermite. The exquisite degree of mixing and intimate nanostructuring of this material is illustrated using transmission and scanning electron microscopies (TEM and SEM). The nanocomposite material has markedly different energy release (burn rate) and thermal properties compared to the conventional composite, results of which will be discussed. Small-scale safety characterization was performed on the nanostructured thermite. The second nanostructured energetic material consists of a nanostructured hydrocarbon resin fuel network with fine ammonium perchlorate (NH4ClO4) oxidizer present.

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