Catalytic Conversion of Oil Palm Fronds to Levulinic Acid in Ionic Liquid

2014 ◽  
Vol 625 ◽  
pp. 361-365 ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin

Conversion of oil palm fronds (OPF) to levulinic acid (LA) over Fe/HY zeolite catalyst in BMIM[Br] ionic liquid has been investigated in this study. The optimization of OPF conversion reported 24.7% levulinic acid yield at 153 °C, 5.9 h, 0.96 g and 1.1 g of reaction temperature, reaction time, OPF loading and catalyst loading, respectively. The results indicated that BMIM[Br] could disrupt the covalent linkages in the OPF structures and dissolved the hollocellulose. This allowed the hollocellulose chains, accessible to the chemical transformation, to react and produce LA in presence of the Fe/HY catalyst. This study demonstrated that the combination of Fe/HY catalyst and BMIM[Br] has the potential to be applied for biomass conversion to LA under adequate process conditions.

2015 ◽  
Vol 44 (6) ◽  
pp. 883-890 ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin

2014 ◽  
Vol 71 (1) ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin ◽  
Ismail Ware

The pretreatment of oil palm frond (OPF) has been carried out using 1-butyl-3-methylimidazolium bromide ([BMIM]Br) in the presence of aqueous sulphuric acid (H2SO4). The effects of reaction temperature, reaction time and [BMIM]Br loading on lignin degradation were investigated by applying Box Behnken Design of Response Surface Methodology (RSM). The optimized process condition for OPF pretreatment were 123°C, 175 min and 9.9 g of [BMIM]Br loading with an optimum lignin degradation of 88.2%. The experimental results fitted-well with the predicted value with less than 5% error. It was also demonstrated that lignin degradation using recycled [BMIM]Br gave sufficient performance for five successive runs. It was revealed from SEM and XRD analyses, that the pretreated OPF was porous and less crystalline after pretreatment. Consequently, the pretreated OPF renders 25.3% levulinic acid yield in acid hydrolysis compared to 18.2% yield for untreated OPF.


2021 ◽  
Vol 60 (5) ◽  
pp. 2011-2026
Author(s):  
Eng Kein New ◽  
Ta Yeong Wu ◽  
Khai Shing Voon ◽  
Alessandra Procentese ◽  
Katrina Pui Yee Shak ◽  
...  

2019 ◽  
Vol 1 (1) ◽  
pp. 30-35
Author(s):  
Seri Maulina ◽  
Gewa Handika

This paper aims to understand the difference in characteristics of activated carbon produced from oil palm fronds (Elaeis guineensis Jacq) through the addition of two different activators, namely sodium carbonate (Na2CO3) and sodium chloride (NaCl). To do this, activator concentration of 10 percent each with activation temperature of 600 oC were applied in the experiment. Moreover, to determine the quality of activated carbon produced, a morphological analysis of activated carbon surfaces as well as FTIR spectra analysis on activated carbon. Identification using FTIR spectrophotometer revealed that the activated carbon in this study contained functional groups of O-H, C = O, C = C, C-C, and C-H.


Solar Energy ◽  
2016 ◽  
Vol 132 ◽  
pp. 415-429 ◽  
Author(s):  
S. Misha ◽  
S. Mat ◽  
M.H. Ruslan ◽  
E. Salleh ◽  
K. Sopian
Keyword(s):  
Oil Palm ◽  

2018 ◽  
Vol 122 ◽  
pp. 617-626 ◽  
Author(s):  
Masniroszaime Md Zain ◽  
Abdul Wahab Mohammad ◽  
Shuhaida Harun ◽  
Nurul Aina Fauzi ◽  
Nur Hanis Hayati Hairom

Fermentation ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 218
Author(s):  
Pin Chanjula ◽  
Chanon Suntara ◽  
Anusorn Cherdthong

This study aimed to examine the combined effects of urea and calcium hydroxide ensiled oil palm fronds on rumen fermentation and digestibility of Thai native-Anglo Nubian goats. A 4 × 4 Latin square design was used to randomly assign four male crossbred goats (Thai native × Anglo Nubian). The dietary treatments were as follows: ensiled oil palm frond with no additives (EOPF as the control), urea 5% (50 g/kg fresh matter) (E-UOPF 5%), calcium hydroxide (Ca(OH)2) 5% (50 g/kg fresh matter) (E-CaOPF 5%), and combination of urea 2.5% (25 g/kg fresh matter) with Ca(OH)2 (25 g/kg fresh matter) (E-UCOPF 2.5%). The oil palm frond ensiled with different additives did not change the DM intake (p > 0.05). The total TMR intakes range from 69.39 to 77.09 g/kg BW0.75. The goats fed with E-UOPF 5.0% consumed significantly more CP than the other groups (p < 0.05). The E-UCOPF increased ME intake by 4.8%, compared with the control treatment (p < 0.05). E-UOPF 5% and E-UCOPF 2.5% significantly increased the CP digestibility by 19.7% and 17.1%, respectively (p < 0.05). Furthermore, E-CaOPF 5.0% and E-UCOPF 2.5% improved the NDF digestibility by about 10.9% and 9.90%, respectively (p < 0.05). The urea-containing oil palm frond (E-UOPF 5.0% and E-UCOPF 2.5%) had higher blood urea nitrogen (BUN) than the other groups (p < 0.05). The TVFA of goats fed E-UCOPF 2.5% was approximately 15.8% higher than that of goats provide EOPF (p < 0.05). The mean concentration of C3 increased by 7.90% and 11.61%, respectively, when E-CaOPF 5.0% and E-UCOPF 2.5% were provided instead of EOPF (p < 0.05). The total N intake and absorbed were highest (p < 0.05) when goats offered E-UOPF 5.0% (p < 0.05). The goats fed oil palm frond without additives had the lowest percentage of N-absorption/N intake (p < 0.05). This study clearly shows that the most suitable treatment is E-UCOPF 2.5%, which enhances DMD, nutrient digestibility, TVFAs, and nitrogen balance and has no negative effects on rumen microbes. This indicates that E-UCOPF 2.5% may be utilized as an alternate roughage source in TMR diets, accounting for at least 40% of the OPF. However, several factors still require consideration for urea-Ca(OH)2 treatments to be successful, including other concentrations of urea, moisture content, duration of pre-treatment, and the metabolizable protein system.


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