Properties of Materials from Activated Fly Ash from Fluidized Burning

2014 ◽  
Vol 1000 ◽  
pp. 338-341
Author(s):  
Jaromír Poláček ◽  
Rostislav Šulc

This article deals with the basic properties of materials based on alkali-activated fly ash which contains a portion of fly ash produced during fluid burning. The primary task of our research was characterization of physical and chemical properties of each type of fly ash and fly ash mixture. The new materials composed of fly ash mixture and fly ash may have the similar mechanical and physical properties. The work focused on findingan appropriate technological procedure, the optimum composition of mixtures. Long-term stability was simulated by means of accelerated aging of these materials.

2014 ◽  
Vol 1054 ◽  
pp. 173-176 ◽  
Author(s):  
Jaromir Polacek ◽  
Rostislav Šulc

This paper describes basic properties of materials composed of fly ash produced during fluid burning. This material is based on alkali-activated fly ash which contains a portion of fly ash produced during fluid burning. Firstly the physical and chemical properties was described for each type of fly ash and fly ash mixture. The new materials composed of fly ash mixture and fly ash may have the similar mechanical and physical properties. The work focused on findingan appropriate technological procedure, the optimum composition of mixtures. Long-term stability was simulated by means of accelerated aging of these materials.


2009 ◽  
Vol 1193 ◽  
Author(s):  
Karl R. Whittle ◽  
Mark G. Blackford ◽  
Gregory R. Lumpkin ◽  
Katherine L. Smith ◽  
Nestor J. Zaluze

AbstractRadiation damage and the effect on physical and chemical properties is an important component in the prediction of the long-term stability of waste form materials. As part of the ongoing goal of increasing the accuracy of long-term predictions of radiation damage, two types of material, based on proposed materials with a waste form application have been irradiated. Results have shown that Y2TiO5 (Y2.67Ti1.33O6.67), and Yb2TiO5 (Yb2.67Ti1.33O6.67), both of which are non-stoichiometric, disordered pyrochlore-based compounds, behave significantly different to the stoichiometric, ordered pyrochlore equivalent. For example the critical temperature, the temperature above which materials remain crystalline during irradiation, is found to decrease from the ordered equivalents, e.g. Y2Ti2O7. ⁡ A second material based on La2TiO5 has been found to behave differently to both La2/3TiO3 and La2Ti2O7, with a change in Tc of ∼ 200 K.


1997 ◽  
Vol 506 ◽  
Author(s):  
M. Steinmann ◽  
P. Stille ◽  
K. Mengel ◽  
M. Siemann ◽  
W. Bernotat

Basaltic dykes in salt rocks can be used in two different ways as natural analogues for high level radioactive waste (HLW) in a salt repository: In the first approach the basalts serve as analogues for the corrosion behavior of HiLW glass products during millions of years because of many similarities in their physical and chemical properties.


Author(s):  
Masashi Nakayama ◽  
Haruo Sato ◽  
Yutaka Sugita ◽  
Seiji Ito ◽  
Masashi Minamide ◽  
...  

In Japan, any high level radioactive waste (HLW) repository is to be constructed at over 300 m depth below surface. Tunnel support is used for safety during the construction and operation, and shotcrete and concrete lining are used as the tunnel support. Concrete is a composite material comprised of aggregate, cement and various admixtures. Low alkaline cement has been developed for the long term stability of the barrier systems whose performance could be negatively affected by highly alkaline conditions arising due to cement used in a repository. Japan Atomic Energy Agency (JAEA) has developed a low alkaline cement, named as HFSC (Highly Fly-ash Contained Silicafume Cement), containing over 60 wt% of silica-fume (SF) and fly-ash (FA). HFSC was used experimentally as the shotcrete material in construction of part of the 140m deep gallery in the Horonobe Underground Research Laboratory (URL). The objective of this experiment was to assess the performance of HFSC shotcrete in terms of mechanics, workability, durability, and so on. HFSC used in this experiment is composed of 40 wt% OPC (Ordinary Portland Cement), 20 wt% SF, and 40 wt% FA. This composition was determined based on mechanical testing of various mixes of the above components. Because of the low OPC content, the strength of HFSC tends to be lower than that of OPC. The total length of tunnel using HFSC shotcrete is about 73 m and about 500 m3 of HFSC was used. The workability of HFSC shotcrete was confirmed in this experimental construction.


2015 ◽  
Vol 63 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Karsten Schacht ◽  
Bernd Marschner

Abstract The use of treated wastewater (TWW) for agricultural irrigation becomes increasingly important in water stressed regions like the Middle East for substituting fresh water (FW) resources. Due to elevated salt concentrations and organic compounds in TWW this practice has potential adverse effects on soil quality, such as the reduction of hydraulic conductivity (HC) and soil aggregate stability (SAS). To assess the impact of TWW irrigation in comparison to FW irrigation on HC, in-situ infiltration measurements using mini disk infiltrometer were deployed in four different long-term experimental orchard test sites in Israel. Topsoil samples (0-10 cm) were collected for analyzing SAS and determination of selected soil chemical and physical characteristics. The mean HC values decreased at all TWW sites by 42.9% up to 50.8% compared to FW sites. The SAS was 11.3% to 32.4% lower at all TWW sites. Soil electrical conductivity (EC) and exchangeable sodium percentage (ESP) were generally higher at TWW sites. These results indicate the use of TWW for irrigation is a viable, but potentially deleterious option, as it influences soil physical and chemical properties.


1987 ◽  
Vol 113 ◽  
Author(s):  
Scott Schlorholtz ◽  
Ken Bergeson ◽  
Turgut Demirel

ABSTRACTThe physical and chemical properties of fly ash produced at Ottumwa Generating Station have been monitored since April, 1985. The fly ash is produced from burning a low sulfur, sub-bituminous coal obtained from the Powder River Basin near Gillette, Wyoming. One-hundred and sixty samples of fly ash were obtained during the two year period. All of the samples were subjected to physical testing as specified by ASTM C 311. About one-hundred of the samples were also subjected to a series of tests designed to monitor the self-cementing properties of the fly ash. Many of the fly ash samples were subjected to x-ray diffraction and fluorescence analysis to define the mineralogical and chemical composition of the bulk fly ash as a function of sampling date. Hydration products in selected hardened fly ash pastes, were studied by x-ray diffraction and scanning electron microscopy. The studies indicated that power plant operating conditions influenced the compressive strength of the fly ash paste specimens. Mineralogical and morphological studies of the fly ash pastes indicated that stratlingite formation occurred in the highstrength specimens, while ettringite was the major hydration product evident in the low-strength specimens.


2016 ◽  
Vol 7 (36) ◽  
pp. 5664-5670 ◽  
Author(s):  
Michał Szuwarzyński ◽  
Karol Wolski ◽  
Szczepan Zapotoczny

Formation and characterization of polyacetylene-based brushes that exhibit exceptional long term stability in air is presented here.


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