Effect of Mn Addition on Mechanical Property and Corrosion Behavior in Hot Rolled 19 % Cr Duplex Stainless Steel

2014 ◽  
Vol 1004-1005 ◽  
pp. 231-234
Author(s):  
Yin Hui Yang ◽  
Yang Gu
Keyword(s):  
Mechanical Property ◽  
Tensile Strength ◽  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Polarization Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Prevention ◽  
Mn Content ◽  
Hot Rolled

The effect of Mn addition on mechanical property and corrosion behavior of hot rolled 19 % Cr duplex stainless steel was investigated. The ultimate tensile strength of specimen decreased from 950 to 840 MPa with increasing Mn content from 3.6 to 5.5 wt.%, and further decreased to 768MPa with Mn content addition up to 8.1 wt.%. The sample with the addition of 5.5 wt.% Mn exhibited the highest elongation up to 43%. The polarization result revealed that higher value of breakdown potentials Eb was obtained with increasing Mn content from 3.6 to 5.5 wt. %, but which decreased with increasing Mn content to 8.1 wt.%. The electrochemical impedance spectroscopy (EIS) spectra showed higher corrosion prevention capability was obtained due to enhancement of polarization resistance with increasing Mn content from 3.6 to 5.5 wt.%.

Corrosion behavior of a new 25Cr-3Ni-7Mn-0.66 N duplex stainless steel in artificial seawater

2021 ◽  
Vol 63 (6) ◽  
pp. 505-511
Author(s):  
Songkran Vongsilathai ◽  
Anchaleeporn Waritswat Lothongkum ◽  
Gobboon Lothongkum
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Passive Film ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Melting Furnace ◽  
Artificial Seawater ◽  
Vacuum Arc ◽  
Significant Difference ◽  
Type Semiconductor

Abstract A new duplex 25Cr-3Ni-7Mn-0.66 N alloy was prepared in a vacuum arc re-melting furnace and characterized by metallographic and EPMA methods. Its corrosion behavior was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and a Mott-Schottky (M-S) analysis in artificial seawater at room temperature and compared with those of super and normal commercial duplex stainless steel (SDSS and DSS). No significant difference in the open circuit potentials and pitting potentials was observed. Its passive film current density lies between those of SDSS and DSS. This was confirmed by EIS analysis. A pit attack was observed on the δ-phase for all duplex samples, because the PREN16 of the δ-phase was lower than that of the γ-phase. From the Mott-Schottky analysis, the passive films were found to be composed of bi-layer structures, a p-type semiconductor inner layer, and a n-type semiconductor outer layer. The degree of defect as well as the effect of nitrogen in passive film layer are discussed with respect to the point defect model.

Microstructure, Texture, Mechanical and Corrosion Performance of the Stainless Duplex Steel UNS S32205 Submitted to Warm Rolling

2018 ◽  
Vol 941 ◽  
pp. 118-123
Author(s):  
Dagoberto Brandão Santos ◽  
Raphael França Assumpção ◽  
Daniela Barçante Perasoli ◽  
Dalila Chaves Sicupira
Keyword(s):  
Tensile Strength ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Warm Rolling ◽  
Optical Scanning ◽  
Transmission Electron ◽  
Duplex Steel ◽  
Hot Rolled ◽  
Chlorine Ion

The UNS S32205 duplex stainless steel was warm rolled at 600°C with 60 and 80% of thickness reduction. The microstructure was characterized by optical, scanning and transmission electron microscopy, X-ray diffractometry and EBSD. The corrosion resistance was evaluated by electrochemical behavior in the chlorine ion environment using potentiodynamic polarization measurements. The tensile strength reached 1185 MPa and 1328 MPa, after warm rolling with 60 and 80%, respectively. In steel as-supplied, hot rolled and annealed, the tensile strength was 774 MPa. Ferrite microtexture presented the α-fiber and the rotated cube component, while the austenite enhanced the brass, copper, and cube components to a lesser extent. The substructure was characterized by intense formation of tangles and forests of dislocations and discrete subgrains in the ferritic phase and by planar gliding of dislocations and formation of dense dislocations walls in the austenite. Despite the existence of a certain similarity among the values of pitting potentials obtained for all samples, the number of pits observed was higher in the as-received sample, followed by the samples with 60 and 80% reduction. These results draw attention to innovative routes in the industrial production of duplex stainless steel of this class, even considering ductility lost. Keywords: Warm rolling; Mechanical strength; Texture; Substructure; Corrosion resistance

Electrochemical Study of Diffusion Bonded Joints between Micro-Duplex Stainless Steel and Ti6Al4V Alloy

2014 ◽  
Vol 783-786 ◽  
pp. 2250-2259
Author(s):  
S.M. Bhola ◽  
S. Kundu ◽  
Brajendra Mishra ◽  
Subrata Chatterjee
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Ti6al4v Alloy ◽  
Uniaxial Pressure ◽  
Equilibrium Potential ◽  
Scattered Electron ◽  
Corrosion Rates ◽  
Bonded Interface

In the present study, corrosion behavior of a diffusion bonded interface formed between micro-duplex stainless steel (MDSS) and a mixed titanium alloy (Ti6Al4V) formed at 900°C for 60 minutes under 4MPa uniaxial pressure in vacuum has been investigated in 1M HCl and 1 M NaOH solutions using various electrochemical measurements such as Equilibrium Potential (EP), Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Polarization (PD). For comparison, corrosion behavior of base metal alloys, MDSS and Ti6Al4V have also been also characterized. Bonded interface has been characterized in light optical microscopy and scanning electron microscopy using back scattered electron. The layer wise σ phase and λ+FeTi phase mixture has been observed at the bond interface and the bond tensile strength and shear strength were ~556.4MPa and ~420.2MPa, respectively. The corrosion rates of the bonded joint are intermediate to the corrosion rates of MDSS and Ti6Al4V alloy.

Corrosion Behavior of Duplex Stainless Steels (2205) in Seawater in the Presence of Deep Sea Bacteria

2014 ◽  
Vol 513-517 ◽  
pp. 189-192 ◽  
Author(s):  
John Gerald Odhiambo ◽  
Li Zhang ◽  
Tao Liu ◽  
Li Hua Dong ◽  
Yan Sheng Yin
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Deep Sea ◽  
Electrochemical Impedance ◽  
Chloride Ions ◽  
Localized Corrosion ◽  
Electrochemical Impedance Spectra ◽  
Deep Sea Bacteria ◽  
Simulated Seawater

The corrosion behavior of duplex stainless steel immersed in nutrient-rich simulated seawater without deep sea bacteria and with deep sea bacteria (Erythrobacter pelagi sp.nov) was studied. The effect of chloride ions and presence of deep sea bacteria on corrosion resistance was investigated. The occurrence of localized corrosion (Viz. pitting and crevice corrosion) was examined using visual inspection and SEM-EDX. Electrochemical impedance spectra were used to study the effects of deep sea bacteria on duplex stainless steel and inferences were made. Most significantly was the reduction of pitting resistance potential with increase in exposure time.

Corrosion Behavior of Duplex Stainless Steel in Industrial White Liquor

CORROSION ◽  
10.5006/2558 ◽  
2017 ◽  
Vol 74 (5) ◽  
pp. 543-550 ◽  
Author(s):  
Luiza Esteves ◽  
Mônica M.A.M. Schvartzman ◽  
Wagner Reis da Costa Campos ◽  
Vanessa F.C. Lins
Keyword(s):  
Weight Loss ◽  
Stainless Steel ◽  
Corrosion Rate ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Extrapolation Method ◽  
White Liquor ◽  
Duplex Steel ◽  
Kraft Mill ◽  
Lower Corrosion Rate

Specimens of lean duplex and duplex stainless steel were exposed at 200°C in industrial white liquor from a Brazilian kraft mill using an autoclave to simulate the same conditions of digester processing. Tafel extrapolation method and weight loss were used to evaluate corrosion behavior of duplex steel in white liquor. The higher alloy steel, although presenting a lower corrosion rate than the lean duplex, presents a more severe selective attack on ferrite, at 200°C and 1.8 MPa, after Tafel extrapolation method in industrial white liquor.

scholarly journals Influence of Molybdenum on Microstructure and Pitting Corrosion Behavior of Solution-Treated Duplex Stainless Steel in a Lithium Chloride Solution

2019 ◽  
Vol 22 (suppl 1) ◽  
Author(s):  
Stephania Cappellari de Rezende ◽  
Isabela Dainezi ◽  
Raíra Chefer Apolinario ◽  
Lucíola Lucena de Sousa ◽  
Neide Aparecida Mariano
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Lithium Chloride ◽  
Pitting Corrosion ◽  
Chloride Solution ◽  
Solution Treated ◽  
Lithium Chloride Solution

Surface Characterization of Incoloy 825 Ni-Based Alloy/2507 Super Duplex Stainless Steel Dissimilar Friction Stir Welds

CORROSION ◽  
10.5006/2755 ◽  
2018 ◽  
Vol 74 (11) ◽  
pp. 1259-1271 ◽  
Author(s):  
Jalal Kangazian ◽  
Morteza Shamanian ◽  
Ali Ashrafi
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Surface Characterization ◽  
Electrochemical Impedance ◽  
Friction Stir Weld ◽  
General Corrosion ◽  
Super Duplex Stainless Steel ◽  
Friction Stir ◽  
Surface Corrosion ◽  
Incoloy 825

Surface features of a dissimilar friction stir weld between Incoloy 825 Ni-based alloy and SAF 2507 super duplex stainless steel were investigated using scanning electron microscopy, microhardness test, cyclic potentiodynamic polarization, and electrochemical impedance spectroscopy. The surface of the weldment showed lower general corrosion resistance in comparison to the base metals. Areas under the weld shoulder exhibited weak pitting resistance because of the deformed structure and/or chromium nitride precipitates. Incoloy 825 located under the shoulder also displayed the highest susceptibility to pit growth because of the austenite matrix containing titanium nitride phases. Overall, the obtained results demonstrated that the friction stir welding method could significantly deteriorate the surface corrosion behavior of the processed regions.

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