Tribological Property of some Triazine Derivatives in Hydrogenated Oil

2014 ◽  
Vol 1008-1009 ◽  
pp. 323-327 ◽  
Author(s):  
Ping Nan Wan ◽  
Jie Yang ◽  
You Quan Zhong
Keyword(s):  
Photoelectron Spectroscopy ◽  
Lubricating Oil ◽  
Protective Film ◽  
Extreme Pressure ◽  
Oil Additives ◽  
Hydrogenated Oil ◽  
Triazine Derivatives ◽  
Antiwear Properties ◽  
Lubricating Oil Additives ◽  
Worn Surface

Two ashless triazine derivatives, 2,4-bi-amido-6-(O,O′-di-i-octhyl dithiophosphate)- 1,3,5 - triazine were synthesized. Their tribological properties as lubricating oil additives compared with ZDDP in hydrogenated oil were evaluated using a four-ball tester. The results show that these triazine derivatives possess extreme pressure capacity, and they can improve antiwear and friction-reducing performance of base stock than that of ZDDP. Their tribological performance is corresponding to the amide. The elements chemical states of the worn surface were estimated through X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM). The results show that a protective film containing sulphide, phosphate and some organic nitrogen compounds was formed on the worn surface during the lubrication process, and the film possesses extreme pressure and antiwear properties.

Tribological Study of Xanthate-Containing Acetic Ester as Additives in Hydrogenated Oil

2012 ◽  
Vol 236-237 ◽  
pp. 123-127 ◽  
Author(s):  
Chao Long Li ◽  
Li Ping Xiong ◽  
Hong Liu ◽  
Li Ting Xiong ◽  
Wei Wang
Keyword(s):  
Photoelectron Spectroscopy ◽  
Protective Film ◽  
Extreme Pressure ◽  
Action Mechanism ◽  
Prepared Compound ◽  
X Ray ◽  
Hydrogenated Oil ◽  
Worn Surface ◽  
Scanning Electron ◽  
Sem Analyses

A novel ester derivative, dodecyl xanthate acetic dodecyl xanthate ester(DXAD) was synthesized and it’s tribological behaviors as additives in hydrogenated oil, were evaluated using a four-ball tester. Results show that the compound possesses good antiwear performance, extreme pressure capacity, and good friction-reducing property. The action mechanism was estimated through analysis of the worn surface with X-ray photoelectron spectroscopy (XPS) and Scanning Electron Microscope (SEM). The results of XPS and SEM analyses illustrate that the prepared compound as an additive in hydrogenated oil forms a protective film containing ferric sulfide and ferric sulfate compounds on the rubbed surface.

Research on Tribological Properties of Serpentine Particles as Lubricating Oil Additives

2011 ◽  
Vol 284-286 ◽  
pp. 1001-1005 ◽  
Author(s):  
Peng Wang ◽  
Jing Lv ◽  
Lian Hai Wang ◽  
Qiang Ma ◽  
Xin He Zhu
Keyword(s):  
Oleic Acid ◽  
Friction And Wear ◽  
Friction Pair ◽  
Volume Ratio ◽  
Lubricating Oil ◽  
Protective Film ◽  
Optimum Dosage ◽  
Oil Additives ◽  
Lubricating Oil Additives ◽  
Friction And Wear Tests

This paper adopts wet method to prepare serpentine particles on the planetary ball mill, executes lipophilic degree tests and friction and wear tests of these particles. The results showed that: 1) as the modification agent, the optimum dosage of oleic acid is when the volume ratio of oleic acid and serpentine particles is 2, and the optimum time of milling (modification) is 24h. 2) 4012 maritime lubricating oil with serpentine particles has obvious anti-wear and friction effect, and the optimum dosage range of serpentine particles is 0.9%-1.0%. According to the outcomes of metallurgical microscope observation and electron microprobe analysis, a conclusion can be drawn: during the process of friction and wear, serpentine particles brought on physical or chemical reactions with the surface of test samples, create a layer of protective film, thus this kind of lubricating oil has filling function to the furrow of friction pair surface, so as to decrease the surface roughness, decrease the degree of friction and wear.

Tribological Properties of Zirconium Oxide, Spinel and Mullite Nanopowders as Lubricating Oil Additives

2016 ◽  
Vol 721 ◽  
pp. 451-455
Author(s):  
Armands Leitans ◽  
Eriks Palcevskis
Keyword(s):  
Tribological Properties ◽  
Zirconium Oxide ◽  
Friction Pair ◽  
Synthesis Method ◽  
Lubricating Oil ◽  
Nanosized Powders ◽  
Base Oil ◽  
Oil Additives ◽  
Oxide Spinel ◽  
Lubricating Oil Additives

In work investigated effects of zirconium oxide (ZrO2), spinel (MgAl2O4) and mullite (Al6Si2O13) nanosized powders on the base oil tribological properties. The nanosized (30-40nm) powders manufactured by plasma chemical synthesis method. Tribological experiments used on ball-on-disc type tribometer, measured coefficient of friction and determined metalic disc wear. Base oil used selectively purified mineral oil (conform SAE-20 viscosity) without any functional additives. Nanosized powders dispersed in base oil at 0.5; 1.0; 2.0; wt.%. At work cocluded, that the adition nanoparticles in base oil, possible reduced friction pair wear and friction coefficient. As the main results include spinel (MgAl2O4) nanoparticles 0.5 and 1.0 wt. % concentration ability reduced friction coeffiecient value.

Tribological performance of nanoparticles as lubricating oil additives

2016 ◽  
Vol 18 (8) ◽  
Author(s):  
M. Gulzar ◽  
H. H. Masjuki ◽  
M. A. Kalam ◽  
M. Varman ◽  
N. W. M. Zulkifli ◽  
...  
Keyword(s):  
Tribological Performance ◽  
Lubricating Oil ◽  
Oil Additives ◽  
Lubricating Oil Additives

Synthesis and Tribological Properties of S- and P-Free Borate Esters With Different Chain Lengths

2011 ◽  
Vol 133 (2) ◽  
Author(s):  
Guangbin Yang ◽  
Zhanming Zhang ◽  
Guihui Li ◽  
Jinfeng Zhang ◽  
Laigui Yu ◽  
...  
Keyword(s):  
Alkyl Chain ◽  
Liquid Paraffin ◽  
Alkyl Chain Length ◽  
Lubricating Oil ◽  
Oil Additives ◽  
Borate Esters ◽  
Lubricating Oil Additives ◽  
Steel Balls ◽  
Chain Lengths ◽  
Antiwear Ability

Three kinds of S- and P-free borate esters containing N with different alkyl chain lengths were prepared by using boric acid, ethanolamine, and alkyl-alcohol as the starting materials. The chemical structure of the products was analyzed by means of Fourier transformation infrared spectrometry, elemental analysis, and so on. The thermal stability of the products was evaluated by thermogravimetric analysis. The tribological properties of the synthesized borate esters as lubricating oil additives in liquid paraffin were evaluated using a four-ball friction and wear tester while the morphologies of the worn scars of the steel balls were observed using a scanning electron microscope. The chemical components on the worn surfaces of the steel balls were analyzed using an X-ray photoelectron spectroscopy. Results show that all the three kinds of synthetic borate esters as additives in liquid paraffin possess good antiwear performance and may be used as promising S- and P-free environmentally acceptable lubricating oil additives. Particularly, borate ester with short alkyl chain length at a low concentration in liquid paraffin was more effective in reducing wear, and the antiwear ability of the additives decreased with increasing alkyl chain length. The antiwear ability of the N-containing borate esters as additives in liquid paraffin might be closely related to the formation of hydrogen bonds via N with a high electronegativity and small atomic radius and the easy permeation of electron-deficient B on the rubbing steel surfaces.

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