Preliminary Study on Reaction Kinetics of Ammonia Nitrogen in Aqueous Samples Removed by Microbial Nano-Silica Ball

2014 ◽  
Vol 1010-1012 ◽  
pp. 528-531
Author(s):  
Chao Yin ◽  
Jia Lu ◽  
Xiao Hou Shao ◽  
Xin Yu Mao ◽  
Long Wang ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Enrichment Culture ◽  
Kinetic Equations ◽  
Culture Liquid ◽  
Ammonia Nitrogen ◽  
Aqueous Samples ◽  
Nano Silica ◽  
N Removal ◽  
Preliminary Study ◽  
Kinetics Of

EM enrichment culture liquid was immobilized on nano-silica carrier to form microbial nano ball, so as to investigate the reaction kinetics of ammonia nitrogen (NH4+-N) by microbial nano ball. The results showed that first order reaction kinetics model could describe NH4+-N removal by different diameter microbial nano-silica balls well. And the microbe could keep higher biological activity between 0-72h. Reaction kinetic equations of NH4+-N were: (1) when diameter was 10mm, (0-48h), (48-72h); (2) when diameter was 20mm, (0-48h), (48-72h); (3) (0-48h), (48-72h).

Preliminary Study on Influencing Factors of Wastewater Purification by Microbial Nano-Silica Ball

2014 ◽  
Vol 1010-1012 ◽  
pp. 777-784 ◽  
Author(s):  
Chao Yin ◽  
Xiao Hou Shao ◽  
Long Wang ◽  
Xin Yu Mao ◽  
Jia Lu ◽  
...  
Keyword(s):  
Dissolved Oxygen ◽  
Influencing Factors ◽  
Enrichment Culture ◽  
Removal Rate ◽  
Culture Liquid ◽  
Ammonia Nitrogen ◽  
Nano Silica ◽  
Wastewater Purification ◽  
N Concentration ◽  
Preliminary Study

EM enrichment culture liquid was immobilized on nano-silica carrier consisting of pond sediment, zeolite powder and nano-silica to form microbial nano-silica ball. Influencing factors of initial ammonia nitrogen (NH4+-N), COD, pH and dissolved oxygen (DO) concentrations on wastewater purification by microbial nano-silica ball were studied. The results showed that removal rate of NH4+-N, total nitrogen (TN) and total phosphorus (TP) was the highest with COD concentration of 500mg/L when initial COD was ranged from 250 to 2000mg/L. On the condition of initial NH4+-N concentration ranged from 50 to 500mg/L, removal amount of NH4+-N and TN in wastewater reached the maximum when NH4+-N concentration was 400mg/L. On the condition that pH was ranged from6 to 9, removal effect of pollutants was the best when pH was 8. The results also showed that NH4+-N and TN removal rates in wastewater could be increased by appropriate aeration. But aeration had no effect on TP removal rate in wastewater.

Preliminary study on removal of nitrate nitrogen in aqueous samples by microbial nano-silica ball

2014 ◽  
Author(s):  
Jia Lu ◽  
Xiaohou Shao ◽  
Chao Yin ◽  
Xinyu Mao ◽  
Long Wang ◽  
...  
Keyword(s):  
Nitrate Nitrogen ◽  
Aqueous Samples ◽  
Nano Silica ◽  
Preliminary Study

An investigation of the kinetics of a reversible monomolecular reaction between n components

1979 ◽  
Vol 44 (4) ◽  
pp. 1146-1159 ◽  
Author(s):  
Jaromír Jakeš
Keyword(s):  
Reaction Kinetics ◽  
Kinetic Equations ◽  
Computer Programs ◽  
Matrix Form ◽  
Monomolecular Reaction ◽  
Kinetics Of ◽  
Derivatives Of

It has been shown that the solution of kinetic equations can be transformed into diagonalization of a symmetrical matrix, in contrast with the solution known so far and requiring diagonalization of a nonsymmetrical matrix. Simple formulas are given for the calculation of derivatives of the concentrations of individual components with respect to the parameters. All formulas are presented in a compact matrix form; their uniformity for a large number of cases recognized in the existing literature greatly facilitates writing computer programs for calculations of reaction kinetics.

Hydrogen Passivation Kinetics of Si Nanocrystals in SiO2

2003 ◽  
Vol 770 ◽  
Author(s):  
Andrew R. Wilkinson ◽  
Robert G. Elliman
Keyword(s):  
Reaction Kinetics ◽  
Activation Energies ◽  
Hydrogen Passivation ◽  
Time Resolved ◽  
Luminescence Efficiency ◽  
Si Nanocrystals ◽  
Preliminary Study ◽  
Kinetics Of ◽  
Insight Into

AbstractHydrogen passivation of non-radiative defects increases the luminescence intensity from silicon nanocrystals. In this study, photoluminescence (PL) and time-resolved PL were used to investigate the chemical kinetics of the hydrogen passivation process. Isochronal and isothermal annealing sequences were used to determine the reaction kinetics for the absorption and desorption of hydrogen, using the generalised consistent simple thermal (GST) model proposed by Stesmans for Pb defects at planar Si/SiO2 interfaces. This included determination of the activation energies and rate constants for the forward and reverse reactions as well as the associated spread in activation energies. The reaction kinetics determined from such measurements were found to be in excellent agreement with those for the passivation of Pb defects at planar Si/SiO2 interfaces, suggesting the nanocrystal emission process is also limited by such defects. These results provide useful model data as well as insight into the processing conditions needed to achieve optimum passivation in H2. As an extension to the work, a preliminary study into passivation by atomic hydrogen was pursued via a post-metallization Al anneal (alneal). A considerable gain in luminescence efficiency was achieved over the previously optimised passivation in H2.

Preliminary Study on Purification of Aquaculture Wastewater by Microbial Nano-Silica Ball

2014 ◽  
Vol 955-959 ◽  
pp. 2187-2191 ◽  
Author(s):  
Long Wang ◽  
Xiao Hou Shao ◽  
Jian Qiang Mao ◽  
Xin Yu Mao ◽  
Chao Yin ◽  
...  
Keyword(s):  
Removal Rate ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Nano Silica ◽  
Initial Value ◽  
Ratio Condition ◽  
Active Calcium ◽  
Preliminary Study ◽  
Aquaculture Wastewater ◽  
Water Ratio

To form microbial nanoball, EM active calcium was immobilized on nano-silica carrier consisting of pond sediment, zeolite powder and nanosilica. Through real-time monitoring of pH, dissolved oxygen (DO), chemical oxygen demand (COD) and ammonia nitrogen (NH4+-N) aquaculture wastewater, the purification effects of Microbial nanoSilica Ball on aquaculture wastewater under different mud-water ratio condition were studied. The results showed that the purification effect reached best in 3-6 days for all treatments and was better for mud-water ratio of 1:2.7. In this mud-water ratio, it was indicated that pH was maintained at 7-8.5 which was an optimum value for the aquaculture, the content of DO was increased by 82.16% compared with the initial value and the removal rate of COD and NH4+-N was 57.80% and 54.60% respectively.

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

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