Summary
This paper describes the design procedures that led to favorable incremental oil production and reduced water production during 12 years of successful polymer flooding in the Daqing oil field. Special emphasis is placed on some new design factors that were found to be important on the basis of extensive experience with polymer flooding. These factors include (1) recognizing when profile modification is needed before polymer injection and when zone isolation is of value during polymer injection, (2) establishing the optimum polymer formulations and injection rates, and (3) time-dependent variation of the molecular weight of the polymer used in the injected slugs.
For some Daqing wells, oil recovery can be enhanced by 2 to 4% of original oil in place (OOIP) with profile modification before polymer injection. For some Daqing wells with significant permeability differential between layers and no crossflow, injecting polymer solutions separately into different layers improved flow profiles, reservoir sweep efficiency, and injection rates, and it reduced the water cut in production wells. Experience over time revealed that larger polymer-bank sizes are preferred. Bank sizes grew from 240-380 mg/L·PV during the initial pilots to 640 to 700 mg/L·PV in the most recent large-scale industrial sites [pore volume (PV)]. Economics and injectivity behavior can favor changing the polymer molecular weight and polymer concentration during the course of injecting the polymer slug. Polymers with molecular weights from 12 to 35 million Daltons were designed and supplied to meet the requirements for different reservoir geological conditions. The optimum polymer-injection volume varied around 0.7 PV, depending on the water cut in the different flooding units. The average polymer concentration was designed approximately 1000 mg/L, but for an individual injection station, it could be 2000 mg/L or more. At Daqing, the injection rates should be less than 0.14-0.20 PV/year, depending on well spacing.
Introduction
Many elements have long been recognized as important during the design of a polymer flood (Li and Niu 2002; Jewett and Schurz 1970; Sorbie 1991; Vela et al. 1976; Taber et al. 1997; Maitin 1992; Koning et al. 1988; Wang et al. 1995; Wang and Qian 2002; Wang et al. 2008). This paper spells out some of those elements, using examples from the Daqing oil field. The Daqing oil field is located in northeast China and is a large river-delta/lacustrine-facies, multilayer, heterogeneous sandstone in an inland basin. The reservoir is buried at a depth of approximately 1000 m, with a temperature of 45°C. The main formation under polymer flood (i.e., the Saertu formation) has a net thickness ranging from from 2.3 to 11.6 m with an average of 6.1 m. The average air permeability is 1.1 µm2, and the Dykstra-Parsons permeability coefficient averages 0.7. Oil viscosity at reservoir temperature averages approximately 9 mPa·s, and the total salinity of the formation water varies from 3000 to 7000 mg/L. The field was discovered in 1959, and a waterflood was initiated in 1960. The world's largest polymer flood was implemented at Daqing, beginning in December 1995. By 2007, 22.3% of total production from the Daqing oil field was attributed to polymer flooding. Polymer flooding should boost the ultimate recovery for the field to more than 50% OOIP--10 to 12% OOIP more than from waterflooding. At the end of 2007, oil production from polymer flooding at the Daqing oil field was more than 11.6 million m3 (73 million bbl) per year (sustained for 6 years). The polymers used at Daqing are high-molecular-weight partially hydrolyzed polyacrylamides (HPAMs).
During design of a polymer flood, critical reservoir factors that traditionally receive consideration are the reservoir lithology, stratigraphy, important heterogeneities (such as fractures), distribution of remaining oil, well pattern, and well distance. Critical polymer properties include cost-effectiveness (e.g., cost per unit of viscosity), resistance to degradation (mechanical or shear, oxidative, thermal, microbial), tolerance of reservoir salinity and hardness, retention by rock, inaccessible pore volume, permeability dependence of performance, rheology, and compatibility with other chemicals that might be used. Issues long recognized as important for polymer-bank design include bank size (volume), polymer concentration and salinity (affecting bank viscosity and mobility), and whether (and how) to grade polymer concentrations in the chase water.
This paper describes the design procedures that led to favorable incremental oil production and reduced water production during 12 years of successful polymer flooding in the Daqing oil field.
Experimental Study of Thermal and Catalytic Pyrolysis of Plastic Waste Components
