Influence of Silane Coupling Agent on Interfacial Strength of SMA Composite

2010 ◽  
Vol 143-144 ◽  
pp. 933-937
Author(s):  
Yu Long Wang ◽  
Zhen Qing Wang ◽  
Li Min Zhou ◽  
Hai Tao Huang

Shape memory alloy (SMA) can be embedded into a host material to achieve shape control, damage repair and self-adaption. It is well recognized that the applications of SMA composites are highly dependent on the integrity of SMA fiber-matrix interface. However, the interfacial debonding often occurs due to the weak bonding of interface between the SMA wire and its surrounding matrix. Therefore, it is necessary to improve interfacial strength of SMA composites. In present paper, the epoxy resin is functionalized by mixing different amount of silane coupling agent to improve the interfacial adhesion of SMA fiber reinforced epoxy matrix composite. The single fiber pull-out test is carried out to evaluate the interfacial strength and the test results indicate that the interfacial strength of SMA composite is improved significantly as compared to the results from unfunctionalized samples.

2014 ◽  
Vol 915-916 ◽  
pp. 709-712
Author(s):  
Xiao Li Wei ◽  
Fa Xing Zhang

In this paper nanoSiO2 particles were prepared with the surface grafted fluorine coupling agents and double bond by using surface modification technology. Dispersion effect of nanoSiO2 particles were studied in different solvents ultrasound cavitation. Test results showed in infrared spectroscopy, TEM and laser particle size distribution analyzer that both F8261 and KH-570 have been grafted onto the surface of nanoSiO2 , particle size and distribution of nanoSiO2 after modified by the two coupling agent became smaller and more narrow; Tg-DSC analysis showed that when the amount of of the coupling agent is up to 10%, fluorine coupling agent and double bond grafted onto surface of nanoSiO2 particles reach the saturation.


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Xuetao Qiao ◽  
Peng Wang ◽  
Cunfu Yan ◽  
Fang Li ◽  
Long Wu

In order to explore the influence of the shape and surface treatment of steel fiber on the mechanical properties of artificial granite matrix, the drawing models of W-type, L-type, V-type, and I-type steel fiber are established, the pull-out force of different shapes of steel fiber is calculated theoretically, and a large number of experimental specimens are made for the pull-out test of steel fiber and material strength test. Both theory and experiment show that W-type steel fiber has the greatest influence in artificial granite. The steel fibers with different shapes were treated with KH-550 silane coupling agent. Then the steel fibers with different shapes before and after treatment were put into the artificial granite matrix for pull-out test and material strength test. The results showed that, compared with L-type, V-type, and I-type steel fibers before and after KH-550 silane coupling agent treatment, W-type steel fibers after KH-550 silane coupling agent treatment have the best strength enhancement effect in artificial granite matrix.


2014 ◽  
Vol 670-671 ◽  
pp. 387-390
Author(s):  
Wei Li ◽  
Zhen Huang ◽  
Xiao Chu Wang ◽  
Jun Wei Wang

5-8 mesh rubber granules was mixed with an equal volume instead of fine aggregate, and the content of rubber was 5%, 10%, 15% and 20%. Compared with the influence of silane coupling agent, latex and silica fume to the mechanical properties of rubber concrete, it studied the mechanism of rubber-modified to the rubber concrete. The test results proved that the silane coupling agent, latex, and silica fume could improve the compressive strength, splitting and flexural strength. Latex could significantly improve the bond strength of cement-based materials and the integrity of the concrete. Coupling agent made rubber bond with cement-based materials to form a stable connection, and silica fume filled the pore in concrete, so it optimized the gradation. Latex was the best, silane coupling agents was second, and silica fume was the last about the improved effect of three kinds of modifiers.


2012 ◽  
Vol 724 ◽  
pp. 274-277 ◽  
Author(s):  
Yan Yan Luan ◽  
Xue Feng Liu ◽  
Zhan Nan Peng ◽  
Jian Xin Xie

nanoTiO2/PBO composite fiber was prepared with a chemical method by depositing nanoTiO2 on the surface of PBO fiber which was treated by silane coupling agent. The process parameters on the preparation of nanoTiO2/PBO composite fiber were optimized according to the interfacial adhesion between the composite fiber and epoxy resin, and the coating mechanism of nanoTiO2/PBO composite fiber was also discussed. The results show that the uniform nanoTiO2/PBO composite fiber with high interfacial adhesion can be prepared on the PBO fiber which was pretreated by silane coupling agent with a concentration of 1.5 % for 35 min at room temperature, in which the nanoTiO2 aqueous solution with a concentration of 1.0wt% was ultrasonic dispersed for 1h in alkaline environment (pH 11), and then the PBO fiber was immersed in the dispersed solution at 60 °C for 6 h to prepare nanoTiO2/PBO composite fiber. The single fiber pull-out strength of the prepared composite fiber was increased by 85.28 % compared with that of the untreated PBO fiber. Silane coupling agent was a bridge of PBO and nanoTiO2, hydrogen bond association and like dissolves like were attributed to the improvement of interfacial adhesion between nanoTiO2 and PBO fiber.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2254
Author(s):  
Adeleke A. Oyekanmi ◽  
N. I. Saharudin ◽  
Che Mohamad Hazwan ◽  
Abdul Khalil H. P. S. ◽  
Niyi G. Olaiya ◽  
...  

Hydrophilic behaviour of carrageenan macroalgae biopolymer, due to hydroxyl groups, has limited its applications, especially for packaging. In this study, macroalgae were reinforced with cellulose nanofibrils (CNFs) isolated from kenaf bast fibres. The macroalgae CNF film was after that treated with silane for hydrophobicity enhancement. The wettability and functional properties of unmodified macroalgae CNF films were compared with silane-modified macroalgae CNF films. Characterisation of the unmodified and modified biopolymers films was investigated. The atomic force microscope (AFM), SEM morphology, tensile properties, water contact angle, and thermal behaviour of the biofilms showed that the incorporation of Kenaf bast CNF remarkably increased the strength, moisture resistance, and thermal stability of the macroalgae biopolymer films. Moreover, the films’ modification using a silane coupling agent further enhanced the strength and thermal stability of the films apart from improved water-resistance of the biopolymer films compared to unmodified films. The morphology and AFM showed good interfacial interaction of the components of the biopolymer films. The modified biopolymer films exhibited significantly improved hydrophobic properties compared to the unmodified films due to the enhanced dispersion resulting from the silane treatment. The improved biopolymer films can potentially be utilised as packaging materials.


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