Piezoelectric and Dielectric Properties of MnO2-Modified Bi(Mg1/2Ti1/2)O3–PbTiO3

2011 ◽  
Vol 415-417 ◽  
pp. 1983-1987
Author(s):  
Xiao Na Wang ◽  
Qing Chi Sun ◽  
Wei Bing Ma ◽  
Tao Liu ◽  
Yong Zhang ◽  
...  

We reported that Bi(Mg1/2Ti1/2)O3–PbTiO3(BMT-PT) systems had high piezoelectric, dielectric performances and high Curie temperature. The phase structure of the system was identified by X-ray diffraction analysis. The piezoelectric and dielectric properties were also investigated. The results showed that 0.6BMT–0.4PT (Mg/Ti = 0.5:0.5) with 1mol% MnO2was the optimum composition which exhibited the highest curie temperature Tc = 511 °C and the stable temperature of dielectric loss reached to 500 °C. Further, the dielectric and piezoelectric properties of this composition were given as follows:kp = 22.5%;εr= 734; room temperature d33= 131.3 pC/N; tanδ = 1.96%.

2006 ◽  
Vol 317-318 ◽  
pp. 849-852
Author(s):  
Hua Jun Sun ◽  
Wen Chen ◽  
Xiao Fang Liu ◽  
Qing Xu ◽  
Jing Zhou ◽  
...  

xPb(Ni1/3Nb2/3)O3-yPb(Mn1/3Nb1/3Sb1/3)O3-(1-x-y)Pb(Zr0.48Ti0.52)O3 ceramics have been prepared by a columbite two-step method. NiNb2O6, MnNb2O6 and MnSb2O6 were used as precursors to produce the pseudoquintnary system ceramics. X-ray diffraction (XRD) results indicate that the pseudoquintnary system ceramics have a single-phase perovskite structure. The piezoelectric and dielectric properties of the ceramics were investigated as functions of x or y. The addition of Pb(Ni1/3Nb2/3)O3 makes the piezoelectric properties to become ‘soft’, while the addition of Pb(Mn1/3Nb1/3Sb1/3)O3 makes the piezoelectric properties to be ‘hard’. The Curie temperature (Tc) of the pseudoquintnary system decreases with the increase of Pb(Ni1/3Nb2/3)O3 or Pb(Mn1/3Nb1/3Sb1/3)O3 contents. The preferred piezoelectric properties were obtained in the composition with x=0.06 and y=0.06.


1999 ◽  
Vol 14 (11) ◽  
pp. 4307-4318 ◽  
Author(s):  
S. Hiboux ◽  
P. Muralt ◽  
T. Maeder

In situ reactively sputter deposited, 300-nm-thick Pb(Zrx, Ti1−x)O3 thin films were investigated as a function of composition, texture, and different electrodes (Pt,RuO2).X-ray diffraction analysis, ferroelectric, dielectric, and piezoelectric measurements were carried out. While for dielectric properties bulklike contributions from lattice as well as from domains are observed, domain wall contributions to piezoelectric properties are very much reduced in the morphotropic phase boundary (MPB) region. Permittivity and d33 do not peak at the same composition; the MPB region is broadened up and generally shifted to the tetragonal side.


2011 ◽  
Vol 284-286 ◽  
pp. 1408-1411
Author(s):  
Yan Li ◽  
Yan Jie Zhang ◽  
Rui Qing Chu ◽  
Zhi Jun Xu ◽  
Qian Chen ◽  
...  

La2O3-doped lead-free 0.82Bi0.5Na0.5TiO3-0.18Bi0.5K0.5TiO3(abbreviated to 0.82BNT-0.18BKT) piezoelectric ceramics were synthesized by the conventional mixed-oxide method, and the effect of La2O3addition on the dielectric and piezoelectric properties was investigated. X-ray diffraction (XRD) patterns show that La2O3diffuses into the lattice of the 0.82BNT-0.18BKT ceramics to form a solid solution with a pure perovskite structure. SEM images indicate that the grain size of the 0.82BNT-0.18BKT ceramics increased with the addition of La2O3doping. The electrical properties of 0.82BNT-0.18BKT ceramics have been greatly improved by certain amount of La2O3substitutions. At room temperature, the 0.82BNT-0.18BKT ceramics doped with 0.25 wt. % La2O3exhibited the optimum properties with high piezoelectric constant (d33= 142 pC/N) and high planar coupling factor (kp= 0.23).


2007 ◽  
Vol 280-283 ◽  
pp. 251-254 ◽  
Author(s):  
Su Chuan Zhao ◽  
Lina Zhang ◽  
Guo Rong Li ◽  
Liao Ying Zheng ◽  
Ai Li Ding

Na0.42K0.08Bi0.5TiO3 and Na0.45K0.05Bi0.5TiO3 ceramics were fabricated by the solid-state reaction. The structures were determined by X-ray diffraction. Dielectric, ferroelectric and piezoelectric properties of the ceramics were measured and discussed. The ceramics have a single perovskite phase with rhombohedral symmetry at room temperature. The thermal variations of the permittivity follow the law 1/ e − 1/ em = C(T − Tm)2 which is the character of typical relax ferroelectrics, when temperature is higher than the temperature of the maximum of dielectric constant (Tm). The depolarization temperature (Td) of spontaneous polarization is 215oC for Na0.45K0.05Bi0.5TiO3 and 152oC for Na0.42K0.08Bi0.5TiO3 respectively. There exist two different dielectric behaviors of the Na0.42K0.08Bi0.5TiO3 ceramic, without and after poling. Na0.45K0.05Bi0.5TiO3 possesses relatively high kt and Td. The use for device application has been indicated.


RSC Advances ◽  
2018 ◽  
Vol 8 (43) ◽  
pp. 24286-24296 ◽  
Author(s):  
Sushmita Dwivedi ◽  
Tanvi Pareek ◽  
Sunil Kumar

Room temperature powder X-ray diffraction patterns of (1 – x)K0.5Na0.5NbO3–xBi(Zn0.5Ti0.5)O3 system.


2013 ◽  
Vol 582 ◽  
pp. 84-87 ◽  
Author(s):  
Ryuta Mitsui ◽  
Ichiro Fujii ◽  
Kouichi Nakashima ◽  
Nobuhiro Kumada ◽  
Yoshihiro Kuroiwa ◽  
...  

1-x-y)BaTiO3-xBi (Mg1/2Ti1/2)O3-yBiFeO3 ceramics were prepared by a conventional solidstate synthesis, and crystal structure and electric properties were investigated. Synchrotron X-ray diffraction pattern revealed that a single perovskite phase was obtained for samples at x=0.05-0.15, y=0.46.5-73.5. Splitting of the (111) peak was observed when (x, y) = (0.050, 0.685) and (0.050, 0.735) indicating that crystal structure of samples changed from a pseudo-cubic phase to a rhombohedral phase with increasing BF. As the BF content increased, the Curie temperature increased. The largest maximum strain (Smax) over the applied maximum electric field (Emax) value (Smax / Emax) of 300 pm/V was observed for 0.365BT-0.050BMT-0.585BF at 25 °C and 1Hz with the Curie temperature of 390 °C.


2020 ◽  
Vol 42 (5) ◽  
pp. 634-634
Author(s):  
Fares Kahoul Fares Kahoul ◽  
Louanes Hamzioui Louanes Hamzioui ◽  
Abderrezak Guemache Abderrezak Guemache ◽  
Michel Aillerie and Ahmed Boutarfaia Michel Aillerie and Ahmed Boutarfaia

Modified-PZT ceramics with a formula (1-x)Pb(Zr0.53 Ti0.47)O3-xSr(Fe2/3, Nb1/3)O3 (doped with isovalent: Sr2+, acceptor: Fe3+ and Donor: Nb5+ ions) abbreviated as (1-x)PZT-xSFN binary system with varying x (x= 0.02, 0.04, 0.06, 0.08 and 0.10) located near the morphotropic phase boundary (MPB) were prepared by a traditional process in a solid state. All the samples were sintered at a temperature of 1200and#176;C during 2 h. The phase structure, the dielectric and piezoelectric properties of the system were studied. In-phase analysis used X-ray diffraction (XRD) at room temperature indicated that the structure of phase of sintered PZT-SFN ceramics was formed in single-phase with a crystalline structure tetragonal. Raman spectroscopy confirms the presence of this tetragonal phase. The optimum electrical parameters are obtained at 0.94Pb(Zr0.53Ti0.47)O3-0.06Sr(Fe2/3, Nb1/3)O3 system: kp= 66.10 %, d31= 145 pC/N, Qm= 473, tanδ= 1.11 %, and ɛr= 1009.


2011 ◽  
Vol 01 (03) ◽  
pp. 345-349 ◽  
Author(s):  
ERIC A. PATTERSON ◽  
DAVID P. CANN

Solid solutions based on Li , Ta and Sb -doped (K0.5Na0.5)NbO3 (KNN) lead-free perovskite systems were created using standard solid-state methods. X-ray diffraction was used to confirm that all compositions were single phase and to verify the phase transition from tetragonal to cubic at TC = 302° C . The three compositions examined, originally developed by Saito and Li , were shown to be strongly ferroelectric with sharp peaks in permittivity present at the Curie temperature. The optimum composition had loss tangent values below 5% up to 100 kHz at room temperature. Bipolar hysteresis measurements showed high values for both maximum polarization (25 and 21 μC/cm2) and remenant polarizations (20 and 16 μC/cm2) for undoped and 0.2 wt% CuO -doped samples. Maximum strain values of greater than 0.23% were observed.


RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12826-12832
Author(s):  
Junjie Xiong ◽  
Zujian Wang ◽  
Xiaoming Yang ◽  
Rongbing Su ◽  
Xifa Long ◽  
...  

The ε33T/ε0 and d33 values of ACP 0.66PIN–0.34PT crystals are shown to be 3070 and 1400 pC N−1, respectively, which are 14% and 18% larger than those of a DCP sample, owing to the enhancement of both intrinsic and extrinsic contributions.


2004 ◽  
Vol 19 (7) ◽  
pp. 2185-2193 ◽  
Author(s):  
Runrun Duan ◽  
Robert F. Speyer ◽  
Edward Alberta ◽  
Thomas R. Shrout

The extent of BiInO3 substitution in the perovskite system xBiInO3–(1 - x)PbTiO3 and the corresponding raise in the Curie temperature were investigated using thermal analysis, dielectric measurements, x-ray diffraction, and electron microscopy. Maximum tetragonal perovskite distortion (c/a = 1.082) was obtained for x = 0.20, with a corresponding Curie temperature of 582 °C. Phase-pure tetragonal perovskite was obtained for x ⩽ 0.25. Compound formation after calcining mixed oxide powders resulted in agglomerated cube-shaped tetragonal perovskite particles, which could be fired to 94.7% of theoretical density (TD). Sol-gel fabrication resulted in nano-sized tetragonal or pseudo-cubic perovskite particles, which after two-step firing, resulted in a tetragonal perovskite microstructure at as high as (x = 0.20) 98.1% of TD.


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