Preparation of Low-K Fluorinated Polyimide/Phlogopite Nanocomposites

2008 ◽  
Vol 47-50 ◽  
pp. 987-990
Author(s):  
Yi He Zhang ◽  
Qing Song Su ◽  
Li Yu ◽  
Li Bing Liao ◽  
Hong Zheng ◽  
...  
Keyword(s):  
In Situ Polymerization ◽  
Layered Silicate ◽  
Polymer Nanocomposite ◽  
Nanocomposite Films ◽  
Polymerization Process ◽  
Ultrasonic Dispersion ◽  
Thermal Stabilities ◽  
Fluorinated Polyimide ◽  
Polyimide Matrix

Phlogopite with layered silicate structure had been firstly chemically modified via an in situ intercalation method, and phlogopite-polymer nanocomposite films were prepared from 2,2'-bis (3,4-dicarboxyphenyl) hexafluropropane dianhydride (6FDA) and oxydimethyl aniline (ODA) in N,N-dimethylacetamide as a solvent by using in-situ polymerization process combined with ultrasonic dispersion and multi-step curing. The structure of phlogopite minerals and its polymer nanocomposites were characterized by X-ray diffraction (XRD) and infrared spectra (FTIR) respectively. The experimental results indicated that the phlogopites with layered nanostructure had lost their ordered structure and had been exfoliated or intercalated. Thereafter, they were dispersed randomly in the polyimide matrix. The dependence of dielectric properties and thermal stabilities of the nanocomposite films on the phlogopite content and frequency were studied.

Electrical properties of TiO2-filled polyimide nanocomposite films prepared via an in situ polymerization process

2010 ◽  
Vol 160 (23-24) ◽  
pp. 2670-2674 ◽  
Author(s):  
Jun-Wei Zha ◽  
Zhi-Min Dang ◽  
Tao Zhou ◽  
Hong-Tao Song ◽  
George Chen
Keyword(s):  
Electrical Properties ◽  
In Situ Polymerization ◽  
Nanocomposite Films ◽  
Polymerization Process ◽  
Polyimide Nanocomposite

scholarly journals UHMWPE-layered silicate nanocomposites by in situ polymerization with tris(pyrazolyl)borate titanium/clay catalyst

2009 ◽  
Vol 20 (3) ◽  
pp. 472-477 ◽  
Author(s):  
Fernando Junges ◽  
Mariana S. Beauvalet ◽  
Bárbara C. Leal ◽  
Adriana C. A. Casagrande ◽  
Fábio F. Mota ◽  
...  
Keyword(s):  
In Situ Polymerization ◽  
Layered Silicate ◽  
Silicate Nanocomposites ◽  
Clay Catalyst

scholarly journals Capacitive type Humidity Sensor based on PANI decorated Cu-Zns Porous Micropshere

2020 ◽  
Author(s):  
Jolly Bhadra ◽  
Hemalatha Parangusan ◽  
Zubair Ahmad ◽  
Shoaib Mallick ◽  
Farid Touati ◽  
...  
Keyword(s):  
Humidity Sensor ◽  
In Situ Polymerization ◽  
Fast Response ◽  
Polymerization Process ◽  
Average Response ◽  
Surface Absorption ◽  
Absorption Properties ◽  
Recovery Times ◽  
Response And Recovery

PANI coated Cu-ZnS porous microsphere structures have been synthesized by hydrothermal method and in-situ polymerization process. The synthesized composite is characterized by different techniques in order to study the structural, morphological and surface absorption properties. The experimental observation demonstrates that the PANI/1%Cu-ZnS composite has better sensitivity, fast response and good stability as compared to pure PANI and other PANI/CuZnS compositions. Finally, PANI/1% Cu-ZnS composite has been found to be optimized for the humidity sensors due to its well-distributed roughness, porosity and hydrophilicity. The average response and recovery times of the PANI/1% Cu-ZnS are found to be 42 s and 24 s, respectively, which outperform recent results.

In Situ Fabrication of Nanoscale Graphene Oxide/Polyaniline Composite and its Electrochemical Properties

2010 ◽  
Vol 148-149 ◽  
pp. 1547-1550 ◽  
Author(s):  
Hua Lan Wang ◽  
Qing Li Hao ◽  
Xi Feng Xia ◽  
Zhi Jia Wang ◽  
Jiao Tian ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
In Situ Polymerization ◽  
Ammonium Persulfate ◽  
Polymerization Process ◽  
Electrochemical Test ◽  
X Ray ◽  
Transmission Electron

A graphene oxide/polyaniline composite was synthesized by an in situ polymerization process. This product was simply prepared in an ethylene glycol medium, using ammonium persulfate as oxidant in ice bath. The composite was characterized by field emission scanning electron microscopy, transmission electron microscopy, X-Ray photoelectron spectroscopy, Raman spectroscopy and electrochemical test. The composite material showed a good electrochemical performance.

scholarly journals In Situ Polymerization of Chiral Poly(fluorene-alt-benzothiadiazole) Nanocomposites with Enhanced Chirality

2020 ◽  
Vol 10 (23) ◽  
pp. 8740
Author(s):  
Hongsub Jee ◽  
Hyeong-Sub Oh ◽  
Jaehyeong Lee
Keyword(s):  
Optical Activity ◽  
In Situ Polymerization ◽  
Nanocomposite Films ◽  
High Quality ◽  
Chiral Metamaterials ◽  
Visible Wavelengths ◽  
Chiral Polymer

Poly(fluorene-alt-benzothiadiazole) (PFBT) is a promising chiral polymer for use in metamaterials and other photonic applications, due to its large chiral optical activity at visible wavelengths. However, its usages are very limited, since it is not readily patternable into microstructures and challenging to apply to applications. In this paper, we demonstrate photo patterning of chiral PFBT/Achiral SU-8 photoresist to produce high quality structures while retaining the extraordinary chiral optical activity of our previously-reported PFBT/SU8 nanocomposite films. The ability to produce cleanly patterned microfeatures with high chirality may enable wider use of PFBT in chiral metamaterials and other photonic applications.

Influence of nanoparticle morphology on reaction kinetics, particle size and rheology in acrylic latex

2015 ◽  
Vol 1767 ◽  
pp. 17-22 ◽  
Author(s):  
Mireya L. Hernandez-Vargas ◽  
Angel Romo-Uribe ◽  
Jamil Baghdachi
Keyword(s):  
Particle Size ◽  
Reaction Kinetics ◽  
Emulsion Polymerization ◽  
In Situ Polymerization ◽  
Layered Silicate ◽  
Monomer Conversion ◽  
Polymerization Process ◽  
Acrylic Latex ◽  
Melt Compounding ◽  
Nanoparticle Morphology

ABSTRACTOrganic/inorganic (O/I) composite latexes combine the best attributes of inorganic solids with the processability, lightweight and handling advantages of organic polymers. There are common methods to produce polymer nanocomposites: melt compounding, in-situ polymerization and solution mixing. Emulsion polymerization is an unique chemical process widely used to produce waterborne resins with various colloidal and physicochemical properties. This free radical polymerization process involves emulsification of the relatively hydrophobic monomer in water by an oil-in-water emulsifier, followed by the initiation reaction with a water insoluble initiator. This research focuses on the synthesis and reactions kinetics of polyacrylic latex with the incorporation of various nanospheres (SiO2, TiO2, Al2O3 and Fe2O3), and layered silicate (Bentonite nanoclay) nanoparticles via emulsion polymerization. The influence of nanoparticle concentration on reaction kinetics was also investigated. The results showed that the concentration of nanoparticles has significant influence on the monomer conversion, particle size, coagulum content and viscosity of the emulsion. Furthermore, the nanostructured emulsions were shear thinning, exhibiting a power-law behavior, and the viscosity was influenced by the nanoparticle morphology.

Study on the Properties of MWNTs/Polyethylene Nanocomposites by In Situ Polymerization

2012 ◽  
Vol 192 ◽  
pp. 289-292
Author(s):  
Shi Yun Li ◽  
De Sheng Hu
Keyword(s):  
Mechanical Properties ◽  
In Situ Polymerization ◽  
Thermal Stabilities ◽  
Multi Walled Carbon Nanotubes ◽  
Photooxidative Stability ◽  
Shielding Properties ◽  
Walled Carbon Nanotubes ◽  
Very High ◽  
Fractured Surface

Multi–walled carbon nanotubes (MWNTs)/polyethylene (PE) nanocomposites were prepared via in situ polymerization with MWNTs supported Cp2ZrCl2 catalyst. XPS and FESEM results imply that Cp2ZrCl2 catalyst has been immobilized in the surface of the MWNTs supports by a MAO bridge. The efficient dispersion of MWNTs in PE matrix and the strong compressive forces associated with PE on the MWNTs were demonstrated by TEM, FESEM and Raman spectra. With introducing 0.2 wt.-% MWNTs, both the tensile strength and elongation of MWNTs/PE nanocomposite increased by factors of 1.6 (from 29 MPa to 45 MPa) and 1.5 (from 909% to 1360%) comparing with the pure PE, respectively. Morphology observation of fractured surface, in accordance with the Raman results, revealed that the PE firmly adheres to the nanotubes, which is responsible for the significant improvement of the mechanical properties of nanocomposites. Thermal stabilities of the nanocomposites were significantly improved. In addition, the MWNTs/PE nanocomposites show very high UV shielding properties, which could increase photooxidative stability of the PE.

Fabrication and Ultraviolet Characterization of Potassium Sodium Niobate/Polyimide Hybrid Films

2013 ◽  
Vol 395-396 ◽  
pp. 121-124
Author(s):  
Jia Qi Lin ◽  
Pan Pan Zhang ◽  
Wen Long Yang
Keyword(s):  
In Situ Polymerization ◽  
Composite Films ◽  
Polymerization Process ◽  
Sodium Niobate ◽  
Hybrid Films ◽  
Potassium Sodium Niobate ◽  
Potassium Sodium

A functional potassium sodium niobate/polyimide (KNN/PI) composite films were prepared in this paper. KNN fillers are well dispersed in the PI matrix without any accumulation through in situ polymerization process. The optical band baps of the hybrid films become smaller with the increase of KNN loading. The optical band baps of the films with 0-20 wt% KNN filler are estimated to be 2.61 eV, 2.57 eV, 2.52 eV, 4.29 eV, 2.35 eV respectively.

scholarly journals Facile preparation of polyimide/graphene nanocomposites via an in situ polymerization approach

RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 3003-3011 ◽  
Author(s):  
Songlv Qin ◽  
Cheng Chen ◽  
Mingjun Cui ◽  
Afang Zhang ◽  
Haichao Zhao ◽  
...  
Keyword(s):  
In Situ Polymerization ◽  
Aromatic Diamine ◽  
Graphene Nanocomposites ◽  
Good Dispersion ◽  
Facile Preparation ◽  
Polyimide Matrix

In this study, to achieve a compatible and good dispersion of graphene in polyimide matrix, we synthesized an aromatic diamine, aniline trimer, as a polymerizable graphene dispersant.

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