Cuprous Oxide Thin Films for a Photoelectrochemical Cell of ITO/Cu2O/PVC-LiClO4/Graphite

2012 ◽  
Vol 501 ◽  
pp. 247-251 ◽  
Author(s):  
Dewi Suriyani Che Halin ◽  
Ibrahim Abu Talib ◽  
Abdul Razak Daud ◽  
Muhammad Azmi Abd Hamid

Cuprous oxide (Cu2O) thin films were formed onto indium tin oxide (ITO) coated glass substrate by sol-gel spin coating technique using different additives namely polyethylene glycol and ethylene glycol. It was found that the organic additives added had an important influenced on the formation mechanism of Cu2O films and lead to different microstructures and optical properties. The films were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and ultraviolet-visible spectroscopy (UV-Vis). Based on the FESEM micrographs the grain size of film prepared by polyethylene glycol has smaller grain of about 83 nm with irregular shape. The highest optical absorbance film was obtained by the addition of polyethylene glycol which improved optical properties due to fine crystalline grain and thus decreases the scattering. The prepared cuprous oxide thin films were used as working electrodes for photovoltaic cell of ITO/Cu2O/PVC-LiClO4/graphite and tested using current-voltage characteristic under light illumination and also in the dark.

2015 ◽  
Vol 754-755 ◽  
pp. 1141-1145 ◽  
Author(s):  
Dewi Suriyani Che Halin ◽  
Khairel Rafezi Ahmad ◽  
Kamarudin Hussin ◽  
I.A. Talib ◽  
Abdul Razak Daud ◽  
...  

Cuprous oxide (Cu2O) thin films were formed onto indium tin oxide (ITO) coated glass substrate by sol-gel spin coating technique using different additives namely polyethylene glycol and ethylene glycol. It was found that the organic additives added had an important influenced on the formation mechanism of Cu2O films and lead to different microstructures and optical properties. The films were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and ultraviolet-visible spectroscopy (UV-Vis). Based on the FESEM micrographs the grain size of film prepared by polyethylene glycol has smallest grain of about 83 nm with irregular shape. The highest optical absorbance film was obtained by the addition of polyethylene glycol.


2015 ◽  
Vol 159 ◽  
pp. 325-332 ◽  
Author(s):  
Artak Karapetyan ◽  
Anna Reymers ◽  
Suzanne Giorgio ◽  
Carole Fauquet ◽  
Laszlo Sajti ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
D. S. C. Halin ◽  
I. A. Talib ◽  
A. R. Daud ◽  
M. A. A. Hamid

Cuprous oxide (Cu2O) thin films were deposited onto indium tin oxide (ITO) coated glass substrate by sol-gel spin coating technique using different additives, namely, polyethylene glycol and ethylene glycol. It was found that the organic additives added had a significant influence on the formation of Cu2O films and lead to different microstructures and optical properties. The films were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and ultraviolet-visible spectroscopy (UV-Vis). Based on the FESEM micrographs, the grain size of film prepared using polyethylene glycol additive has smaller grains of about 83 nm with irregular shapes. The highest optical absorbance film was obtained by the addition of polyethylene glycol. The Cu2O thin films were used as a working electrode in the application of photoelectrochemical solar cell (PESC).


2009 ◽  
Vol 156 (1) ◽  
pp. J6 ◽  
Author(s):  
Myung Soo Huh ◽  
Bong Seop Yang ◽  
Jaewon Song ◽  
Jaeyeong Heo ◽  
Seok-Jun Won ◽  
...  

2014 ◽  
Vol 34 (10) ◽  
pp. 1031003
Author(s):  
胡慧 Hu Hui ◽  
张丽平 Zhang Liping ◽  
孟凡英 Meng Fanying ◽  
刘正新 Liu Zhengxin

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