Reinforcement of NR with ENR Modified RHA

2012 ◽  
Vol 581-582 ◽  
pp. 663-667
Author(s):  
Zong Qiang Zeng ◽  
Hong Chao Liu ◽  
He Ping Yu
Keyword(s):  
Thermal Stability ◽  
Glass Transition ◽  
Transition Temperature ◽  
Natural Rubber ◽  
Rice Husk Ash ◽  
Dynamic Properties ◽  
Natural Rubber Latex ◽  
Morphological Structure ◽  
Rubber Latex ◽  
Tga Analysis

The rice husk ash (RHA) was first modified with epoxidized natural rubber latex (ENRL) and then blended with natural rubber latex (NRL) to prepare NR/RHA composite. The morphological structure, thermal stability and dynamic properties were studied with multiple instruments. FTIR and TGA analysis showed that ENR was grafted onto the surface of RHA. The composite prepared with modified RHA showed better dispersity and reinforcement compared to the composite with unmodified RHA, and the glass-transition temperature tended to be higher.

Thermal stability and mechanical properties of modified starch/NR composite

e-Polymers ◽  
2010 ◽  
Vol 10 (1) ◽  
Author(s):  
Zhi-Fen Wang ◽  
Si-Dong Li ◽  
Xin Fu ◽  
Hua Lin ◽  
Xiao-Dong She ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Natural Rubber ◽  
Permanent Deformation ◽  
Natural Rubber Latex ◽  
Modified Starch ◽  
Rubber Latex ◽  
Rubber Composite ◽  
Reaction Activation Energy ◽  
Thermal Stability Of

AbstractThe starch/natural rubber composite was prepared by blending the modified starch by esterification with natural rubber latex. The modified starch particles are homogenously distributed throughout the natural rubber (NR) matrix. In comparison with the host NR, the thermal stability of composite is significantly improved. The thermal degradation temperatures (T) and reaction activation energy (E) of composite are higher than those of the pure NR. The hardness, stress at 500%, tensile strength, permanent deformation and tear strength of composite increase linearly with the increment of dosage of modified starch.

HAF/SILICA/NANOCLAY “TERNARY” MASTERBATCH AND HAF/SILICA BINARY MASTERBATCH FROM FRESH NATURAL RUBBER LATEX

2014 ◽  
Vol 87 (2) ◽  
pp. 250-263 ◽  
Author(s):  
Sasidharan Krishnan ◽  
Rosamma Alex ◽  
Thomas Kurian
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Black ◽  
Natural Rubber ◽  
Abrasion Resistance ◽  
Dynamic Properties ◽  
Natural Rubber Latex ◽  
Rubber Latex ◽  
X Ray ◽  
Filler Dispersion

ABSTRACT A process for production of carbon black/silica/nanoclay ternary filler masterbatch from fresh natural rubber (NR) latex was standardized. The fillers, nanoclay, carbon black, and silica were incorporated in fresh NR latex by a modified coagulation process. The latex, mixed with filler dispersions, coagulated immediately on addition of acids. The coagulum containing fillers was dried at 70 °C in an air oven to get the latex filler masterbatch, which was further processed in the conventional way. The masterbatch compounds containing only silica/carbon black showed a higher level of vulcanization as compared with the corresponding dry mixes. The mechanical properties, such as tensile strength, modulus, tear strength, abrasion resistance, and hardness, increased with the proportion of nanoclay in the mixes up to 5 phr, and with a greater amount, the change was only marginal. Lower tan delta values were observed for all of the masterbatches containing nanoclay in the ranges of 3 to 10 phr compared with the control dry mix containing 25/25 carbon black/silica. The improvement in mechanical properties and dynamic properties shown by the masterbatches over the conventional mill-mixed compounds was attributed to factors related to filler dispersion, as evidenced from the data from dispersion analyzer images, X-ray diffractograms, and a higher level of vulcanization.

Study on Properties of Modified Porous Starch/ Natural Rubber Composite

2014 ◽  
Vol 941-944 ◽  
pp. 294-300 ◽  
Author(s):  
Xue Mei Pan ◽  
Min Wu ◽  
Si Dong Li ◽  
Lin Fang ◽  
Zhi Feng Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Natural Rubber ◽  
Water Resistance ◽  
Natural Rubber Latex ◽  
Swelling Behavior ◽  
Modified Starch ◽  
Rubber Latex ◽  
Solvent Resistance ◽  
Rubber Composite

The porous starch was modified by xanthates, and the starch/natural rubber composite was prepared by blending the modified starch with natural rubber latex. The morphology, thermal stability, swelling behavior and mechanical properties of the composite were investigated. Morphology studies by SEM showed that the modified porous starch were homogeneously dispersed in NR matrix. The composite has higher solvent resistance and lower water resistance after adding modified porous starch. The mechanical properties of composite are improved significanly with the increase of modified porous starch.

Effect of Grafting Conditions on NR-s-g-HFMA Copolymer and its Thermal Stability

2015 ◽  
Vol 1094 ◽  
pp. 91-95
Author(s):  
Fu Chun Zhao ◽  
Shuang Quan Liao ◽  
Chun Ping Wu
Keyword(s):  
Thermal Stability ◽  
Natural Rubber ◽  
Natural Rubber Latex ◽  
Low Grade ◽  
Solution Polymerization ◽  
Rubber Latex ◽  
Grafted Copolymer ◽  
Grafting Ratio ◽  
Polymerization Method ◽  
Comprehensive Property

<p>Skim natural rubber (NR-s) is solidified by skim natural rubber latex. NR-s is often evaluated to low grade natural rubber because of its many bad properties such as poor resistance to aging. In order to improve the NR-s comprehensive property, fluorinated groups were incorporated into NR-s molecular chain by grafting via solution polymerization method. The grafted copolymer was characterized and the effects of conditions on grafting ratio and grafting efficiency were investigated. The thermal stability are also examined.</p>

Physical and Mechanical Properties of Cement/Natural Rubber Latex/Rice Husk Ash Composites

2015 ◽  
Vol 804 ◽  
pp. 124-128
Author(s):  
Nittaya Jaitanong ◽  
Tanapong Chaipunti
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Natural Rubber ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Natural Rubber Latex ◽  
Physical And Mechanical Properties ◽  
Ammonia Solution ◽  
Rubber Latex ◽  
Cement Ratio

The microstructure and mechanical properties of Portland cement (PC)- natural rubber latex (NRL)- rice husk ash (RHA) composites have been investigated. The proportions of PC-NRL-RHA composites with NRL to cement ratio (NRL/C) that use in this experiment were 0, 0.10, 0.15 and 0.20 respectively. Portland cement (PC) was partially replaced with rice husk ash at 20% by weight of binder. The rice husk ash (RHA) was ground for 180 minutes before using. Water to cement ratio (W/C) equal of 0.5 by weight not include water in NRL. Nonionic surfactant was added in cement before mixed with NRL. In addition, to provide latex from natural rubber, the ammonia solution is added into natural rubber. The specimens were casting in standard mold which samples size of 50x50x50 and 40x40x160 mm3 respectively. Moreover, the PC-NRL-RHA composites were cured in water for 3, 7 and 28 days at room temperature before measurement. Then, mechanical properties (compressive strength and flexural strength) and microstructure were studied.

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