Preparation and Corrosion Resistance of Cu-Based Bulk Glassy Alloys

2013 ◽  
Vol 652-654 ◽  
pp. 1143-1148
Author(s):  
Peng Jun Cao ◽  
Ji Ling Dong ◽  
Hai Dong Wu ◽  
Pei Geng Fan
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Glassy Alloy ◽  
Maximum Diameter ◽  
Nacl Solution ◽  
Corrosion Condition ◽  
Glassy Alloys ◽  
Weight Method ◽  
Bulk Glassy Alloy ◽  
Better Than

The Cu-based bulk glassy alloys in Cu-Zr-Ti-Ni systems were prepared by means of copper mold casting. The structure and corrosion resistance of Cu-based bulk glassy alloys were analyzed by X-ray diffraction (XRD), differential scanning calorimetry (DSC), electrochemistry method, lost weight method. The result indicates the supercooled liquid temperature interval (ΔTx) is up to 70.98 K for Cu50Zr25Ti15Ni10bulk glassy alloy. The maximum diameter was up to 5.0 mm for the Cu55Zr25Ti15Ni5bulk glassy alloy. For electrochemistry corrosion in 3.5% NaCl solution, self-corrosion electric current density of the Cu50Zr25Ti15Ni10bulk glassy alloys is obviously lower than that of stainless steel and brass, so corrosion resistance of Cu-based bulk glassy alloys is better than stainless steel and brass at the same corrosion condition. The lost weight method showed that the corrosion rate of brass, stainless steel and glassy alloy is respectively 10.08 g/(m2•h), 6.08 g/(m2•h) and 2.19 g/(m2•h) in the 3% NaCl solution, which also indicates that the corrosion resistance of Cu-based bulk glassy alloys is better than stainless steel and brass. The Cu-based bulk glassy alloys can be used in the special field demanding to have the super high strength, hardness and corrosion resistance.

scholarly journals Formation and mechanical properties of Cu–Hf–Ti bulk glassy alloys [Article Retracted]

2001 ◽  
Vol 16 (10) ◽  
pp. 2836-2844 ◽  
Author(s):  
Akihisa Inoue ◽  
Wei Zhang ◽  
Tao Zhang ◽  
Kei Kurosaka
Keyword(s):  
Fracture Strength ◽  
Glassy Alloy ◽  
Supercooled Liquid Region ◽  
Maximum Diameter ◽  
Tensile Fracture ◽  
Liquid Region ◽  
High Fracture ◽  
Glassy Alloys ◽  
Plastic Elongation ◽  
Bulk Glassy Alloy

High-strength Cu-based bulk glassy alloys were formed in the Cu–Hf–Ti system by the copper mold casting and melt clamp forging methods. The maximum diameter is 4 mm for the Cu60Hf25Ti15 alloy. The substitution of Hf in the Cu60Hf40 alloy by Ti causes an increase in the glass-forming ability (GFA). As the Ti content increases, the glass transition temperature (Tg) decreases, while the crystallization temperature (Tx) shows a maximum at 5% Ti and then decreases, resulting in a maximum supercooled liquid region ΔTx (= Tx − Tg) of 78 K at 5% Ti. The liquidus temperature (T1) has a minimum of 1172 K around 20% Ti, and hence, a maximum Tg//T1 of 0.62 is obtained at 20% Ti. The high GFA was obtained at the compositions with high Tg/T1. The bulk glassy alloy exhibits tensile fracture strength of 2130 MPa, compressive fracture strength of 2160 MPa, and compressive plastic elongation of 0.8 to 1.6%. The new Cu-based bulk glassy alloys with high Tg/T1 above 0.60, high fracture strength above 2100 MPa, and distinct plastic elongation are encouraging for future development as a new type of bulk glassy alloy that can be used for structural materials.

CRUCIBLE CPM S30V

Alloy Digest ◽  
2003 ◽  
Vol 52 (9) ◽  
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Wear Resistance ◽  
Corrosion Resistance ◽  
Physical Properties ◽  
Martensitic Stainless Steel ◽  
Heat Treating ◽  
Corrosion And Wear ◽  
Better Than

Abstract Crucible CPM S30V is a martensitic stainless steel designed with a combination of toughness, wear resistance, and corrosion resistance equal to or better than 440C. This datasheet provides information on composition, physical properties, microstructure, hardness, and elasticity as well as fracture toughness. It also includes information on corrosion and wear resistance as well as heat treating and machining. Filing Code: SS-891. Producer or source: Crucible Service Centers.

URANUS 52N

Alloy Digest ◽  
1994 ◽  
Vol 43 (5) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Flue Gas ◽  
Crevice Corrosion ◽  
Heat Treating ◽  
Flue Gas Desulfurization ◽  
Temperature Performance ◽  
Aisi Type ◽  
Better Than

Abstract URANUS 52N is a nitrogen-alloyed duplex stainless steel improved in stress-corrosion cracking resistance and with pitting and crevice corrosion resistance better than AISI Type 317L. Applications include handling phosphoric acid contaminated with chlorides and in flue gas desulfurization scrubbers. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-566. Producer or source: Creusot-Marrel.

Effect of Cr and Zr Addition on the Corrosion Behaviour of Copper in the Chloride Solution

2011 ◽  
Vol 194-196 ◽  
pp. 1253-1256
Author(s):  
Ya Ni Zhang ◽  
Mao Sheng Zheng ◽  
Jie Wu Zhu
Keyword(s):  
Corrosion Resistance ◽  
Chloride Solution ◽  
Corrosion Behaviour ◽  
Pure Copper ◽  
Base Material ◽  
Nacl Solution ◽  
Corrosion Performance ◽  
Zr Addition ◽  
Corrosion Scales ◽  
Better Than

The corrosion behavior of CuCr, CuZr and CuCrZr alloys in NaCl solution is reported in this paper. The corrosion performance has been evaluated in NaCl solution atmosphere. The results show the corrosion resistance of pure copper decrease with the addition of the alloying elements initially. However, in the later exposure stages, the corrosion resistance of CuZr and CuCrZr alloy deteriorates significantly while the corrosion resistance of CuCr alloy is slightly better than that of pure copper. In addition, the results of the electrochemical experiments indicate that the different behavior for the element Cr and Zr in the base material and corrosion scales lead to the change of the corrosion resistance.

Enhancement of plasticity in Ti-rich Ti–Zr–Be–Cu–Ni–Ta bulk glassy alloy via introducing the structural inhomogeneity

2008 ◽  
Vol 23 (11) ◽  
pp. 2984-2989 ◽  
Author(s):  
Jin Man Park ◽  
Do Hyang Kim ◽  
Ki Buem Kim ◽  
Eric Fleury ◽  
Min Ha Lee ◽  
...  
Keyword(s):  
Glassy Alloy ◽  
Shear Bands ◽  
Structural Inhomogeneity ◽  
Glassy Matrix ◽  
Premature Failure ◽  
Glassy Alloys ◽  
Alloy Chemistry ◽  
Bulk Glassy Alloy ◽  
Heterogeneous Microstructures ◽  
Micrometer Scale

The effect of microstructural inhomogeneities with different length scale on the plasticity of (Ti45Zr16Be20Cu10Ni9)100–xTax (x = 0, 5, and 10) bulk glassy alloys has been studied. The formation of specific heterogeneous microstructures with a different type of structural inhomogeneity, i.e., short-/medium-range ordered clusters or micrometer-scale ductile dendrites combined with a glassy matrix, evolved by appropriately tuning the alloy chemistry, improves the room temperature plasticity up to ∼12.5% and ∼15%, respectively. The pronouncedly enhanced plasticity is mainly attributed to the retardation of shear localization and multiplication of shear bands by controlling the plastic and failure instabilities otherwise responsible for premature failure.

scholarly journals Effects of NiSO4 Concentration on the Coloring Performance and Corrosion Resistance of the Colored Film on 304 Stainless Steel

Coatings ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 598
Author(s):  
Wenwei Li ◽  
Jun-e Qu ◽  
Zhiyong Cao ◽  
Hairen Wang
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Negative Impact ◽  
304 Stainless Steel ◽  
Nacl Solution ◽  
Time Curve ◽  
Steel Surfaces

The colored films were successfully prepared on the 304 stainless steel surfaces in coloring solutions with different NiSO4 contents. The purpose of this study was to investigate the effects of NiSO4 in the coloring solution on the coloring performance of 304 stainless steel and corrosion resistance of the obtained colored film in NaCl solution. The coloring rate was determined from coloring potential-time curve, and the protection properties of the color films in a 3.5% NaCl solution were characterized by potentiodynamic polarization scan, electrochemical impedance spectroscopy, and wear resistance test. The results showed that adding NiSO4 could accelerate the coloring process but brought about a negative impact on the surface’s corrosion resistance.

scholarly journals Properties of a Plasma-Nitrided Coating and a CrNx Coating on the Stainless Steel Bipolar Plate of PEMFC

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 183 ◽  
Author(s):  
Meiling Xu ◽  
Shumei Kang ◽  
Jinlin Lu ◽  
Xinyong Yan ◽  
Tingting Chen ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
316L Stainless Steel ◽  
High Efficiency ◽  
Electrochemical Impedance ◽  
Bipolar Plate ◽  
Working Environment ◽  
Stainless Steel Surface ◽  
Bipolar Plates ◽  
Better Than

PEMFC are considered to be the most promising for automotive energy because of their good working effect, low temperature, high efficiency, and zero pollution. Stainless steel as a PEMFC bipolar plate has unparalleled advantages in strength, cost, and processability, but it is easy to corrode in a PEMFC working environment. In order to improve the corrosion resistance, the surface modification of 316L stainless steel is a feasible solution for PEMFC bipolar plates. In the present study, the plasma-nitrided coating and CrNx coating were prepared by the plasma-enhanced balanced magnetron sputtering technology on the 316L stainless steel surface. The microstructures, phase compositions, and corrosion resistance behavior of the coatings were investigated. The corrosion behavior of the prepared plasma-nitrided coating and CrNx coating was investigated by potentiodynamic polarization, potentiostatic polarization, and electrochemical impedance spectroscopy (EIS) in both cathodic and anodic environments. The experimental results show that corrosion resistance of the CrNx coating was better than the plasma-nitrided coating. It was indicated that the technology process of nitriding first and then depositing Cr was better than nitriding only.

Application Performance of Super Ferrite Stainless Steel on Condenser in Power Plant

2014 ◽  
Vol 651-653 ◽  
pp. 3-6
Author(s):  
Xiao Rui Guan ◽  
Da Lei Zhang ◽  
You Hai Jin
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Power Plant ◽  
Mechanical Test ◽  
Cooling Water ◽  
Electrochemical Test ◽  
Application Performance ◽  
Shock Resistance ◽  
Rate Of Cooling ◽  
Better Than

The application performances of TA2 titanium\S44660 super ferrite stainless steel\B30 cupronickel, which are widely used in power plant, were researched using electrochemical test and mechanical test. The results show that corrosion resistance of B30 is significantly lower than TA2 and S44660. Besides, corrosion resistance of S44660 is superior to TA2. Yield strength and tensile strength of S44660 is higher than TA2 and B30. When considering thickness of cooling tubes, flow rate of cooling water and clean coefficient, the thermal conductivity of three materials have little differences. The shock resistance of S44660 is better than TA2 and B30. S44660 contains a small amount of Ni, which improves greatly the anti-cracking ability of the base metal and welding bead.

Effect of Ni addition on corrosion resistance of FePC bulk glassy alloy

2014 ◽  
Vol 50 (6) ◽  
pp. 433-437 ◽  
Author(s):  
X. H. Ma ◽  
L. Zhang ◽  
X. H. Yang ◽  
Q. Li ◽  
Y. D. Huang
Keyword(s):  
Corrosion Resistance ◽  
Glassy Alloy ◽  
Ni Addition ◽  
Bulk Glassy Alloy

scholarly journals (Fe,Co,Ni)–B–Si–Nb Bulk Glassy Alloy With Super-High Strength and Some Ductility [Article Retracted]

2005 ◽  
Vol 20 (1) ◽  
pp. 1-5 ◽  
Author(s):  
Baolong Shen ◽  
Akihisa Inoue
Keyword(s):  
Plastic Strain ◽  
Glassy Alloy ◽  
Functional Materials ◽  
High Strength ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
Glassy Alloys ◽  
Strength Alloy ◽  
Bulk Glassy Alloy

Glassy [(Fe0.8Co0.1Ni0.1)0.75B0.2Si0.05]96Nb4 alloy rods with glass transition temperature of 835 K, followed by a large supercooled liquid region of 55 K were produced in the diameter range up to 2 mm by copper mold casting. The glassy alloy rods exhibit super-high true fracture strength of 4225 MPa combined with elastic strain of 0.02 and true plastic strain of 0.005. The super-high strength alloy simultaneously exhibits high magnetization of 1.1 T, low coercivity of 3 A/m, and high permeability of 1.8 × 104 at 1 kHz. The success of synthesizing a super-high strength Fe-based bulk glassy alloy with some compressive plastic strain and good soft magnetic properties is encouraging for future development of Fe-based bulk glassy alloys as new engineering and functional materials.

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