Microbial healing of nature-like rough sandstone fractures for rock weathering mitigation

Rock weathering fractures in nature are complex and fracture healing is an effective strategy for rock weathering mitigation. This study is a first attempt to apply microbially induced calcium carbonate precipitation (MICP) technology in the healing of nature-weathering-like rough fractures (NWLRF). Sandstone was studied as an example due to it is a wide-spread construction, sculpture and monuments material all over the world. In order to achieve a high healing efficiency, a repeated mixture injection strategy was proposed. Based on a series of laboratory MICP injection experiments on four types of NWLRF, we systematically explored the fundamental micro-healing mechanism and the influence of factors including fracture aperture, characteristics of branch fractures, and cementation solution concentration. Experimental results demonstrated that MICP healing with the repeated mixture injection strategy had the ability to efficiently heal the penetrated NWLRF well with length in centimeter-scale and aperture in millimeter-scale, but cannot heal the non-penetrated branch fractures under low injection pressure. The repeated mixture injection strategy furtherly achieved a high apparent fracture healing ratio and a significant reduction of transmissivity. The apparent fracture healing ratios of all main fractures were higher than 80% and the maximum was 99.1%. Fracture transmissivity was reduced by at least three orders of magnitude from about 1×10-4 m2/s to less than 1×10-7 m2/s, and the highest reduction reached to four orders. For the aspect of the effects, larger cementation solution concentration, finer aperture and the existing of penetrated branch fracture were beneficial to improve the healing effect. Moreover, the MICP healing mechanism with high fracture healing ratio and significant reduction of transmissivity on sandstone NWLRF was also analyzed. The research results have important theoretical significance and technical guidance value for the disaster prevention and mitigation of rock weathering.

Machining of Poly Methyl Methacrylate (PMMA) and Other Olymeric Materials

Polymers have been adopted industrially in the manufacture of lenses for optical applications due to their attractive properties such as high hardness, high strength, high ductility, high fracture toughness, and also their low thermal and electrical conductivities. However, they have limited machinability and are therefore classified as hard-to-machine materials. This study conducts a critical review on the machining of various polymers and polymeric materials, with particular focus on poly (methyl methacrylate) (PMMA). From the review it was concluded that various machining parameters affect the output qualities of polymers and which include the spindle speed, the feed rate, vibrations, the depth of cut, and the machining environment. These parameters tend to affect the surface roughness, the cutting forces, delamination, cutting temperatures, tool wear, precision, vibrations, material removal rate, and the mechanical properties such as hardness, among others. A multi-objective optimization of these machining parameters is therefore required, especially in the machining of PMMA.

Different Thermal Treatment Methods and TGase Addition Affect Gel Quality and Flavour Characteristics of Decapterus maruadsi Surimi Products

Decapterus maruadsi surimi products were prepared using the thermal treatment methods of boiling (BOI), steaming (STE), back-pressure sterilization (BAC), roasting (ROA), microwaving (MIC), and frying (FRI), respectively. The effect of glutamine transaminase (TGase) addition was also investigated. The moisture distribution, water retention, microstructure, color, fracture constant, protein secondary structure, chemical forces, and flavor components of each sample were determined. The differences in gel and favor characteristics between D. maruadsi surimi products caused by thermal treatment methods were analyzed. The results showed that BOI, STE, and FRI had the largest protein secondary structure transitions and formed dense gel structures with high fracture constant. The kinds of flavour components in BOI and STE were completer and more balanced. The high temperature treatment available at BAC and FRI (110 °C and 150 °C) accelerated the chemical reaction involved in flavor formation, which highlighted the flavor profiles dominated by furans or esters. The open thermal treatment environments of ROA, MIC, and FRI gave them a low moisture content and water loss. This allowed the MIC to underheat during the heat treatment, which formed a loose gel structure with a low fracture coefficient. The addition of TGase enhances the gel quality, most noticeably in the ROA. The aldehyde content of the FRI was enhanced in the flavor characteristic. The effect of adding TGase to enhance the quality of the gel is most evident in ROA. It also substantially increased the content of aldehydes in FRI. In conclusion, different heat treatments could change the gel characteristics of surimi products and provide different flavor profiles. The gel quality of BOI and STE was consistently better in all aspects.

Effects of Transient Thermal Shock on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy Coatings

CoCrFeNiMn high-entropy alloy (HEA) has great potential for engineering application due to its good ductility and high fracture toughness at low temperature. It can be deposited on components as coatings to take advantage of its excellent properties and reduce the cost. In this study, CoCrFeNiMn HEA coatings were deposited on 316L stainless steel substrates by atmospheric plasma spraying (APS) technique, and a series of transient thermal shock tests were performed. It was found that the coatings contained two main phases: a face-centered cubic (FCC) solid solution phase and a flocculent oxides phase. The elemental contents of Co, Cr, Fe, and Ni were close to equal atomic percentage in the coating, while Mn was reduced significantly. The oxygen was mainly distributed in the dark flocculent oxides phase. After transient thermal shock tests, these two phases remained stable, but some tiny cracks appeared on the surface. Meanwhile, the microhardness of the coating after transient thermal shock tests also showed stable, ∼ 420 HV. Weibull statistics were used to analyze the reliability of the microhardness, and the Weibull modulus m was distributed from 9 to 15. The CoCrFeNiMn HEA coating exhibited high phase stability and excellent properties under transient thermal shock, making it have service advantages in extreme environments, especially in the fields of the development of future nuclear and aerospace structural materials.

Fracture Toughness Characteristics of High-Manganese Austenitic Steel Plate for Application in a Liquefied Natural Gas Carrier

High-manganese austenitic steel was developed to improve the fracture toughness and safety of steel under cryogenic temperatures, and its austenite structure was formed by increasing the Mn content. The developed high-manganese austenitic steel was alloyed with austenite-stabilizing elements (e.g., C, Mn, and Ni) to increase cryogenic toughness. It was demonstrated that 30 mm thickness high-manganese austenitic steel, as well as joints welded with this steel, had a sufficiently higher fracture toughness than the required toughness values evaluated under the postulated stress conditions. High-manganese austenitic steel can be applied to large offshore and onshore LNG storage and fuel tanks located in areas experiencing cryogenic conditions. Generally, fracture toughness decreases at lower temperatures; therefore, cryogenic steel requires high fracture toughness to prevent unstable fractures. Brittle fracture initiation and arrest tests were performed using 30 mm thickness high-manganese austenitic steel and SAW joints. The ductile fracture resistance of the weld joints (weld metal, fusion line, fusion line + 2 mm) was investigated using the R-curve because a crack in the weld joint tends to deviate into the weld metal in the case of undermatched joints. The developed high-manganese austenitic steel showed little possibility of brittle fracture and a remarkably unstable ductile fracture toughness.

The Fabrication and Mechanical Properties of Laminated ZrB2-Mo5SiB2 Ceramics with an Mo-Mo5SiB2 Interlayer

The excellent physical and chemical properties of ultra-high temperature ceramics make them suitable for many high-temperature structural components, while their poor toughness and high sintering temperature become key limitations to their application. Laminated toughening has long been considered an effective toughening method to improve the mechanical properties of ceramics. In this study, laminated ZrB2-Mo5SiB2 ceramics with an Mo-Mo5SiB2 interlayer were fabricated by tape casting and hot press sintering at 1900 °C for 2 h. Different layer thickness ratios between the matrix layer and the interlayer were designed to illustrate the toughening mechanism. Both the fracture toughness and flexural strength of the laminated ceramics showed a trend of first increasing and then decreasing with the increase of the layer thickness ratio. High fracture toughness (9.89 ± 0.26 MPa·m1/2) and flexural strength (431.6 ± 15.1 MPa) were obtained when the layer thickness ratio was 13. The improvement in fracture toughness of the laminated ceramics could be attributed to the generation of the residual stress, the deflection and the bifurcation of the cracks. Residual stress that developed in the laminated ceramics was also evaluated.

Step Change in Delivering High Fracture Wells by Eliminating Expandable Liner

This paper discusses the journey of finding alternate solution for having to run the Expandable Liners operations in the Fahud field which is already one of the most operationally challenging fields to drill in Petroleum Development Oman (PDO), due to the presence of a gas cap in highly fractured and depleted limestone formations with total losses and the need for dynamic annulus fill to maintain primary well control. In Fahud field, there is a highly reactive shale formation within reservoir limestone formation. Due to high likelihood of total losses, this shale formation caused bore hole instability challenges while drilling. And with more depletion took place, the challenges became more frequently to occurred. In 2001, expandable tubular liner was introduced to address these bore hole instability challenges while drilling highly reactive shale formation under total losses in the 8-1/2″ section. The use of expandable technology was sustained over the years in delivering all wells drilled to traverse this reactive shale column. Previously before 2001, wells used to have fat well design by installations of extra casing to cover the formations and problematic zones. Also, Fahud field was not depleted as it is now, and the problematic shale zone used to drill by normal conventional way without any issue using inhibition frilling fluid. Petroleum Development Oman (PDO) identified expandable liner as a preferred alternative to ‘Fat’ well design. The ‘Fat’ well design would have a large hole size through potential loss zones, resulting in unmanageable volumes of water being required. Expandable liber was fast-tracked - various technical options were considered by PDO with expandable liner technology being identified as the best solution to address the problem of the shale column. However, the deployment of expandable tubular liner technology supported to drill & deliver wells but also has its associated challenges incurring additional time and cost with reasonable installation and low operations success rate due to number of operational steps required prior and after the expandable liner. Adding to that, all the challenges associated with each step. The installation of the expandable liner required eight operational steps with multiple trips to under-ream, install and expand, cement, caliper log and drill through the liner which increased the probability of something going wrong due to mainly the challenging well profile and multiple operations steps. The expandable liners technology was required when the target formation was below the reactive shale interval. The team carried out a study of previous deployments with the intention of identifying well planning and operational contributors to the installation difficulties and operations failures, with a view of eliminating the need for installing the expandable liner and drilling the well to the desired landing point at designed section total depth. Most of the unsuccessful installation rates were observed to be prevalent in wells with high angle applications. The team also observed that the length of the hole interval below the reactive shale column contributed to the number of unsuccessful installation and operational failure rates recorded. The team evaluated the impact of reducing well inclination on the ability to deliver the hole section without installing the expandable liner. Subsequently the team developed an optimization plan which involved keeping all build activities above and below the problematic interval and holding tangent at less than 45° inclination while drilling across the problematic shale. In conclusion, in 2020 the team delivered six wells (90% of wells crossing reactive shale formation delivered) using the above described approach and traversed the historically highly reactive shale formation without installing expandable liners. This resulted in a 20% reduction in total well construction time and 17% reduction in total well delivery cost per well. In addition to the time and cost saving, with the new approach, described in this paper, less water needed to be pumped for dynamic fill. This allowed bringing the wells quicker to production, thus reducing oil deferment.