The Technical Study on Photo-Catalytic Oxidation Treatment of Low Concentration Methanol Wastewater in Gas Field

2013 ◽  
Vol 671-674 ◽  
pp. 2769-2772 ◽  
Author(s):  
Min Zhao ◽  
Ji Hui Jiang ◽  
Li Hui Zhou ◽  
Peng Kang Jin ◽  
Dong He

Though analysis and determination on wastewater quality of Gas Field, it can be seen that the main organic matter in wastewater is low concentration methanol. Aiming at the characteristics of higher degree of mineralization, methanol and lower pH ,the experiment is focusing on the effect of manganese dioxide & hydrogen peroxide catalytic oxidation process on methanol wastewater treatment properties and functions.The results show, for low concentration methanol wastewater,the manganese dioxide used has a diameter of 5nm with a dosage of 300mg/L, also a illumination intensity of 120Q, when the dosing ratio with hydrogen peroxide is 1:10, after 8h reaction period, the degradation rate of methanol were all above 70.0%.The methanol content after treated can meet the reference standard for Gas Field reinjection water

2011 ◽  
Vol 233-235 ◽  
pp. 1684-1689 ◽  
Author(s):  
Heng Shen Xie ◽  
Zhi Min Zong ◽  
Qing Wei ◽  
Pei Zhi Zhao ◽  
Jian Jun Zhao ◽  
...  

Shenfu bituminous coal (SFBC) and Xilinhaote lignite (XL) were subject to photo-catalytic oxidation with hydrogen peroxide over titanium dioxide. The reaction mixtures were extracted with acetone exhaustively. The extracts were analyzed with FTIR and GC/MS. The results show that coals be oxidized selectively and degraded partially. Compared with the bituminite coal, the oxidation effect of the lignite coal with active hydrogens is more obvious. The alkyl side chains of the macromolecules, particularly, chains of methyl, methylene and aromatic, are the most vulnerable in relation to other compounds in coals. Moreover, the increasing of straight-chain alkanes and the decreasing of condensed nucleus in SFBC and XL through oxidation suggest that the oxidation is an effective method of coal utilization with no difficultly, also be friendly towards the environment after treated as well as in the process of the treatment.


2014 ◽  
Vol 887-888 ◽  
pp. 766-769 ◽  
Author(s):  
Huey Ling Chang ◽  
Chih Ming Chen ◽  
Chin Huang Sun ◽  
Jin Shyong Lin

This study produced a regularly arranged membrane, called anodic aluminum oxide (referred AAO), by mean of anodic oxidation treatment. The structure of AAO can be molecular self-assembly and its pore size is consistent. Also, the manufacturing process cost is low. These properties make the AAO be a nanotemplate material. This study further created a high quality of nanostructured film by electrochemical mould with the design of electrolyzer. In addition, a uniform nanothin film was grown on the aluminum surface in the stable control of current and temperature according to the conditions of different anode treatment. This film can form a nanopore array which the diameter can be controlled the size ranging from 15 nm to 400 nm. As results, the study can produce nanoporous template for various aperture by mean of anodic oxidation.


1923 ◽  
Vol 45 (12) ◽  
pp. 2841-2851 ◽  
Author(s):  
W. A. Whitesell ◽  
J. C. W. Frazer

2009 ◽  
Vol 610-613 ◽  
pp. 161-164
Author(s):  
Li Li Liang ◽  
Xue Gang Luo ◽  
Xiao Yan Lin

A ferric stearate electrode was made by doctor-blade methods using the Fluorine tin oxide (FTO) conductive glass. The electrochemical behavior of ferric stearate electrode was studied by the cyclic voltammetry. The electro-catalytic effects of ferric stearate on H2O2 were also investigated by cyclic voltammetry.


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