Determination of Organochlorine Pesticides in Water Samples through Hollow Fiber Membrane-Liquid Phase Microextraction Using Ionic Liquid Material as Extractant

2013 ◽  
Vol 675 ◽  
pp. 260-263 ◽  
Author(s):  
Du Shu Huang ◽  
Ya Shun Chen ◽  
He Ping Yan ◽  
Na Wu ◽  
Wei Liu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Organochlorine Pesticides ◽  
Hollow Fiber ◽  
Water Samples ◽  
Hollow Fiber Membrane ◽  
Fiber Membrane ◽  
Liquid Phase Microextraction ◽  
Liquid Material

A novel method for determination of organochlorine pesticides residuals (2,4-DDT and 4,4-DDT) in water samples through hollow fiber membrane-liquid phase microextraction using ionic liquid material as extractant coupled with high performance liquid chromatography has been developed. The effect of extraction parameters including pH of the feed solution, stirring rate and extraction time was investigated. The proposed method provided enrichment efficiency of 323 and 289 for 2,4-DDT and 4,4-DDT respectively. The method had good linear range of 0.5-50 μg /L and the limits of detection of the pesticides were 0.1 μg /L.

Determination of Organochlorine Pesticides by Headspace Liquid Phase Microextraction Using Ionic Liquid Material

2013 ◽  
Vol 675 ◽  
pp. 256-259
Author(s):  
Du Shu Huang ◽  
Ping Yi ◽  
Yun Hui Long ◽  
Yan Jiang ◽  
Qing Shan Pan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Phase ◽  
Organochlorine Pesticides ◽  
Room Temperature ◽  
Salt Content ◽  
Sample Volume ◽  
Liquid Phase Microextraction ◽  
Operation Temperature ◽  
Liquid Material

Headspace liquid-phase microextraction with room temperature ionic liquid material, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM][PF6]) as extractant for the determination of organochlorine pesticides including 2,4 '-DDT and 4,4'-DDT from water were investigated in this study. The factors such as salt content, sample pH, operation temperature, stirring rate, extraction time, microdrop volume, and sample volume were found to have significant influence on this process. Results show that the satisfactory extraction conditions were as follows: 30% NaCl (w/v), 800 rpm, 30 min, 60 °C, and 10μL ionic liquid.

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