Photoelectrode with Multilayer of Gradual Scattering Structure Used in Dye-Sensitized Solar Cells

2013 ◽  
Vol 699 ◽  
pp. 22-27
Author(s):  
Xiao Peng ◽  
Bao Zhang ◽  
Shu Xian Meng ◽  
Xiang Mei Yu ◽  
Zhe Zeng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion ◽  
Emulsion Method ◽  
Dye Sensitized ◽  
Scattering Centers ◽  
Micro Emulsion ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

A multilayer TiO2 film featured with gradual scattering structure was developed and used as photoelectrode for dye-sensitized solar cells. This structure of film consists of P25 nanoparticles and TiO2 aggregate which was synthesized by micro-emulsion method as scattering centers The scattering centers were deposited by gradually increasing the amount from the film’s bottom to its top. The special films were used for the studies on the photovoltaic performance of N719 and Zn-3, and their photoelectric conversion efficiencies were 7.34% and 4.04%, respectively. Furthermore, more improvement of the conversion efficiency is realized for Zn-3 than for N719 by using our newly developed multilayer films as photoelectrode compared with ordinary photoelectrode.

scholarly journals Construction of NiMoS3/BC heterostructure photoanodes and optimization of light scattering to improve the photovoltaic performance of dye sensitized solar cells (DSSCs)

2021 ◽  
Author(s):  
T Sumathi ◽  
Sonia A Fredricka ◽  
G Deepa
Keyword(s):  
Solar Cells ◽  
Large Scale ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photocurrent Density ◽  
Electron Hole ◽  
Dye Sensitized ◽  
Electron Hole Pair ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Abstract In the last two decades, dye sensitized solar cells (DSSCs) have gotten a lot of attention from researchers and have progressed quickly. To promote commercialization and large-scale application of DSSCs, their efficiency should be increased. This paper details significant advancements in advanced NiMoS3/BC nanocomposites for improving photoanodes and DSSC conversion efficiencies. The fabricated electrode samples were characterized by XRD, SEM, TEM, Raman, UV, PL and BET to explore the structural, morphological and optical properties. A significant reduction band gap with enhanced light absorption and rapid prevention of electron hole pair was explored by UV-DRS and PL studies. The photocurrent density-voltage (J-V) and IPCE characteristics were analyzed for assembled solar cell. The NiMoS3/BC (NMSC5) nanocomposite DSSC showed a PCE of 8.85%, far higher than that of the NiMoS3 (2.45%) and a PCE value equivalent to Pt CE (4.79 %). The enhanced PCE of the proposed electrodes are also discussed in scientifically.

Effects of triphenyl phosphate as an inexpensive additive on the photovoltaic performance of dye-sensitized nanocrystalline TiO2 solar cells

RSC Advances ◽  
2015 ◽  
Vol 5 (62) ◽  
pp. 50483-50493 ◽  
Author(s):  
Malihe Afrooz ◽  
Hossein Dehghani
Keyword(s):  
Solar Cells ◽  
Conversion Efficiency ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Triphenyl Phosphate ◽  
Photoelectric Conversion ◽  
Nanocrystalline Tio2 ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

In this study, triphenyl phosphate (TPP) is applied as an effective and inexpensive additive in the dye sensitized solar cells (DSSCs) and an increase in the photoelectric conversion efficiency is obtained of almost 24%.

Accurate estimation of the photoelectric conversion efficiency of a series of anthracene-based organic dyes for dye-sensitized solar cells

2020 ◽  
Vol 8 (7) ◽  
pp. 2388-2399 ◽  
Author(s):  
Panpan Heng ◽  
Lemin Mao ◽  
Xugeng Guo ◽  
Li Wang ◽  
Jinglai Zhang
Keyword(s):  
Solar Cells ◽  
Optical Absorption ◽  
Organic Dyes ◽  
Dye Sensitized Solar Cells ◽  
Accurate Estimation ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Studies demonstrate that our designed dyes 3 and 4 exhibit broad optical absorption in the 550–650 nm region and high photoelectric conversion efficiencies of over 32%.

Phenothiazine-based dyes for efficient dye-sensitized solar cells

2016 ◽  
Vol 4 (13) ◽  
pp. 2404-2426 ◽  
Author(s):  
Zu-Sheng Huang ◽  
Herbert Meier ◽  
Derong Cao
Keyword(s):  
Molecular Structure ◽  
Solar Cells ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Scientific Progress ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
The Relationship ◽  
Sensitized Solar Cells

Due to their structure features, 10H-phenothiazine-based dyes show high photovoltaic performance and have great potential for future technical applications in dye-sensitized solar cells (DSSCs). The recent significant scientific progress of the dyes and their DSSCs is reviewed, and the relationship between the molecular structure and the photoelectric conversion properties is especially discussed.

scholarly journals Computational Prediction of Electronic and Photovoltaic Properties of Anthracene-Based Organic Dyes for Dye-Sensitized Solar Cells

2018 ◽  
Vol 2018 ◽  
pp. 1-17 ◽  
Author(s):  
Hongbo Wang ◽  
Qian Liu ◽  
Dejiang Liu ◽  
Runzhou Su ◽  
Jinglin Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Density Functional ◽  
Organic Dyes ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Photoelectric Properties ◽  
Sensitized Solar Cells

Three kinds of anthracene-based organic dyes for dye-sensitized solar cells (DSSCs) were studied, and their structures are based on a push–pull framework with anthracenyl diphenylamine as the donor connected to a carboxyphenyl or carboxyphenyl-bromothiazole (BTZ) as the acceptor via an acetylene bridge. The photoelectric properties of the three dyes were investigated using density functional theory (DFT). The simulations indicate that the improvement of anthracene-based dyes (the addition of BTZ and the change of alkyl groups to alkoxy chains) can reduce the energy gap and produce a red shift. This structural modification also improves the light capturing and the electron injection capability, making it excellent in photoelectric conversion efficiency (PCE). In addition, twelve molecules have been designed to regulate photovoltaic performance.

A new type of multibenzyloxy-wrapped porphyrin sensitizers for developing efficient dye-sensitized solar cells

2020 ◽  
Vol 24 (01n03) ◽  
pp. 401-409
Author(s):  
Yingying Chen ◽  
Kaiwen Zeng ◽  
Chengjie Li ◽  
Xiujun Liu ◽  
Yongshu Xie
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Negative Effects ◽  
Dye Sensitized ◽  
Dye Aggregation ◽  
Novel Strategy ◽  
Conversion Efficiencies ◽  
Sensitized Solar Cells

Porphyrin dyes have been widely used for the fabrication of efficient dye-sensitized solar cells (DSSCs). However, dye aggregation and charge recombination still exert negative effects on photovoltaic performance, resulting in unsatisfactory power conversion efficiencies (PCEs). Herein, we report a new class of porphyrin sensitizers, XW52 and XW53 employing four benzyloxy groups to wrap the porphyrin cores. As a result, an efficiency of 7.6% was obtained for XW52, with [Formula: see text] and [Formula: see text] of 668 mV and 16.63 mA cm[Formula: see text], respectively. Compared with XW52, an additional 2,6-dialkoxyphenyl group has been introduced to the N-atom of the phenothiazine donor to furnish XW53 with the aim to further improve the anti-aggregation character and the solubility, and thus the [Formula: see text] was improved to 674 mV, and a higher efficiency of 7.9% was achieved for XW53. Upon cosensitization with PT-C6, the[Formula: see text] and [Formula: see text] were synergistically enhanced to 727 mV and 18.67 mA cm[Formula: see text], respectively. As a result, a high efficiency of 9.6% was successfully achieved for the cosensitization system of XW53 + PT-C6. These results provide an effective novel strategy for designing efficient porphyrin dyes by introducing multiple benzyloxy groups to the meso-phenyl groups.

scholarly journals Hierarchical TiO2 microspheres composed with nanoparticle-decorated nanorods for the enhanced photovoltaic performance in dye-sensitized solar cells

RSC Advances ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 3056-3062 ◽  
Author(s):  
Xiong He ◽  
Jingyu Zhang ◽  
Yan Guo ◽  
Jinghua Liu ◽  
Xin Li
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Dye Loading ◽  
Tio2 Microspheres ◽  
Sensitized Solar Cells

Hierarchical NP-MS combines the beneficial properties of improved scattering capability, dye loading ability, electron transport and inhibited charge recombination. The photoelectric conversion efficiency up to 7.32% has been obtained.

POTENTIAL EVALUATION OF YELLOW COTTON (COCHLOSPERMUM REGIUM) PIGMENTS FOR DYE SENSITIZED SOLAR CELLS APPLICATION

2020 ◽  
pp. 16-21
Author(s):  
PHITCHAPHORN KHAMMEE ◽  
YUWALEE UNPAPROM ◽  
UBONWAN SUBHASAEN ◽  
RAMESHPRABU RAMARAJ
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Plant Materials ◽  
Natural Pigments ◽  
Dye Sensitized ◽  
Study Results ◽  
Sensitized Solar Cells

Recently, dye-sensitized solar cells (DSSC) have concerned significant attention attributable to their material preparation process, architectural and environmental compatibility, also low cost and effective photoelectric conversion efficiency. Therefore, this study aimed to use potential plant materials for DSSC. This research presents the extraction of natural pigments from yellow cotton flowers (Cochlospermum regium). In addition, the natural pigments were revealed that outstanding advantages, including a wide absorption range (visible light), easy extraction method, safe, innocuous pigments, inexpensive, complete biodegradation and ecofriendly. Methanol was used as a solvent extraction for the yellow cotton flower. The chlorophylls and carotenoid pigments extractions were estimated by a UV-visible spectrometer. The chlorophyll-a, chlorophyll-b, and carotenoid yield were 0.719±0.061 µg/ml, 1.484±0.107 µg/ml and 7.743±0.141 µg/ml, respectively. Thus, this study results suggested that yellow cotton flowers containing reasonable amounts appealable in the DSSC production.

Tetraphenylethylene-bridged double-branched sensitizers featuring hetero-donors for dye-sensitized solar cells

2020 ◽  
Vol 44 (30) ◽  
pp. 12909-12915
Author(s):  
Yi-Qiao Yan ◽  
Yi-Zhou Zhu ◽  
Pan-Pan Dai ◽  
Jun Han ◽  
Mao Yan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Dyes ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Effects of hetero-donors on the photovoltaic performance of tetraphenylethylene-based organic dyes were systematically investigated.

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